己二酸与1,4-丁二醇和1,2-乙二醇的聚合物 | 26570-73-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 己二酸与1,4-丁二醇和1,2-乙二醇的聚合物
• 英文名称: Butane-1,4-diol;ethane-1,2-diol;hexanedioic acid
• CAS: 26570-73-0
• 化学式: C12H26O8
• 分子量: 298.33
• InChiKey: LBXDJRWWKSGUOY-UHFFFAOYSA-N

物化性质

• 熔点：
  20 °C
• 密度：
  1.27 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  -0.56
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  156
• 氢给体数：
  6
• 氢受体数：
  8

文献信息

• Elastomers based on 4,4'-diisocyanato dicyclohexylmethane enriched in the trans, trans isomer which contain essentially no chain extenders
  申请人：Bayer Corporation

  公开号：EP0536604A2

  公开（公告）日：1993-04-14

  Disclosed herein is an improved elastomer comprising a reaction product of a polyisocyanate and an active hydrogen containing material, the improvement wherein the elastomer is essentially free of a chain extender, wherein the polyisocyanate comprises 4,4'-diisocyanato dicyclohexylmethane containing from about 45 to 100 percent of the trans,trans isomer.

  本文公开了一种改进型弹性体，该弹性体由多异氰酸酯和活性含氢材料的反应产物组成，改进型弹性体基本上不含扩链剂，其中多异氰酸酯包括 4,4'-二异氰酸酯二环己基甲烷，含有约 45%至 100%的反式、反式异构体。
• Chain extender useful in the manufacture of polyurethanes and the corresponding polyurethanes
  申请人：HUNTSMAN INTERNATIONAL LLC

  公开号：EP1466932A1

  公开（公告）日：2004-10-13

  The invention provides a novel chain extender which is a diamino-substituted heterocycle of formula I, and its use in the manufacture of polyurethanes (PUs), the PUs thus obtained, reactive compositions containing said chain extender, and processes for manufacturing PUs. The formula I is represented as follows:

  本发明提供了一种新型扩链剂，它是式 I 的二氨基取代杂环，并提供了其在制造聚氨酯 (PU) 中的用途、由此获得的聚氨酯、含有所述扩链剂的反应性组合物以及制造聚氨酯的工艺。式 I 表示如下
• Fabrication and application of shape memory polymer possessing transesterification induced permanent reshaping property
  申请人：ZHEJIANG UNIVERSITY

  公开号：US10449709B2

  公开（公告）日：2019-10-22

  The present invention discloses the fabrication and application of a shape memory polymer possessing transesterification-induced permanent reshaping. The ester-containing crosslinked polymer is obtained by crosslinking ester bearing polymer precursors or by reaction of monomers which yield ester bonds. The transition temperature falls between 20-150° C. The reshaping temperature is tuned by catalyst amount and should be 20° C. above the transition temperature. The breakthrough of the present invention lies in integrating shape memory effect and plastic deformation into the same polymer and triggering the respective function at different occasions. The permanent shape of as synthesized polymer could be modified arbitrarily and cumulatively. Therefore, the hierarchical structure which could not otherwise be obtained due to the limit of mold fabrication process should expand the practical application of SMPs.

  本发明公开了一种形状记忆聚合物的制造和应用，这种聚合物具有酯化诱导的永久重塑特性。含酯交联聚合物是通过交联含酯聚合物前体或单体反应生成酯键而获得的。转变温度介于 20-150 摄氏度之间。重塑温度由催化剂用量调节，应高于转变温度 20 摄氏度。本发明的突破在于将形状记忆效应和塑性变形整合到同一种聚合物中，并在不同场合触发各自的功能。合成聚合物的永久形状可任意累积改变。因此，由于模具制造工艺的限制而无法获得的分层结构应能扩大 SMP 的实际应用。
• Method for controlling stress distribution in material and reading stress information
  申请人：ZHEJIANG UNIVERSITY

  公开号：US10685200B2

  公开（公告）日：2020-06-16

  The invention relates to a method for controlling the stress distribution in a material, comprising the steps of: a, preparing a crosslinked polymer containing reversible exchange bonds; b, applying an external force to the crosslinked polymer to cause a certain strain; c, specific region of the crosslinked polymer is selectively heated while maintaining the strain. This method controls and utilizes the internal stresses which are commonly considered as unfavorable. The invention also provides a method for reading information in a polarized light field, wherein the crosslinked polymer treated by the method is transparent under natural light. The information therein can be read only under polarized light, and possesses concealment.

  本发明涉及一种控制材料应力分布的方法，包括以下步骤：a, 制备含有可逆交换键的交联聚合物；b, 对交联聚合物施加外力，使其产生一定的应变；c, 在保持应变的同时，选择性地加热交联聚合物的特定区域。这种方法可以控制和利用通常被认为不利的内应力。本发明还提供了一种在偏振光场中读取信息的方法，其中经该方法处理的交联聚合物在自然光下是透明的。其中的信息只能在偏振光下读取，具有隐蔽性。
• Novel chain extender useful in the manufacture of polyurethanes and the corresponding polyurethanes
  申请人：Lindsay Ian Chris

  公开号：US20060058493A1

  公开（公告）日：2006-03-16

  Novel chain extender that is a diamino-substituted heterocycle of formula I, and its use in the manufacture of polyurethanes (PUs), the PUs thus obtained, reactive compositions containing said chain extender, and processes for manufacturing PUs. Formula I is represented as follows:

  式 I 的二氨基取代杂环的新型扩链剂及其在制造聚氨酯 (PU) 中的用途、由此获得的聚氨酯、含有所述扩链剂的反应性组合物以及制造聚氨酯的工艺。式 I 表示如下