4-(6-methacryloxyhexyloxy)benzoic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(6-methacryloxyhexyloxy)benzoic acid
• 英文别名: 4-[6-(2-Methylprop-2-enoxy)hexoxy]benzoic acid
• 化学式: C₁₇H₂₄O₄
• 分子量: 292.375
• InChiKey: QDJZQOGSGIEUDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-甲氧基对苯二酚 、 4-(6-methacryloxyhexyloxy)benzoic acid 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 32.0h， 以4.5 g的产率得到[3-Methoxy-4-[4-[6-[(2-methyloxiran-2-yl)methoxy]hexoxy]benzoyl]oxyphenyl] 4-[6-[(2-methyloxiran-2-yl)methoxy]hexoxy]benzoate
  参考文献：
  名称：

  JP5750861

  摘要：

  公开号：
• 作为产物：
  描述：

  1,6-二溴己烷 在 四丁基溴化铵 、 potassium hydroxide 、 sodium hydroxide 作用下， 以 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 17.0h， 生成 4-(6-methacryloxyhexyloxy)benzoic acid
  参考文献：
  名称：

  JP5750861

  摘要：

  公开号：

文献信息

• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY ELEMENT COMPRISING THE LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2243813A1

  公开（公告）日：2010-10-27

  A liquid crystal composition comprising 100 parts by mass of a nematic liquid crystal composition having negative dielectric anisotropy and 0.01 to 3 parts by mass of a polymerizable compound of general formula (I). On being irradiated with an energy ray, such as UV rays, the liquid crystal composition provides an LCD capable of high-speed response without undergoing reduction in reliability (voltage holding ratio). In formula (I), rings C1, C2, and C3 are each benzene, cyclohexane or naphthalene; M1 and M2 are each hydrogen or methyl; Z1 is a direct bond, -L1-, -L1O-, etc.; Z4 is a direct bond, -L2-, -OL2-, etc.; at least one of Z1 and Z4 is not a direct bond; L1 and L2 are each C1-C10 alkylene; when Z1=Z4, one or more hydrogen atoms of the rings C1, C2, and C3 are substituted; Z2 and Z3 are each a direct bond, an ester bond, etc.; p and q are each 0 or 1, provided that p+q≥1.

  一种液晶组合物，由 100 份（质量份）具有负介电各向异性的向列液晶组合物和 0.01 至 3 份（质量份）通式（I）的可聚合化合物组成。当受到能量射线（如紫外线）照射时，该液晶组合物可提供高速响应的液晶显示器，而不会降低可靠性（电压保持率）。 在式 (I) 中，环 C1、C2 和 C3 分别是苯、环己烷或萘；M1 和 M2 分别是氢或甲基；Z1 是直接键、-L1-、-L1O- 等；Z4 是直接键、-L2-、-OL2- 等。当 Z1=Z4 时，环 C1、C2 和 C3 的一个或多个氢原子被取代；Z2 和 Z3 各为直接键、酯键等；p 和 q 各为 0 或 1，条件是 p+q≥1。
• Amid-Seitenkettenpolymere
  申请人：F. HOFFMANN-LA ROCHE AG

  公开号：EP0322708B1

  公开（公告）日：1993-04-28
• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING THE LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2243813B1

  公开（公告）日：2015-11-04
• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND AND LIQUID CRYSTAL DISPLAY USING THE LIQUID CRYSTAL COMPOSITION
  申请人：Matsumoto Ken

  公开号：US20100328601A1

  公开（公告）日：2010-12-30

  A liquid crystal composition includes 100 parts by mass of a nematic liquid crystal composition having negative dielectric anisotropy and 0.01 to 3 parts by mass of a polymerizable compound of general formula (I). On being irradiated with an energy ray, such as UV rays, the liquid crystal composition provides an LCD capable of high-speed response without undergoing reduction in reliability (voltage holding ratio). In formula (I), rings C 1-3 are benzene, cyclohexane or naphthalene; M 1-2 are hydrogen or methyl; Z 1 is a direct bond, -L 1 -, -L 1 O—, etc.; Z 4 is a direct bond, -L 2 -, —OL 2 -, etc.; at least one of Z 1 and Z 4 is not a direct bond; L 1,2 are C1-C10 alkylene; when Z 1 ═Z 4 , one or more hydrogen atoms of the rings C 1 , C 2 , and C 3 are substituted; Z 2 and Z 3 are each a direct bond, an ester bond, etc.; p and q are each 0 or 1, provided that p+q≧1.
• POLYMERIZABLE LIQUID CRYSTAL COMPOUNDS HAVING OXIRANYL GROUP, POLYMERIZABLE LIQUID CRYSTAL COMPOSITIONS AND POLYMERS
  申请人：Ootsuki Daisuke

  公开号：US20110147656A1

  公开（公告）日：2011-06-23

  Subject The main aim of the invention is to provide a polymerizable liquid crystal compound that has a liquid crystal phase with a wide temperature range centering at room temperature, has an excellent compatibility with another polymerizable liquid crystal compound, has an excellent solubility in an organic solvent and is polymerizable even in air by heat or light. Means for Solving the Subject A polymerizable liquid crystal compound represented by formula (1-1) or formula (1-2): wherein A 1 and A 2 are a divalent cyclic-structure group such as cyclohexylene and phenylene; Z 1 is a bonding group such as a single bond and —O—; m is an integer from 1 to 5; Q 1 and Q 2 are alkylene having 1 to 20 carbons; R 1 is fluorine, cyano, trifluoromethyl, trifluoromethoxy, alkyl, alkoxy and so forth; and R a and R b is hydrogen, halogen or alkyl.