(4-己基硫烷基苯基)硼酸 | 151588-39-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: (4-己基硫烷基苯基)硼酸
• 英文名称: 4-(hexylsulfanyl)phenylboronic acid
• 英文别名: Boronic acid, [4-(hexylthio)phenyl]-；(4-hexylsulfanylphenyl)boronic acid
• CAS: 151588-39-5
• 化学式: C₁₂H₁₉BO₂S
• 分子量: 238.159
• InChiKey: AFWKCJULYLAZEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.04
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  65.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (4-己基硫烷基苯基)硼酸 在 palladium diacetate 、 正丁基锂 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 8.0h， 生成
  参考文献：
  名称：

  Synthesis and fluorescence enhancement of oligophenylene-substituted calix[4]arene assembliesElectronic supplementary information (ESI) available: experimental procedures and spectral data of all new compounds. See http://www.rsc.org/suppdata/cc/b2/b210493h/

  摘要：

  已经通过收敛方法合成了替代四苯基的杯[4]芳烃组装体，其中含有多达三个苯基单元，并使用铃木交叉偶联法对其进行了合成，同时研究了其光学特性并与相应的单体进行了比较。

  DOI：

  10.1039/b210493h
• 作为产物：
  描述：

  1-bromo-4-hexylthiobenzene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 (4-己基硫烷基苯基)硼酸
  参考文献：
  名称：

  Synthesis and fluorescence enhancement of oligophenylene-substituted calix[4]arene assembliesElectronic supplementary information (ESI) available: experimental procedures and spectral data of all new compounds. See http://www.rsc.org/suppdata/cc/b2/b210493h/

  摘要：

  已经通过收敛方法合成了替代四苯基的杯[4]芳烃组装体，其中含有多达三个苯基单元，并使用铃木交叉偶联法对其进行了合成，同时研究了其光学特性并与相应的单体进行了比较。

  DOI：

  10.1039/b210493h

文献信息

• Syntheses, Phase Behavior, Supramolecular Chirality, and Field-Effect Carrier Mobility of Asymmetrically End-Capped Mesogenic Oligothiophenes
  作者：Qingwei Meng、Xiao-Hua Sun、Zhengyu Lu、Ping-Fang Xia、Zehua Shi、Dongzhong Chen、Man Shing Wong、Salem Wakim、Jianping Lu、Jean-Marc Baribeau、Ye Tao

  DOI：10.1002/chem.200802470

  日期：2009.3.23

  Supramolecular chirality and liquid crystalline OFET: Achiral end‐capped oligothiophenes can be tuned to exhibit supramolecular chirality with unique striped textures showing distinct circular dichroism signals as well as a highly ordered SmE phase that leads to high hole carrier mobility.

  超分子手性和液晶OFET：可以调节手性末端封端的寡噻吩，表现出超分子手性，具有独特的条纹结构，显示出独特的圆二色性信号以及高度有序的SmE相，从而导致高的空穴载流子迁移率。
• NOVEL ANTIBACTERIAL AGENTS FOR THE TREATMENT OF GRAM POSITIVE INFECTIONS
  申请人：MetCalf, III Chester A.

  公开号：US20100184649A1

  公开（公告）日：2010-07-22

  The present invention relates to novel lipopeptide compounds, pharmaceutical compositions of these compounds and methods of using these compounds as antibacterial compounds. The compounds of the invention are particularly useful against a variety of bacteria, including resistant strains. The compounds are useful as antibacterial agents against Clostridium difficile.

  本发明涉及一种新型的脂肽化合物，这些化合物的药物组成和使用这些化合物作为抗菌化合物的方法。本发明的化合物尤其适用于各种细菌，包括耐药菌株。这些化合物可用作抗Clostridium difficile的抗菌剂。
• Antibacterial agents for the treatment of gram positive infections
  申请人：Metcalf, III Chester A.

  公开号：US08507647B2

  公开（公告）日：2013-08-13

  The present invention relates to novel lipopeptide compounds, pharmaceutical compositions of these compounds and methods of using these compounds as antibacterial compounds. The compounds of the invention are particularly useful against a variety of bacteria, including resistant strains. The compounds are useful as antibacterial agents against Clostridium difficile.

  本发明涉及新型脂肽化合物，这些化合物的制药组合物和使用这些化合物作为抗菌化合物的方法。本发明的化合物特别对多种细菌，包括耐药菌株，具有显著的抗菌作用。这些化合物对Clostridium difficile的抗菌作用尤其有效。
• Facile Synthesis of Oligophenylene-Substituted Calix[4]arenes and Their Enhanced Binding Properties
  作者：Man Shing Wong、Ping Fang Xia、Xiao Ling Zhang、Pik Kwan Lo、Yuen-Kit Cheng、Kai-Tai Yeung、Xiliang Guo、Shaomin Shuang

  DOI：10.1021/jo048545p

  日期：2005.4.1

  A facile and efficient protocol for the synthesis of oligophenylene OPP(n)-substituted calix[4]arenes (with n up to 4) via iodo-substituted oligoarylcalix[4]arenes has been developed. The cooperation effect of the proximate fluoroionophores in hexylsulfanyl end-capped OPP(n)-substituted calix[4]arene assemblies leads to metal ion binding enhancement.
• Two-dimensional oligoarylenes: synthesis and structure–properties relationships
  作者：Zhong Hui Li、Man Shing Wong、Ye Tao

  DOI：10.1016/j.tet.2005.03.077

  日期：2005.5

  A novel-series of two-dimensional pi-conjugated oligoarylenes has been synthesized by a divergent approach using Pd-catalysed Suzuki cross-coupling of tetraiodophenylbenzene and arylboronic acid as a key step. It has been shown that the 'X-branched' structure can provide a useful platform to construct amorphous molecular materials as it can enhance the morphological and thermal stability as well as to facilitate solubility and processibility of a material when compared to those of the corresponding linear oligomers. The diphenylamino end-capped two-dimensional oligoarylenes were found useful as a hole transporting/emitting layer for light emitting applications. (c) 2005 Elsevier Ltd. All rights reserved.