己二酸与1,2-乙二醇和1,2-丙二醇的聚合物 | 26523-14-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 己二酸与1,2-乙二醇和1,2-丙二醇的聚合物
• 英文名称: Ethane-1,2-diol;hexanedioic acid;propane-1,2-diol
• CAS: 26523-14-8
• 化学式: C11H24O8
• 分子量: 284.3
• InChiKey: SBTWDPVRUJHZSW-UHFFFAOYSA-N

物化性质

• 熔点：
  60 °C

计算性质

• 辛醇/水分配系数(LogP)：
  -0.95
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  156
• 氢给体数：
  6
• 氢受体数：
  8

文献信息

• Aqueous coating composition for plastic substrates and coating method
  申请人：KANSAI PAINT CO. LTD.

  公开号：EP0466136A1

  公开（公告）日：1992-01-15

  The present invention relates to aqueous coating compositions for plastics substrates, a coating method and a plastics article the surface of which is formed with an undercoat of said coating composition. The coating composition comprises an aqueous medium having dispersed therein a water-miscible vehicle component comprising an olefin resin, a urethane resin and an epoxy resin. The aqueous coating composition of the invention forms coatings which exhibit excellent adhesion to plastics substrates and to overcoats. Moreover, the composition itself has high storage stability, while the coating prepared from the composition has high resistance to bending and water in addition to the above characteristics and is highly smooth-surfaced to give an excellent appearance to the overcoat or top coat.

  本发明涉及用于塑料基材的水性涂料组合物、涂覆方法和塑料制品，其表面由所述涂料组合物的底涂层形成。 涂层组合物由水介质组成，水介质中分散有水可混溶的载体组分，载体组分包括烯烃树脂、聚氨酯树脂和环氧树脂。 本发明的水性涂料组合物形成的涂料对塑料基材和外涂层具有极佳的附着力。此外，该组合物本身具有很高的储存稳定性，而由该组合物制备的涂层除具有上述特点外，还具有很高的抗弯曲性和抗水性，并且表面非常光滑，使罩面漆或面漆具有极佳的外观。
• AQUEOUS POLYPROPYLENE DISPERSION, AQUEOUS POLYPROPYLENE COMPOSITE EMULSION COMPOSITION, AND USE THEREOF
  申请人：Mitsubishi Chemical Corporation

  公开号：EP1500680A1

  公开（公告）日：2005-01-26

  A polypropylene type aqueous dispersion comprising the following components (a) to (c): (a) a polypropylene type polymer and/or a modified polypropylene type polymer 100 parts by weight (b) a surfactant 1 to 100 parts by weight, and (c) water 100 to 1,000 parts by weight, wherein the component (a) has a main chain having the following features (1) and (2) and dispersion particles in the dispersion have an average particle size of at most 0.5 µm,    Feature (1) when observing a peak derived from a carbon atom of a methyl group in a propylene unit chain part comprising a head-to-tail bond by 13C-NMR and fixing a chemical shift of a peak top at a peak attributable to pentad expressed by mmmm to 21.8 ppm, a ratio (S1/S) of an area S1 of a peak of a peak top at 21.8 ppm to a total area S of peaks at from 19.8 ppm to 22.1 ppm is at least 10% and at most 60%, and when an area of a peak (mmmr) of a peak top at 21.5 to 21.6 ppm is expressed as S2, 4+2S1/S2>5, and    Feature (2) a content ratio (mol ratio) of propylene unit (A): other olefin unit (B) is from 100:0 to 90:10.

  一种聚丙烯型水性分散体，包括以下成分(a)至(c)： (a) 聚丙烯类聚合物和/或改性聚丙烯类聚合物 100 份（重量比 (b) 表面活性剂 1 至 100 份（按重量计），和 (c) 水 100 至 1,000 份（重量比），其中组分（a）的主链具有以下特征（1）和（2）， 分散液中的分散微粒的平均粒径不超过 0.5 微米、 特征(1)当用 13C-NMR 观察由头对尾键组成的丙烯单元链部分中的甲基的碳原子所产生的峰，并将峰顶的化学位移固定在以 mmmm 表示的归属于 pentad 的峰的化学位移为 21.8 ppm，21.8 ppm处峰顶的峰面积S1与19.8 ppm至22.1 ppm处峰的总面积S之比(S1/S)至少为10%，最多为60%，当21.5至21.6 ppm处峰顶的峰面积(mmmr)用S2表示时，4+2S1/S2>5，以及 特征（2）丙烯单元（A）：其他烯烃单元（B）的含量比（摩尔比）为 100:0 至 90:10。
• AQUEOUS RESIN DISPERSION, METHOD FOR PRODUCING SAME, COATING MATERIAL, AND MULTILAYER BODY
  申请人：Mitsubishi Chemical Corporation

  公开号：EP1887026A1

  公开（公告）日：2008-02-13

  To provide an aqueous dispersion of a resin wherein dispersed particles are stable with fine particle sizes and whereby bleeding out is suppressed, which is thus useful as e.g. a surface treating agent for a polyolefin substrate, an adhesive or a coating material. A resin dispersion having dispersed in water a polymer (C) having a hydrophilic polymer (B) bonded to a polyolefin (A) in a ratio of (A):(B)=100:5 to 100:500 (weight ratio); a method for producing the resin dispersion; and a coating material and a laminate, employing it.

