异亚丙基二(对亚苯基碳酸烯丙基酯) | 84000-75-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 异亚丙基二(对亚苯基碳酸烯丙基酯)
• 英文名称: 2,2-bis-(4-allyloxycarbonyloxy-phenyl)-propane
• 英文别名: 2,2-Bis-(4-allyloxycarbonyloxy-phenyl)-propan；diallyl isopropylidenebis(p-phenylenecarbonate)；Carbonic acid, (1-methylethylidene)di-4,1-phenylene di-2-propenyl ester；[4-[2-(4-prop-2-enoxycarbonyloxyphenyl)propan-2-yl]phenyl] prop-2-enyl carbonate
• CAS: 84000-75-9
• 化学式: C₂₃H₂₄O₆
• 分子量: 396.44
• InChiKey: SZYLPVRUCVUHGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  29
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2920909090

反应信息

• 作为产物：
  描述：

  双酚A 、 氯甲酸烯丙酯 在 sodium hydroxide 、 丙酮 作用下， 生成 异亚丙基二(对亚苯基碳酸烯丙基酯)
  参考文献：
  名称：

  Di(alkenyl carbonato) aromatic compounds and polymers thereof

  摘要：

  公开号：

  US02455653A1

文献信息

• High refractive index monomers, compositions and uses thereof
  申请人：Craciun Liliana

  公开号：US20080200582A1

  公开（公告）日：2008-08-21

  The invention relates to novel sulfur-containing (meth)acrylic monomers and compositions thereof characterized by a high refractive index, for optical and industrial applications. The invention also relates to a method for preparing high refractive index polymeric materials and more specifically to a method for formation of ultraviolet cast optical lenses and compositions thereof comprising the sulfur-containing (meth)acrylic monomers.

  本发明涉及一种新型含硫（甲基）丙烯酸单体及其组合物，其具有高折射率，适用于光学和工业应用。本发明还涉及一种制备高折射率聚合材料的方法，更具体地涉及一种形成紫外线铸造光学透镜的方法和组合物，其中包括含硫（甲基）丙烯酸单体。
• Inhibited monomeric compositions of polyol(allyl carbonate), method for their preparation and method for their polymerization
  申请人：PPG INDUSTRIES, INC.

  公开号：EP0093550A1

  公开（公告）日：1983-11-09

  A composition comprising monomeric polyol(allyl carbonate) and a viscosity stabilizing amount of a polymerization inhibitor chosen from the group consisting of dihydroxy atomatics, dioxy aromatics, derivatives thereof, and mixtures thereof in the composition. A method of inhibiting the thermally induced thickening of compositions containing monomeric polyol(allyl carbonate) comprising providing a viscosity stabilizing amount of a polymerization inhibitor chosen from the group consisting of dihydroxy aromatics, dioxy aromatics, derivatives thereof, and mixtures thereof in the composition. A method of polymerizing a composition of polyol(allyl carbonate) monomer comprising providing a viscosity stabilizing amount of a polymerization inhibitor chosen from the group consisting of dihydroxy aromatics, dioxy aromatics, derivatives thereof, and mixtures thereof in the compositions whereby to inhibit the thermally induced thickening thereof, and thereafter, without removing the polymerization inhibitor, adding a free radical polymerization initiator to the composition and heating the composition whereby to polymerize the composition.

  一种组合物，包含单体多元醇（碳酸烯丙酯）和一种稳定粘度的聚合抑制剂，该聚合抑制剂选自由二羟基原子化合物、二羟基芳香族化合物、其衍生物及其混合物组成的组。 一种抑制含有单体多元醇（碳酸烯丙酯）的组合物的热诱导增稠的方法，包括在组合物中加入一定量的粘度稳定剂，该粘度稳定剂选自由二羟基芳烃、二羟基芳烃、其衍生物和其混合物组成的组。 一种使多元醇（碳酸烯丙酯）单体组合物聚合的方法，包括在组合物中提供一定量的稳定粘度的聚合抑制剂，该抑制剂选自二羟基芳烃、二羟基芳烃、其衍生物和其混合物组成的组，从而抑制热引起的增稠，然后，在不去除聚合抑制剂的情况下，向组合物中加入自由基聚合引发剂，并加热组合物，从而使组合物聚合。
• Use of sulfur-containing acid phosphoric ester as internal release agent
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0553801A1

  公开（公告）日：1993-08-04

  An internal release agent comprises a sulfur-containing acid phosphoric esters selected from the group consisting of thiophosphoric acid esters and dithiophosphoric acid esters of the formula, where X and Y are independently selected from the group consisting of an oxygen atom and a sulfur atom, at least one of X and Y is a sulfur atom, and R₁ and R₂ are independently alkyl groups.

  内脱模剂包括从硫代磷酸酯和二硫代磷酸酯组成的组中选出的含硫酸性磷酸酯，其式为 其中，X 和 Y 独立地选自由氧原子和硫原子组成的组，X 和 Y 中至少有一个是硫原子，R₁ 和 R₂ 独立地为烷基。
• Polymerizable polyol (allyl carbonate) compositions
  申请人：——

  公开号：US20030173551A1

  公开（公告）日：2003-09-18

  A polymerizable composition is described, which composition comprises a major amount of a polyol(allyl carbonate) monomer, e.g., diethylene glycol bis(allyl carbonate) monomer, and a minor amount of a radically polymerizable second monomer represented by the general formula, 1 wherein R 2 is a polyvalent linking group that is free of urethane linkages, e.g., R 2 may be a residue of a polyisocyanate, such as isophorone diisocyanate; R 3 is a residue of a material having a single hydroxy group and at least one allyl group, R 3 being free of urethane linkages, e.g., R 3 may be a residue of a poly(alkylene glycol) allyl ether, such as poly(1,2-propylene glycol) allyl ether; and j is a number from 2 to 4. The second monomer may also be present in the composition in an amount at least sufficient such that a polymerizate, e.g., a plus ophthalmic lens, obtained from the composition is substantially free of tinting defects, e.g., ferns and/or moons.

  描述了一种可聚合的组合物，该组合物包括主要量的多元醇（碳酸烯丙酯）单体，如二甘醇双（碳酸烯丙酯）单体，和少量的由通式表示的可辐射聚合的第二单体、 1 其中 R 2 是不含氨基甲酸酯连接的多价连接基团，如 R 2 可以是多异氰酸酯（如异佛尔酮二异氰酸酯）的残留物；R 3 是具有一个羟基和至少一个烯丙基的材料的残基，R 3 不含氨基甲酸乙酯连接，例如 R 3 第二单体还可以以至少足够的量存在于组合物中，从而使从组合物中获得的聚合物（例如，外加眼科镜片）基本上不存在着色缺陷，例如，蕨类和/或月亮。
• High refractive index polymerizable composition
  申请人：——

  公开号：US20040021133A1

  公开（公告）日：2004-02-05

  The present invention is directed to a polymerizable composition including a polymerizable monomer component and a nanoparticle material, having a refractive index of from 1.595 to 1.695. When at least partially cured, the polymerizable composition is especially useful for ophthalmic applications.

  本发明涉及一种可聚合组合物，包括可聚合单体成分和纳米颗粒材料，其折射率为 1.595 至 1.695。当至少部分固化时，该可聚合组合物尤其适用于眼科应用。