4'-methyl-[2,2']bipyridinyl-4-(2-anthracen-9-ylmethyl-1-methyl ether)

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4'-methyl-[2,2']bipyridinyl-4-(2-anthracen-9-ylmethyl-1-methyl ether)
• 英文别名: 2-[4-[1,3-Di(anthracen-9-yl)propan-2-yloxymethyl]pyridin-2-yl]-4-methylpyridine；2-[4-[1,3-di(anthracen-9-yl)propan-2-yloxymethyl]pyridin-2-yl]-4-methylpyridine
• 化学式: C₄₃H₃₄N₂O
• 分子量: 594.756
• InChiKey: WTGYVOOSMJPGEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  46
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  35
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  9-溴蒽 在 正丁基锂 、 sodium hydride 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 74.5h， 生成 4'-methyl-[2,2']bipyridinyl-4-(2-anthracen-9-ylmethyl-1-methyl ether)
  参考文献：
  名称：

  Metal−Organic Approach to Binary Optical Memory

  摘要：

  Two new Ru(II) diimine chromophores, each containing a single photochromic dianthryl unit, have been prepared and characterized. The photoluminescence from the Ru(II) complexes is modulated by the photochromic action of the dianthryl species, which serves as a triplet energy transfer quencher in one photochromic state. The coupling of the dianthryl photochromic action to the Ru(II) complex emission permits nondestructive photoluminescence readout of binary information photochemically recorded on the molecular level. Luminescent images stored on polystyrene films that contain these molecules maintained their integrity for periods of months with no apparent degradation or variation in the image resolution, suggesting their durability for long-term storage in read-only memory applications.

  DOI：

  10.1021/ja0255608

文献信息

• Metal−Organic Approach to Binary Optical Memory
  作者：Daniel S. Tyson、Carlo A. Bignozzi、Felix N. Castellano

  DOI：10.1021/ja0255608

  日期：2002.5.1

  Two new Ru(II) diimine chromophores, each containing a single photochromic dianthryl unit, have been prepared and characterized. The photoluminescence from the Ru(II) complexes is modulated by the photochromic action of the dianthryl species, which serves as a triplet energy transfer quencher in one photochromic state. The coupling of the dianthryl photochromic action to the Ru(II) complex emission permits nondestructive photoluminescence readout of binary information photochemically recorded on the molecular level. Luminescent images stored on polystyrene films that contain these molecules maintained their integrity for periods of months with no apparent degradation or variation in the image resolution, suggesting their durability for long-term storage in read-only memory applications.