Process for the selective hydrogenation of triglyceride oils and products so obtained
申请人:UNILEVER N.V.
公开号:EP0021528A1
公开(公告)日:1981-01-07
Triglyceride oils, which contain besides fatty acids having two double bonds, fatty acids having more than two double bonds, are hydrogenated using palladium, platinum, rhodium and/or iridium as a catalyst, the catalyst being treated with dry ammonia. The hydrogenation is carried out at a temperature of at least 100°C. The hydrogenation progresses in a particularly selective manner. On using, for instance, soyabean oil, which contains about 55 % of linoleic acid and 7% of linolenic acid, the amount of linolenic acid can be reduced to 2%, whereby more than 45% of linoleic acid is retained in the hydrogenated product. In case the catalyst is not treated, said amount is only about 35%.
三甘油酯油除了含有两个双键的脂肪酸外,还含有两个以上双键的脂肪酸,使用钯、铂、铑和/或铱作为催化剂进行氢化,催化剂用干氨处理。氢化在至少 100°C 的温度下进行。氢化以特别选择性的方式进行。例如,在使用含亚油酸约 55% 和亚麻酸 7% 的大豆油时,亚麻酸的含量可降至 2%,从而在氢化产品中保留了 45% 以上的亚油酸。如果不对催化剂进行处理,上述亚油酸含量仅为 35%左右。