己二酸与1,4-二丁烷二胺聚合物

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 己二酸与1,4-二丁烷二胺聚合物
• 中文别名: 2H-1,3-噻嗪-2-丙酸,四氢-4,4-二甲基-
• 英文名称: Tetramethylene diammonium adipate
• 英文别名: 4-azaniumylbutylazanium;hexanedioate
• 化学式: C10H22N2O4
• 分子量: 234.29
• InChiKey: SHPVGWLRFPFLNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  127
• 氢给体数：
  4
• 氢受体数：
  6

文献信息

• NEAR-INFRARED ABSORBENT DISPERSION, AQUEOUS INK FOR INK JET RECORDING, AND AQUEOUS INK SET FOR INK JET RECORDING
  申请人：FUJI XEROX CO., LTD.

  公开号：US20180112092A1

  公开（公告）日：2018-04-26

  A near-infrared absorbent dispersion includes water, a near-infrared absorbent, and a resin dispersant, wherein a weight ratio of the near-infrared absorbent to the total weight of the near-infrared absorbent and the resin dispersant is more than 0.01 and less than 0.33.

  一种近红外吸收分散液包括水、近红外吸收剂和树脂分散剂，其中近红外吸收剂与近红外吸收剂和树脂分散剂总重量的重量比大于0.01且小于0.33。
• Preparation of high molecular polytetramethylene adipamide
  申请人：STAMICARBON B.V.

  公开号：EP0038094A2

  公开（公告）日：1981-10-21

  The invention concerns the preparation of white polyamides of high molecular weight based substantially on 1.4-diaminobutane and adipic acid. They are prepared by subjecting prepolymers, which contain less than 0.20 mgeq/g of cyclic (pyrrolidinyl) end groups and which have been prepared using an excess of the diamine. to aftercondensation in the solid phase in an atmosphere containing water vapour. The presence of water vapour is essential to prevent discoloration. The polyamides thus obtained can be used as engineering plastic or for the production of fibers.

  本发明用于制备主要基于 1.4-二氨基丁烷和己二酸的高分子量白色聚酰胺。制备方法是将环状（吡咯烷基）端基含量小于 0.20 mgeq/g 的预聚物和过量二胺在含有水蒸气的环境中进行固相缩合。水蒸气的存在对防止变色至关重要。由此获得的聚酰胺可用作工程塑料或生产纤维。
• Preparation of polytetramethylene adipamide
  申请人：STAMICARBON B.V.

  公开号：EP0039524A1

  公开（公告）日：1981-11-11

  A process for the preparation of white nylon 4,6 polyamide of high molecular weight from a tetramethylenediamine adipic acid prepolymer, formed under controlled conditions of temperature and water vapor pressure and wherein the plurality of cyclical end-groups in the prepolymer does not exceed 0.20 mg. equivalent per gram of prepolymer.

  一种利用己二酸四亚甲基二胺预聚物制备高分子量白色尼龙 4,6 聚酰胺的工艺，该预聚物是在温度和水蒸气压力受控的条件下形成的，其中预聚物中的多个环状端基不超过每克预聚物 0.20 毫克当量。
• Polyamide film and process for its production
  申请人：UNITIKA LTD.

  公开号：EP0158807A2

  公开（公告）日：1985-10-23

  A polyamide film made of a polyamide composition containing at least 60% by weight of polytetramethyleneadipamide or a copolymer polyamide containing at least 60% by weight of a polytetramethyleneadipamide component, which is at least monoaxially stretched at a stretching ratio of at least 1.5 times and has a crystallization characteristic value AT of from 30 to 60°C, where where Tm (melting point) is a melting peak temperature (°C) when the temperature is raised at a rate of 20°C/min by means of a differential scanning calorimater (DSC), and Tc (crystallization temperature) is a crystallization peak temperature (°C) when the temperature (20°C above the melting point) is lowered at a rate of 80°C/min by means of DSC.

  一种由聚酰胺组合物制成的聚酰胺薄膜，该聚酰胺组合物含有至少 60%（按重量计）的聚四亚甲基二酰胺或含有至少 60%（按重量计）的聚四亚甲基二酰胺组分的共聚聚酰胺，该聚酰胺薄膜至少以至少 1.5 倍的拉伸比进行单轴拉伸，其结晶特性值 AT 为 30 至 60°C，其中 其中 Tm（熔点）是通过差示扫描量热仪（DSC）以 20°C/min 的速度升温时的熔化峰温度（°C），Tc（结晶温度）是通过 DSC 以 80°C/min 的速度降温（高于熔点 20°C）时的结晶峰温度（°C）。
• Polyether-polyamide block copolymer and polyether prepolymer
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0293143A2

  公开（公告）日：1988-11-30

  A polyether-polyamide block copolymer having an ethylenically unsaturated group is represented by formula (I): and a polyether prepolymer thereof is represented by formula (II):     R¹ is H or an aliphatic hydrocarbon group, R² and R³ are each C2-6 aliphatic hydrocarbon, A is -OOC- or -OOC-NH-; B is C1-18 aliphatic hydrocarbon which may contain -NH-CO-NH, -NH-COO- or -NH-CO-; M is a hydrocarbon amide chain; Q is an ether or amino group, E is an aliphatic hydrocarbon ether or ester C1-12 group; V is an ethylenic hydrocarbon group; k=1-6, m=0-140, n=1-140, m+n=7-140; j, p, q=0 or 1, i=1-1000, r=5-500; and     Y is an isocyanate carbamoyl lactam, acid chloride or (oxy)carbonyl lactam group. The prepolymer can be made by polymerizing an alcohol as R¹ component and an unsaturated 1,2- epoxy compound and/or a cyclic ether in the presence of an ionic catalyst to form a block or random copolymer; a component reactant then replaces the hydroxyl groups. The prepolymer is linked to a polyamide moiety by anionic polymerisation of a lactam; the block copolymer can be of A-B, A-B-A or multi-block type. The drawings show NMR spectra of a prepolymer and copolymer. The copolymer is moldable at high temperature and has good heat stability.

  一种具有乙烯基不饱和基团的聚醚-聚酰胺嵌段共聚物由式（I）表示： 及其聚醚预聚物由式（II）表示： R¹ 是 H 或脂肪族烃基，R² 和 R³ 分别是 C2-6 脂肪族烃，A 是 -OOC- 或 -OOC-NH-；B 是 C1-18 脂肪族烃，可含有 -NH-CO-NH、-NH-COO- 或 -NH-CO-；M 是烃酰胺链；Q 是醚基或氨基，E 是 C1-12 脂肪烃醚或酯基；V 是乙烯烃基；k=1-6，m=0-140，n=1-140，m+n=7-140；j、p、q=0 或 1，i=1-1000，r=5-500；以及 Y 是异氰酸酯氨基甲酰基内酰胺、酸氯化物或（氧）羰基内酰胺基团。 预聚物的制造方法是：在离子催化剂存在下，将作为 R¹ 组分的醇和不饱和 1,2-环氧化合物和/或环醚聚合，形成嵌段或无规共聚物；然后用一种组分反应物取代羟基。预聚物通过内酰胺的阴离子聚合与聚酰胺分子相连；嵌段共聚物可以是 A-B、A-B-A 或多嵌段类型。 图中显示了预聚物和共聚物的核磁共振光谱。 共聚物可在高温下成型，并具有良好的热稳定性。