N,N'-bis(trans-cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(trans-cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane
• 英文别名: (E)-3-phenyl-N-[2-[2-[2-[[(E)-3-phenylprop-2-enylidene]amino]phenyl]sulfanylethylsulfanyl]phenyl]prop-2-en-1-imine
• 化学式: C₃₂H₂₈N₂S₂
• 分子量: 504.72
• InChiKey: SSNSCPHNFSOIGQ-VHULFRMVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  36
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  75.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 N,N'-bis(trans-cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane 以 氯仿 、 乙腈 为溶剂， 以79%的产率得到[Cu(N,N'-bis(trans-cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane)2]ClO4
  参考文献：
  名称：

  Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca2-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca2dapte)]ClO4 and [{Cu(PPh3)(X)}2(ca2dapte)] (X=I and Br)

  摘要：

  A mononuclear copper(I) complex, [Cu(ca(2)dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = 1 (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca(2)dapte = N,N'-bis(trans-cinnamaidehyde)-1,2-di(o-iminophenylthio)ethane). These compounds have been characterized by elemental analyses (CHN), FT-IR, UV-Vis and H-1 NMR spectroscopy. The crystal structures of these copper(l) complexes have been determined by single-crystal X-ray diffraction. The coordination geometry around Cu(I) centers in these complexes is a distorted tetrahedron. The Ca(2)dapte is coordinated to Cu(I) as a tetradentate ligand in 1, while it acts as a bis-bidentate bridging ligand in 2 and 3. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.018

文献信息

• Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca2-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca2dapte)]ClO4 and [{Cu(PPh3)(X)}2(ca2dapte)] (X=I and Br)
  作者：Mahbod Morshedi、Mehdi Amirnasr、Alexandra M.Z. Slawin、J Derek Woollins、Aliakbar Dehno Khalaji

  DOI：10.1016/j.poly.2008.10.018

  日期：2009.1

  A mononuclear copper(I) complex, [Cu(ca(2)dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = 1 (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca(2)dapte = N,N'-bis(trans-cinnamaidehyde)-1,2-di(o-iminophenylthio)ethane). These compounds have been characterized by elemental analyses (CHN), FT-IR, UV-Vis and H-1 NMR spectroscopy. The crystal structures of these copper(l) complexes have been determined by single-crystal X-ray diffraction. The coordination geometry around Cu(I) centers in these complexes is a distorted tetrahedron. The Ca(2)dapte is coordinated to Cu(I) as a tetradentate ligand in 1, while it acts as a bis-bidentate bridging ligand in 2 and 3. (C) 2008 Elsevier Ltd. All rights reserved.