(2-methoxyphenyl)triphenylphosphonium chloride

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-methoxyphenyl)triphenylphosphonium chloride
• 英文别名: (2-Methoxyphenyl)-triphenylphosphanium;chloride
• 化学式: C₂₅H₂₂OP*Cl
• 分子量: 404.876
• InChiKey: OEJRZRJGJKOGJS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.32
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-氯苯甲醚 、 三苯基膦 在 2,4,5-tri(9H-carbazol-9-yl)-6-(ethyl(phenyl)amino)isophthalonitrile 、 N,N-二异丙基乙胺 作用下， 以 乙腈 为溶剂， 反应 48.0h， 以80%的产率得到(2-methoxyphenyl)triphenylphosphonium chloride
  参考文献：
  名称：

  揭示供体-受体氰芳烃从芳基氯化物中获取芳基自由基的极端光还原潜力

  摘要：

  自 2016 年张的开创性工作以来，供体 - 受体氰芳烃基荧光团，如 1,2,3,5-四（咔唑-9-基）-4,6-二氰基苯（4CzIPN），已广泛应用于光氧化还原催化，并用作贵金属 Ir 和 Ru 基光催化剂的优良无金属替代品。然而，所有报道的涉及这个发色团家族的光氧化还原反应都是基于利用来自单个可见光光子的能量，氧化还原电位范围有限，从 -1.92 到 +1.79 V vs SCE。在这里，我们记录了这一前所未有的发现，即该荧光团家族可以进行连续的光致电子转移 (ConPET) 以实现非常高的还原电位。一种新合成的催化剂，2,4,5-tri(9 H-咔唑-9-基)-6-(乙基(苯基)氨基)间苯二甲腈 (3CzEPAIPN)，具有长寿命 (12.95 ns) 激发自由基阴离子形式，3CzEPAIPN •– *，可用于活化还原性顽固芳基氯化物（E red ≈ -1.9 至 -2.9 V vs

  DOI：

  10.1021/jacs.1c05994

文献信息

• PROCESSES FOR THE PRODUCTION OF POLYCARBONATE
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0908484A1

  公开（公告）日：1999-04-14

  Provided are a method for producing polycarbonates through melt transesterification, wherein is used a polymerization catalyst comprising a phosphorus-containing basic compound and a quaternary phosphonium salt having a specific structure; and a method for producing polycarbonates, which comprises pre-polymerization to prepare polycarbonate prepolymers followed by final polymerization of said prepolymers in a solid phase or in a swollen solid phase to produce the products, polycarbonates, and in which (1) a catalyst comprising a phosphorus-containing basic compound and a quaternary phosphonium salt having a specific structure is used in the pre-polymerization and in the final polymerization, or (2) a catalyst of a tri-valent or penta-valent phosphorus compound or a nitrogen-containing organic basic compound is used in the final polymerization, or (3) the final polymerization is effected in a vapor-phase atmosphere having an oxygen concentration of not larger than 2 ppm. In those methods, high-quality polycarbonates having good appearance, high heat resistance and high hydrolysis resistance are produced extremely efficiently.

  提供了一种通过熔融酯交换反应生产聚碳酸酯的方法，其中使用了一种聚合催化剂，该催化剂由含磷碱性化合物和具有特定结构的季鏻盐组成；一种生产聚碳酸酯的方法，包括预聚合以制备聚碳酸酯预聚物，然后在固相或溶胀固相中对所述预聚物进行最终聚合以生产产品聚碳酸酯，其中 (1) 在预聚合和最终聚合中使用由含磷碱性化合物和具有特定结构的季鏻盐组成的催化剂、或 (2) 在最终聚合中使用三价或五价磷化合物或含氮有机碱性化合物催化剂，或 (3) 在氧气浓度不大于 2 ppm 的气相气氛中进行最终聚合。在这些方法中，可以极其高效地生产出具有良好外观、高耐热性和高抗水解性的优质聚碳酸酯。
• COPOLYCARBONATE AND PROCESS FOR PRODUCING THE SAME
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1035150A1

