1,2,5-trimethyl-3-phenoxybenzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,5-trimethyl-3-phenoxybenzene
• 英文别名: 1,3,4-trimethyl-5-phenoxybenzene
• 化学式: C₁₅H₁₆O
• 分子量: 212.291
• InChiKey: GQNKWBHBFKOICK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  碘苯 、 2,3,5-三甲基苯酚 在 caesium carbonate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以86%的产率得到1,2,5-trimethyl-3-phenoxybenzene
  参考文献：
  名称：

  Cu^I–USY as a Ligand-Free and Recyclable Catalytic System for the Ullmann-Type Diaryl Ether Synthesis

  摘要：

  The catalytic potential of copper(I)-exchanged zeolites was evaluated in the Ullmann-type synthesis of diaryl ethers. Among four investigated zeolites (i.e., USY, MOR, beta, and ZSMS), Cu-I-USY was the best catalyst and proved efficient under ligand-free conditions in toluene at 120 degrees C. Cu-I-USY was also easy to recover and was recyclable up to five times without significant loss of activity.

  DOI：

  10.1021/acs.orglett.5b02167

文献信息

• Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation
  作者：S. Quideau、L. Pouységu、A. Ozanne、J. Gagnepain

  DOI：10.3390/10010201

  日期：——

  Treatment of 2-methylphenols with chloro(diphenyl)-λ3-iodane led to theirregioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via aproposed ligand coupling reaction. In the same vein of investigation, treatment of2-methylanilines with the λ5-iodane 2-iodoxybenzoic acid IBX reagent led to theirregioselective dearomatization into previously undescribed ortho-quinol imines.

  对2-甲基苯酚与氯(diphenyl)-λ3-碘烷的反应促进了其区域选择性去芳构化反应，生成了环己-2,4-二烯酮衍生物，这一过程通过提出的配体耦合反应实现。同样，在这方面的研究中，2-甲基苯胺与λ5-碘烷2-碘氧苯甲酸（IBX）试剂的反应导致其区域选择性去芳构化，形成了先前未描述的邻-喹啉亚胺。
• Process for preparing polyarylene thioethers
  申请人：SEISAN KAIHATSU KAGAKU KENKYUSHO

  公开号：EP0440106A2

  公开（公告）日：1991-08-07

  Polyarylene thioethers are easily prepared by an oxidative polymerization of an aromatic compound of the formula (I) wherein R¹, R², R³ and R⁴ are each independently a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group, and Y is a hydrogen atom or a group of the formula (II) wherein R⁵, R⁶, R⁷ and R⁸ are each independently a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group and X is -O-, -S-, a methylene group or an ethylene group with a sulfidizing agent in the presence of an acid and an oxidizing agent, or in the presence of an acid, a catalyst for oxidative polymerization and oxygen, or in the presence of a Friedel-Crafts catalyst.

  通过式 (I) 的芳香族化合物的氧化聚合可轻松制备聚芳硫醚，式 (I) 中 R¹、R²、R³ 和 R⁴ 各自独立地为氢原子、卤素原子、低级烷基或低级烷氧基，Y 为氢原子或式 (II) 的基团，式 (II) 中 R⁵、R⁶、 R⁵、R⁶、R⁷ 和 R⁸ 各自独立地为氢原子、卤素原子、低级烷基或低级烷氧基，X 为-O-、-S-、亚甲基或亚乙基，在有酸和氧化剂存在下，或在有酸、氧化聚合催化剂和氧存在下，或在有 Friedel-Crafts 催化剂存在下，加入硫化剂。
• Film-forming ink, film formation method, device with film, and electronic apparatus
  申请人：SEIKO EPSON CORPORATION

  公开号：US10557046B2

  公开（公告）日：2020-02-11

  To provide a film-forming ink and a film formation method, capable of making the dimensional accuracy of a film to be formed excellent by increasing the apparent liquid droplet amount of a film-forming ink to be supplied as a liquid droplet into an opening part included in a partition wall, and also to provide a device with a film and an electronic apparatus, each of which has a film formed using the film formation method. A film-forming ink of the invention includes a film-forming material and a liquid medium in which the film-forming material is dissolved or dispersed, wherein the liquid medium contains a first component which has a boiling point at an atmospheric pressure of 200° C. or higher and a second component which has a boiling point at an atmospheric pressure lower than the first component.

  提供一种成膜油墨和一种成膜方法，能够通过增加成膜油墨作为液滴供应到包括在隔墙中的开口部分的表观液滴量，使要形成的薄膜的尺寸精度极佳，还提供一种带有薄膜的装置和一种电子设备，其中每种装置和设备都具有使用该成膜方法形成的薄膜。本发明的成膜油墨包括一种成膜材料和一种液体介质，成膜材料溶解或分散在液体介质中，其中液体介质包含在大气压力下沸点为 200 摄氏度或更高的第一种成分和在大气压力下沸点低于第一种成分的第二种成分。
• Regioselective Hypervalent-Iodine(III)-Mediated Dearomatizing Phenylation of Phenols through Direct Ligand Coupling
  作者：Aurélie Ozanne-Beaudenon、Stéphane Quideau

  DOI：10.1002/anie.200501638

  日期：2005.11.4
• FILM-FORMING INK, FILM FORMATION METHOD, DEVICE WITH FILM, AND ELECTRONIC APPARATUS
  申请人：SEIKO EPSON CORPORATION

  公开号：US20170267880A1

  公开（公告）日：2017-09-21

  To provide a film-forming ink and a film formation method, capable of making the dimensional accuracy of a film to be formed excellent by increasing the apparent liquid droplet amount of a film-forming ink to be supplied as a liquid droplet into an opening part included in a partition wall, and also to provide a device with a film and an electronic apparatus, each of which has a film formed using the film formation method. A film-forming ink of the invention includes a film-forming material and a liquid medium in which the film-forming material is dissolved or dispersed, wherein the liquid medium contains a first component which has a boiling point at an atmospheric pressure of 200° C. or higher and a second component which has a boiling point at an atmospheric pressure lower than the first component.