(9ci)-6-甲基-1-环己烯-1-羰酰氯 | 72622-71-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 中文名称: (9ci)-6-甲基-1-环己烯-1-羰酰氯
• 英文名称: 6-methyl-cyclohex-1-enecarbonyl chloride
• 英文别名: 6-Methyl-cyclohex-1-encarbonylchlorid；6-Methylcyclohexene-1-carbonyl chloride
• CAS: 72622-71-0
• 化学式: C₈H₁₁ClO
• 分子量: 158.628
• InChiKey: YZSPCUFGCNOYEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2916209090

反应信息

• 作为反应物：
  描述：

  (9ci)-6-甲基-1-环己烯-1-羰酰氯 在 盐酸 作用下， 以 1,4-二氧六环 、 苯 为溶剂， 反应 0.25h， 生成 (1R,4aR,10aS)-1-Methyl-1,3,4,4a,5,10a-hexahydro-2H-indeno[1,2-b]indol-10-one
  参考文献：
  名称：

  Intramolecular, ring closure of α,β-unsaturated 3-acylindoles

  摘要：

  DOI：

  10.1016/s0040-4039(00)96373-1
• 作为产物：
  描述：

  2-甲基环己烷氰醇 在 氯化亚砜 、 二氢四氧代磷酸 、 三氯氧磷 作用下， 以 吡啶 、 水 为溶剂， 生成 (9ci)-6-甲基-1-环己烯-1-羰酰氯
  参考文献：
  名称：

  Synthesis of All Eight Stereoisomers of the Germination Stimulant Sorgolactone

  摘要：

  The naturally occurring sesquiterpene sorgolactone (2) belongs to the class of "strigolactones", which are highly potent germination stimulants for seeds of the parasitic weeds Striga and Orobanche. The aim of the present work was to synthesize all eight stereoisomers of sorgolactone and to evaluate their activities in the stimulation of germination of S. hermontica and O. crenata. Two racemic diastereomers of the ABC part of sorgolactone, rac.10a and rac.10b respectively, were prepared and coupled with homochiral latent D-ring synthons 12 and ent.12. In this manner, four mixtures of two separable (protected) sorgolactone diastereomers were obtained. Deprotection gave all eight target compounds as single isomers. Bioassays revealed that only those isomers possessing the same stereochemistry as natural sorgolactone at two adjacent chiral centers exhibit high biological activities.

  DOI：

  10.1021/jo9718408

文献信息

• The first total synthesis of the naturally occurring germination stimulant sorgolactone
  作者：Yukihiro Sugimoto、Suzanne C.M. Wigchert、Jan Willem J.F. Thuring、Binne Zwanenburg

  DOI：10.1016/s0040-4039(97)00304-3

  日期：1997.3

  The first total synthesis of sorgolactone is reported, which confirms the proposed structure of the naturally occurring germination stimulant.

  报道了高粱内酯的第一个全合成，证实了自然萌发刺激物的拟议结构。
• 1-Cycloalkenyltetrazolinones
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0728750A1

  公开（公告）日：1996-08-28

  1-Cycloalkenyltetrazolinone derivatives of the following formulae (I) and (II): wherein R1represents cycloalkenyl which may optionally be substituted by halogen or C1-4 alkyl, or bicycloalkenyl which may optionally be substituted by halogen or C1-4 alkyl, and R2 and R3each independently represents alkyl, cycloalkyl, phenyl, substituted phenyl (said substituent being selected from nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and alkylthio), alkenyl or alkynyl, or R2 and R3may optionally form, together with N-atom to which they are bonded, a 5- or 6-membered heterocyclic ring, said heterocyclic ring may optionally be benzo-condensed and/or be substituted by C1-4 alkyl. The compounds of formula (I) exhibit an excellent herbicidal activity and the compounds of formula (II) are useful as intermediate compounds in the production process of the compounds of the formula (I).

  下式(I)和(II)的 1-环烯基四唑啉酮衍生物： 其中 R1 代表可任选被卤素或 C1-4 烷基取代的环烯基，或可任选被卤素或 C1-4 烷基取代的双环烯基，以及 R2 和 R3 各自独立地代表烷基、环烷基、苯基、取代苯基（所述取代基选自硝基、氰基、卤素、烷基、卤代烷基、烷氧基、卤代烷氧基和烷硫基）、烯基或炔基、 或 R2 和 R3 可选择与它们所结合的 N 原子一起形成一个 5 或 6 元杂环，所述杂环可选择为苯并缩合和/或被 C1-4 烷基取代。 式（I）化合物具有优异的除草活性，式（II）化合物可作为式（I）化合物生产过程中的中间化合物。
• Silicon in synthesis. 8. Vinyltrimethylsilane, a convenient ethylene equivalent for the synthesis of vinyl arylsulfides, vinyl arylsulfoxides, thiosilylketene acetals, and fused cyclopentenones
  作者：Frank Cooke、Rudi Moerck、James Schwindeman、Philip Magnus

  DOI：10.1021/jo01294a026

  日期：1980.3
• 117. The production of polycyclic aromatic types through the cyclodehydration of unsaturated ketones
  作者：W. S. Rapson、R. G. Shuttleworth

  DOI：10.1039/jr9400000636

  日期：——
• Grundmann; Loew, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1938, vol. 256, p. 141,151
  作者：Grundmann、Loew

  DOI：——

  日期：——