  公开（公告）日：2000-09-13

  Provided are an aromatic polycarbonate copolymer and a method for producing it. An aromatic dihydroxy compound, at least one member selected from the group consisting of polyorganosiloxanes and aliphatic polyalcohols, and a dicarbonate are prepolymerized under heat to give a polycarbonate prepolymer, and the prepolymer is polymerized in a solid or swollen solid phase in the presence of a quaternary phosphonium salt serving as a catalyst to give an aromatic polycarbonate copolymer. The remaining monomer content, the acetone soluble content (that is, the low-molecular-weight substance content) and the cyclic oligomer content of the copolymer are all reduced, and the terminal hydroxyl fraction thereof is also reduced.

  本发明提供了一种芳香族聚碳酸酯共聚物及其生产方法。一种芳香族二羟基化合物、至少一种选自聚有机硅氧烷和脂肪族多元醇组成的组的成员和一种二碳酸盐在加热下预聚，得到一种聚碳酸酯预聚物，该预聚物在作为催化剂的季鏻盐存在下在固相或膨胀固相中聚合，得到一种芳香族聚碳酸酯共聚物。共聚物的剩余单体含量、丙酮可溶物含量（即低分子量物质含量）和环状低聚物含量都会降低，其末端羟基部分也会降低。
• POLYCARBONATE AND OPTICAL MATERIAL
  申请人：Idemitsu Petrochemical Co., Ltd.

  公开号：EP1069146A1

  公开（公告）日：2001-01-17

  Disclosed are polycarbonates which are obtained by preparing a polycarbonate prepolymer through prepolymerization followed by polymerizing it through solid-phase, swollen solid-phase or thin film melt-phase transesterification, and have a remaining monomer content of smaller than 100 ppm, especially a dihydroxy compound content of smaller than 100 ppm, or have an acetone soluble content of at most 3.5 or at most 3.0 % by weight, or have a terminal hydroxyl fraction of smaller than 2 or smaller than 15 mol%; and optical materials and blow molding materials comprising the polycarbonate. The polycarbonates contain a reduced amount of impurities such as remaining monomers, oligomers and others and have improved physical properties including impact strength, and these are useful as optical materials and blow molding materials.

  所公开的聚碳酸酯是通过预聚合制备聚碳酸酯预聚物，然后通过固相、膨胀固相或薄膜熔融相酯化聚合而得，其剩余单体含量小于 100 ppm，特别是二羟基化合物含量小于 100 ppm，或丙酮可溶物含量最多为 3.5 或最多 3.0%（按重量计），或末端羟基部分小于 2 或小于 15 摩尔%；以及包含这种聚碳酸酯的光学材料和吹塑材料。这种聚碳酸酯含有较少的杂质，如剩余的单体、低聚物和其他物质，具有更好的物理性能，包括冲击强度，可用作光学材料和吹塑材料。
• PROCESS FOR PRODUCING POLYCARBONATE
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0807657B1

  公开（公告）日：2004-05-19
• Polycarbonate Prepolymer for Solid Phase Polymerization and Process for Producing Polycarbonate
  申请人：Ito Mitsunori

  公开号：US20080064847A1

  公开（公告）日：2008-03-13

  A polycarbonate prepolymer for solid state polymerization, which is produced by an oxidative carbonylation reaction of an aromatic dihydroxy compound, a monohydric phenol having a boiling point of 330° C. or below, carbon monoxide and oxygen, the polycarbonate prepolymer being characterized by that (a) a ratio of aryl carbonate groups and hydroxyl groups each constituting terminal groups of the prepolymer is from 2:8 to 8:2, and (b) a molecular weight distribution (Mw/Mn) is from 1.1 to 2.1; and a process of producing polycarbonates including a step of solid state-polymerizing the prepolymer so as to increase the molecular weight thereof. According to the present invention, the prepolymer having a controlled molecular weight distribution suitable for solid state polymerization is provided, and a high quality polycarbonate is efficiently produced in environmentally friend manner.