1,8-diselenanthracenometacyclophane

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,8-diselenanthracenometacyclophane
• 英文别名: 3,19-Diselenapentacyclo[19.3.1.19,13.05,10.012,17]hexacosa-1(25),5,7,9(26),10,12,14,16,21,23-decaene；3,19-diselenapentacyclo[19.3.1.19,13.05,10.012,17]hexacosa-1(25),5,7,9(26),10,12,14,16,21,23-decaene
• 化学式: C₂₄H₂₀Se₂
• 分子量: 466.343
• InChiKey: KPTGOGDSUIWALS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.12
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,3-bis(selenocyanatomethyl)benzene 、 1,8-双(溴甲基)蒽 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 以65%的产率得到1,8-diselenanthracenometacyclophane
  参考文献：
  名称：

  Anthracene derivatives bearing sulfur atoms or selenium atoms as fluorescent chemosensors for Cu2+ and Hg2+: different selectivity induced from ligand immobilization onto anthracene

  摘要：

  Two new selenium containing anthracene derivatives and two new sulfur containing anthracene derivatives were synthesized as fluorescent chemosensors; for Hg2+ and CU2+. Compound 1 displayed a highly selective chelation enhanced fluorescence quenching (CHEQ) effect only with Cu2+, on the other hand, compounds 3 and 4 displayed highly selective chelation enhanced fluorescence (CHEF) effects only with Hg2+ among the metal ions examined. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.10.001

文献信息

• Anthracene derivatives bearing sulfur atoms or selenium atoms as fluorescent chemosensors for Cu2+ and Hg2+: different selectivity induced from ligand immobilization onto anthracene
  作者：Yoon Ju Lee、Dongwon Seo、Ji Young Kwon、Guiyoup Son、Min Sun Park、Yun-Hee Choi、Jung Hyun Soh、Ha Na Lee、Kap Duk Lee、Juyoung Yoon

  DOI：10.1016/j.tet.2006.10.001

  日期：2006.12

  Two new selenium containing anthracene derivatives and two new sulfur containing anthracene derivatives were synthesized as fluorescent chemosensors; for Hg2+ and CU2+. Compound 1 displayed a highly selective chelation enhanced fluorescence quenching (CHEQ) effect only with Cu2+, on the other hand, compounds 3 and 4 displayed highly selective chelation enhanced fluorescence (CHEF) effects only with Hg2+ among the metal ions examined. (c) 2006 Elsevier Ltd. All rights reserved.