Liquid stable polymer/polyol composition and the use there of for producing polyurethanes
申请人:ARCO Chemical Technology, L.P.
公开号:EP0190769A2
公开(公告)日:1986-08-13
A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alkyl mercaptan, (1) from about 25 to about 60 weight percent of an ethylenically unsaturated monomer or monomers, for example, a mixture of acrylonitrile and styrene in weight ratio respectively of 25:75 to 0:100, dissolved or dispersed in (2) from about 40 to about 75 weight precent of a polyol comprising a base polyol having a hydroxyl number of less than about 150, wherein the polymer is characterized by a crosslinking coefficient of less than 55 and an intrinsic viscosity of at least 0.30.
The resulting polymer/polyol composition is treated to reduce the product viscosity to essentially the indigenous system viscosity in polymer/polyol compositions of this type.
一种通常为液态的稳定聚合物/多元醇组合物,可改善由其制备的聚氨酯泡沫塑料的耐燃烧性,同时保持令人满意的泡沫塑料拉伸性能,该组合物是在存在自由基催化剂且基本不含烷基硫醇的情况下,通过聚合以下物质而形成的:(1)约 25 至约 60 重量百分数的乙烯基不饱和单体或单体,例如重量比分别为 25:(2) 约 40 至约 75 重量百分比的多元醇,包括羟基数小于约 150 的基质多元醇, 其中聚合物的特点是交联系数小于 55,固有粘度至少为 0.30.
所得聚合物/多元醇组合物经处理后,产品粘度基本上可降至此类聚合物/多元醇组合物的固有体系粘度。