2,2-bis[4-(1,3-thioxolane-2-one-4-yl-methoxy)phenyl]propane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis[4-(1,3-thioxolane-2-one-4-yl-methoxy)phenyl]propane
• 英文别名: 2,2-Bis{4-(1,3-thioxolane-2-one-4-yl-methoxy)phenyl}propane；5-[[4-[2-[4-[(2-oxo-1,3-oxathiolan-5-yl)methoxy]phenyl]propan-2-yl]phenoxy]methyl]-1,3-oxathiolan-2-one
• 化学式: C₂₃H₂₄O₆S₂
• 分子量: 460.572
• InChiKey: MGQITNLWYYJRMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  122
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2,2-双-(4-甘胺氧苯)丙烷 在 sodium sulfide 、 四丁基氯化铵 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 2.2h， 生成 2,2-bis[4-(1,3-thioxolane-2-one-4-yl-methoxy)phenyl]propane
  参考文献：
  名称：

  [EN] METHOD FOR THE PREPARATION OF THIOCARBONATES
  [FR] PROCÉDÉ DE PRÉPARATION DE THIOCARBONATES

  摘要：

  制备至少含有一个五元环单硫代碳酸酯基团的化合物的方法：a）以至少含有一个环氧基团的化合物作为起始物质；b）将该化合物与光气或烷基氯甲酸酯反应，从而得到一个加合物；c）将该加合物与含有阴离子硫的化合物反应，从而获得至少含有一个五元环单硫代碳酸酯基团的化合物。

  公开号：

  WO2019034469A1

文献信息

• [EN] PROCESS FOR THE MANUFACTURING OF A POLYMER WITH URETHANE GROUPS<br/>[FR] PROCÉDÉ DE FABRICATION D'UN POLYMÈRE AYANT DES GROUPES URÉTHANNE
  申请人：BASF SE

  公开号：WO2019034473A1

  公开（公告）日：2019-02-21

  Process for the manufacturing of a polymer with urethane groups, wherein in a first alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups and a compound B) with at least two amino groups, selected from primary or secondary amino groups and optionally a compound C) with at least one functional group that reacts with a group -SH are reacted or wherein in a second alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups or a mixture of a compound A) with a compound A1)with one five-membered cyclic monothiocarbonate group and a compound B) with at least two amino groups, selected from primary or secondary amino groups or a compound B1) with one amino group selected from primary or secondary amino groups or mixtures of compounds B) and B1) and a compound C) with at least two functional groups that react with a group -SH or in case of a carbon-carbon triple bond as functional group that react with a group -SH, a compound C) with at least one carbon-carbon triple bond. are reacted.

  制造含有尿烷基团的聚合物的过程，其中，在第一种替代方案中，至少具有两个五元环状单硫代碳酸酯基团的化合物A)与至少具有两个氨基的化合物B)反应，这些氨基选自伯氨基或仲氨基，以及可选的至少含有一个与-SH基团反应的功能性基团的化合物C)；或者在第二种替代方案中，至少具有两个五元环状单硫代碳酸酯基团的化合物A)或化合物A)与具有一个五元环状单硫代碳酸酯基团的化合物A1)的混合物与至少具有两个氨基的化合物B)反应，这些氨基选自伯氨基或仲氨基，或具有一个氨基的化合物B1)，该氨基选自伯氨基或仲氨基，或化合物B)和B1)的混合物，以及至少具有两个与-SH基团反应的功能性基团的化合物C)，或当功能性基团为碳-碳三键时，至少具有一个碳-碳三键的化合物C)。
• [EN] PROCESS FOR THE SYNTHESIS OF POLYCARBONATES FROM CYCLIC MONOTHIOCARBONATES<br/>[FR] PROCÉDÉ DE SYNTHÈSE DE POLYCARBONATES À PARTIR DE MONOTHIOCARBONATES CYCLIQUES
  申请人：BASF SE

  公开号：WO2020229393A1

  公开（公告）日：2020-11-19

  A process for the synthesis of compounds comprising at least one non-cyclic carbonate group is provided, wherein a compound A) comprising at least one five-membered cyclic monothiocarbonate group is reacted with at least one hydroxy group of a compound B) or of compound A) itself.

  提供一种合成至少含有一个非环状碳酸酯基团的化合物的方法，其中将至少含有一个五元环单硫代碳酸酯基团的化合物A)与化合物B)或化合物A)本身的至少一个羟基发生反应。
• Method for the preparation of thiocarbonates
  申请人：BASF SE

  公开号：US11247979B2

  公开（公告）日：2022-02-15

  Process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group wherein a) a compound with at least one epoxy group is used as starting material b) the compound is reacted with phosgene or an alkyl chloroformate thus giving an adduct and c) the adduct is reacted with a compound comprising anionic sulfurthus obtaining the compound with at least one five-membered cyclic monothiocarbonate group.

  制备含有至少一个五元环单硫代碳酸酯基团的化合物的工艺，其中 a) 使用含有至少一个环氧基团的化合物作为起始原料；b) 将该化合物与光气或氯甲酸烷基酯反应，从而得到加合物；c) 将该加合物与含有阴离子硫磺的化合物反应，得到含有至少一个五元环单硫代碳酸酯基团的化合物。
• PROCESS FOR THE MANUFACTURING OF A POLYMER WITH URETHANE GROUPS
  申请人：BASF SE

  公开号：US20200239633A1

  公开（公告）日：2020-07-30

  Process for the manufacturing of a polymer with urethane groups, wherein in a first alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups and a compound B) with at least two amino groups, selected from primary or secondary amino groups and optionally a compound C) with at least one functional group that reacts with a group —SH are reacted or wherein in a second alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups or a mixture of a compound A) with a compound A1) with one five-membered cyclic monothiocarbonate group and a compound B) with at least two amino groups, selected from primary or secondary amino groups or a compound B1) with one amino group selected from primary or secondary amino groups or mixtures of compounds B) and B1) and a compound C) with at least two functional groups that react with a group —SH or in case of a carbon-carbon triple bond as functional group that react with a group —SH, a compound C) with at least one carbon-carbon triple bond. are reacted.
• METHOD FOR THE PREPARATION OF THIOCARBONATES
  申请人：BASF SE

  公开号：US20200369641A1

  公开（公告）日：2020-11-26

  Process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group wherein a) a compound with at least one epoxy group is used as starting material b) the compound is reacted with phosgene or an alkyl chloroformate thus giving an adduct and c) the adduct is reacted with a compound comprising anionic sulfurthus obtaining the comound with at least one five-membered cyclic monothiocarbonate group.