Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer
申请人:BASF SE
公开号:US10414938B2
公开(公告)日:2019-09-17
The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an α,β-ethylenically unsaturated C3-C8 carboxylic acid, glycidyl methacrylate or glycidyl acrylate, optionally an ethylenically unsaturated sulfonic acid and optionally an ethylenically unsaturated other monomer. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.
本发明涉及一种制备聚合物 P 的水性分散体的工艺,该工艺包括乙酸乙烯酯、丙烯酸酯单体(C1-C10 丙烯酸烷基酯或 C1-C10 甲基丙烯酸酯)、α,β-乙烯基不饱和 C3-C8 羧酸、甲基丙烯酸缩水甘油酯或丙烯酸缩水甘油酯、可选的乙烯基不饱和磺酸和可选的乙烯基不饱和其他单体的乳液聚合。此外,还公开了从该工艺中获得的含水聚合物分散体及其粉末形式。它们适用于含有上述形式之一的纸张涂层滑液。纸张或纸板在涂上这种纸张涂层滑剂后,会显示出良好的表面强度,这种强度表现为良好的耐干镐性能、良好的耐湿镐性能或良好的胶印测试结果。水性聚合物分散体或其粉末形式还可用作粘合剂。