  提供一种树脂的水分散液，其中分散的颗粒稳定，粒度细小，并可抑制渗出，因此可用作聚烯烃基材的表面处理剂、粘合剂或涂层材料等。 一种树脂分散体，其在水中分散有聚合物（C），该聚合物（C）具有亲水性聚合物（B），并以 (A):(B)=100:5 至 100:500（重量比）的比例与聚烯烃（A）粘合；一种生产该树脂分散体的方法；以及一种使用该树脂分散体的涂层材料和层压板。
• AQUEOUS DISPERSION CONTAINING POLYOLEFIN GRAFT COPOLYMER
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2241582A1

  公开（公告）日：2010-10-20

  According to the present invention, an aqueous dispersion containing a graft copolymer satisfying (a) to (e) shown below and water is provided, and it is an aqueous dispersion containing a graft copolymer which shows an excellent dispersibility even in a state of reducing a surfactant and which is excellent in an affinity with a binder resin, a pigment and the like: (a) a graft rate is 1 to 150 % by mass, (b) a weight average molecular weight measured by GPC is 500 to 400000, (c) a molecular weight distribution (Mw/Mn) is 1.5 to 4, (d) a main chain is a polymerization chain containing a monomer unit having a hydrophilic group and (e) a side chain is a homopolymerization chain of a single kind or a copolymerization chain of two or more kinds selected from α-olefins having 3 to 28 carbon atoms or a copolymerization chain comprising an α-olefin unit having 3 to 28 carbon atoms and an ethylene unit which accounts for 50 % by mass or less, wherein a mesopentad ratio [mmmm] of the polymerization chain is 30 to 80 mole %.

  根据本发明，提供了一种含有满足下图(a)至(e)的接枝共聚物和水的水性分散体，它是一种含有接枝共聚物的水性分散体，即使在减少表面活性剂的状态下也显示出优异的分散性，并且与粘合剂树脂、颜料等的亲和性优异： (a) 接枝率为 1-150%（质量百分比）、 (b) 用 GPC 测得的平均分子量为 500 至 400000、 (c) 分子量分布（Mw/Mn）为 1.5 至 4、 (d) 主链是含有亲水基团单体单元的聚合链，以及 (e) 侧链是单一种类的均聚链，或两种或两种以上的共聚链，选自具有 3 至 28 个碳原子的 α-烯烃，或由具有 3 至 28 个碳原子的 α-烯烃单元和乙烯单元组成的共聚链，乙烯单元的质量占 50%或更少，其中聚合链的中五元比[mmm]为 30 至 80 摩尔%。
• AQUEOUS PAINT COMPOSITION AND METHOD FOR FORMING COATING
  申请人：KANSAI PAINT CO., LTD.

  公开号：EP2835404A1

  公开（公告）日：2015-02-11

  An object of the present invention is to provide an aqueous coating composition that can form a coating with excellent smoothness, distinctness of image, water resistance, and chipping resistance, and that has excellent wash-off properties, and a method for forming the coating film. As means for achieving this object, the present invention provides an aqueous coating composition for use as an aqueous first colored coating composition in a multilayer coating-forming method, the coating composition containing an aqueous film-forming resin (A), a crosslinking agent (B), and acrylic urethane resin composite particles (C). The acrylic resin of the acrylic urethane resin composite particles (C) is obtained by using, as constituent monomers, 30 to 80 mass% of a polymerizable unsaturated monomer (c-1-1) having one polymerizable unsaturated group per molecule and having a C4-22 alkyl group, 1 to 20 mass% of a polymerizable unsaturated monomer (c-2) having two or more polymerizable unsaturated groups per molecule, and 0 to 69 mass% of a polymerizable unsaturated monomer (c-1-2) having one polymerizable unsaturated group per molecule and being other than the polymerizable unsaturated monomer (c-1-1).

  本发明的目的是提供一种水性涂料组合物，该组合物可以形成具有优异平滑度、图像清晰度、耐水性和抗崩角性的涂层，并且具有优异的冲洗性能，以及一种形成涂膜的方法。作为实现这一目标的方法，本发明提供了一种水性涂料组合物，可用作多层涂料形成方法中的水性第一有色涂料组合物，该涂料组合物含有水性成膜树脂（A）、交联剂（B）和丙烯酸聚氨酯树脂复合颗粒（C）。丙烯酸聚氨酯树脂复合颗粒（C）中的丙烯酸树脂是通过使用 30% 至 80% 的可聚合不饱和单体（c-1-1）作为组成单体获得的，该单体每个分子具有一个可聚合不饱和基团，并具有一个 C4-22 烷基、1 至 20 质量百分比的可聚合不饱和单体 (c-2)，其每个分子具有两个或两个以上的可聚合不饱和基团；以及 0 至 69 质量百分比的可聚合不饱和单体 (c-1-2)，其每个分子具有一个可聚合不饱和基团，且与可聚合不饱和单体 (c-1-1) 不同。