1,2,4,5-tetrakis(isopropylselenomethyl)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,4,5-tetrakis(isopropylselenomethyl)benzene
• 英文别名: 1,2,4,5-Tetrakis(propan-2-ylselanylmethyl)benzene；1,2,4,5-tetrakis(propan-2-ylselanylmethyl)benzene
• 化学式: C₂₂H₃₈Se₄
• 分子量: 618.384
• InChiKey: QJOWQYJMAXQXBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.82
• 重原子数：
  26
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  二异丙基二硒醚 、 四溴甲苯 在 sodium tetrahydroborate 、 水 作用下， 以 四氢呋喃 、 水 为溶剂， 以75%的产率得到1,2,4,5-tetrakis(isopropylselenomethyl)benzene
  参考文献：
  名称：

  Synthesis of sterically encumbered organoselenium species and their selectivity towards Hg(II) ions

  摘要：

  The synthesis and characterization data for an intriguing family of sterically encumbered tetrasubstituted organoselenium species are described. The open exterior geometry and flexibility of the multiple soft selenium-containing donor arms enhances conformational organization thus allowing the molecule to reveal a propensity for trapping Hg(II) ions. Preliminary studies on the ion-sensing properties of these molecules revealed that they can act as selective ionophores for Hg(II) ions. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.05.020

文献信息

• Synthesis of sterically encumbered organoselenium species and their selectivity towards Hg(II) ions
  作者：Monika Maheshwari、Shabana Khan、Jai Deo Singh

  DOI：10.1016/j.tetlet.2007.05.020

  日期：2007.7

  The synthesis and characterization data for an intriguing family of sterically encumbered tetrasubstituted organoselenium species are described. The open exterior geometry and flexibility of the multiple soft selenium-containing donor arms enhances conformational organization thus allowing the molecule to reveal a propensity for trapping Hg(II) ions. Preliminary studies on the ion-sensing properties of these molecules revealed that they can act as selective ionophores for Hg(II) ions. (c) 2007 Elsevier Ltd. All rights reserved.