Silver halide photographic elements containing 2-equivalent 5-pyrazolone magenta couplers
申请人:MINNESOTA MINING AND MANUFACTURING COMPANY
公开号:EP0735417A1
公开(公告)日:1996-10-02
Silver halide photographic element comprising a support and at least one silver halide emulsion layer having associated a 2-equivalent 5-pyrazolone magenta coupler represented by the formula:
wherein
a represents an integer from 0 to 3,
b represents an integer from 0 to 2,
R1 and R2 are each individually hydrogen, alkyl, alkoxy, halogen, aryl, aryloxy, acylamino, sulfonamido, sulfamoyl, carbamoyl, arylsulfonyl, aryloxycarbonyl, alkoxycarbonyl, alkoxysulfonyl, aryloxysulfonyl, alkylureido, arylureido, nitro, cyano, hydroxyl or carboxy group,
R3 is halogen atom, alkyl or aryl group,
X is a direct link or a linking group,
Ball is a ballasting group which renders a group to which is attached non-diffusible in photographic coatings, and
the sum of the sigma values of R1, R3 and X-Ball is less than 1.3.
卤化银感光元件,包括一个支撑体和至少一个卤化银乳剂层,该层上附有由式表示的 2-当量 5-吡唑酮品红耦合剂:
其中
a 代表 0 至 3 的整数、
b 代表 0 至 2 的整数、
R1 和 R2 分别是氢、烷基、烷氧基、卤素、芳基、芳氧基、酰氨基、磺酰胺基、氨基磺酰基、氨基甲酰基、芳基磺酰基、芳氧基羰基、烷氧基羰基、烷氧基磺酰基、芳氧基磺酰基、烷基脲基、芳基脲基、硝基、氰基、羟基或羧基、
R3 是卤素原子、烷基或芳基、
X 是直接连接或连接基团、
Ball 是压载基团,它使所连接的基团在感光涂层中不易扩散,以及
R1、R3 和 X-Ball 的西格玛值之和小于 1.3。