1,1'-氧基二(3-苯氧基苯) | 748-30-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,1'-氧基二(3-苯氧基苯)
• 英文名称: bis(m-phenoxyphenyl)ether
• 英文别名: -benzol；Bis-<3-phenoxy-phenyl>-ether；Phenoxybi-(m-phenoxylen)-benzol；Bis-(3-phenoxy-phenyl)-ether；Bis(m-phenoxyphenyl)-ether；Bis(m-phenoxyphenyl)aether；1-phenoxy-3-(3-phenoxyphenoxy)benzene
• CAS: 748-30-1
• 化学式: C₂₄H₁₈O₃
• 分子量: 354.405
• InChiKey: MVCITNPWSJQCBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,1'-氧基二(3-苯氧基苯) 在 三乙基硅烷 、 potassium tert-butylate 作用下， 以 均三甲苯 为溶剂， 反应 20.0h， 生成 间苯二酚 、 苯 、 苯酚
  参考文献：
  名称：

  [EN] SILYLATION OF AROMATIC HETEROCYCLES BY EARTH ABUNDANT TRANSITION-METAL-FREE CATALYSTS
  [FR] SILYLATION D'HÉTÉROCYCLES AROMATIQUES PAR DES CATALYSEURS ABONDANTS SUR TERRE, EXEMPTS DE MÉTAUX DE TRANSITION

  摘要：

  公开号：

  WO2016022624A9
• 作为产物：
  描述：

  3-苯氧基苯胺 生成 1,1'-氧基二(3-苯氧基苯)
  参考文献：
  名称：

  Preparation and Infrared Absorption Spectra of Some Phenyl Ethers¹

  摘要：

  DOI：

  10.1021/jo01079a029

文献信息

• Dicarboxylic diester, process for producing the same, and refrigerating machine lubricating oil comprising the ester
  申请人：Kawahara Yasuyuki

  公开号：US20050038283A1

  公开（公告）日：2005-02-17

  A diester represented by the formula wherein A represents a cyclohexane ring, cyclohexene ring or benzene ring, X is H or methyl group, R X and R Y are the same or different and each is C3-C18 branched-chain alkyl group, C1-C18 straight-chain alkyl group, C2-C18 straight-chain alkenyl or C3-C18 cycloalkyl, provided that when A is a benzene ring, R X and R Y are different from each other and —COOR X and —COOR Y are attached to two adjacent carbon atoms of the benzene ring, and having the following properties: 1) a total acid number of 0.05 mgKOH/g or less, 2) a sulfated ash content of 10 ppm or less, 3) a sulfur content of 20 ppm or less, 4) a phosphorus content of 20 ppm or less, 5) a peroxide value of 1.0 meq/kg or less, 6) a carbonyl value of 10 or less; 7) a volume resistivity of 1×10 11 Ω·cm or more, 8) a hydroxyl value of 3 mgKOH/g or less, and 9) a water content of 100 ppm or less, a process for preparing the same and a refrigerator lubricating oil comprising the diester.

  由以下公式表示的二酯，其中A代表环己烷环、环己烯环或苯环，X为H或甲基基团，RX和RY相同或不同，且每个均为C3-C18支链烷基基团、C1-C18直链烷基基团、C2-C18直链烯基或C3-C18环烷基，前提是当A为苯环时，RX和RY彼此不同，且—COORX和—COORY连接到苯环的两个相邻碳原子，并具有以下特性：1）总酸值为0.05 mgKOH/g或更低，2）硫酸盐灰分含量为10 ppm或更低，3）硫含量为20 ppm或更低，4）磷含量为20 ppm或更低，5）过氧化值为1.0 meq/kg或更低，6）羰基值为10或更低；7）体积电阻率为1×1011Ω·cm或更高，8）羟值为3 mgKOH/g或更低，9）水含量为100 ppm或更低，制备该二酯的方法以及包含该二酯的制冷剂润滑油。
• [EN] FLAME RETARDANT HALOGENATED PHENYL ETHERS<br/>[FR] ÉTHERS DE PHÉNYLE HALOGÉNÉS IGNIFUGES
  申请人：CHEMTURA CORP

  公开号：WO2011090631A1

  公开（公告）日：2011-07-28

  A halogenated non-polymeric phenyl ether is described having the general formula (I): wherein each X is independently Cl or Br, n is an integer of 1 or 2, each m is independently an integer of 1 to 5 and each p is independently an integer of 1 to 4, provided that, when X is Cl, the total amount halogen in the ether is from about 50 to about 65 wt% and when, X is Br, the total amount halogen in the ether is from at least 70 wt % to about 79 wt%.

  描述了具有通式（I）的卤代非聚合物苯醚，其中每个X独立地是Cl或Br，n是1或2的整数，每个m独立地是1到5的整数，每个p独立地是1到4的整数，前提是，当X为Cl时，醚中卤素的总量约为50至65重量％，当X为Br时，醚中卤素的总量至少为70重量％至约79重量％。
• FLAME RETARDANT HALOGENATED PHENYL ETHERS
  申请人：Timberlake Larry D.

  公开号：US20110184107A1

  公开（公告）日：2011-07-28

  A halogenated non-polymeric phenyl ether is described having the general formula (I): wherein each X is independently Cl or Br, n is an integer of 1 or 2, each m is independently an integer of 1 to 5 and each p is independently an integer of 1 to 4, provided that, when X is Cl, the total amount halogen in the ether is from about 50 to about 65 wt % and when, X is Br, the total amount halogen in the ether is from at least 70 wt % to about 79 wt %.

  描述了一种卤代非聚合苯醚，其一般式为(I)：其中每个X独立地为Cl或Br，n为1或2的整数，每个m独立地为1至5的整数，每个p独立地为1至4的整数，但当X为Cl时，醚中卤素的总量约为50至65重量％，当X为Br时，醚中卤素的总量至少为70重量％至约79重量％。
• Lubricant base oil for power transmission
  申请人：NEW JAPAN CHEMICAL CO., LTD.

  公开号：US10947472B2

  公开（公告）日：2021-03-16

  An object of the present invention is to provide a lubricant base oil for power transmission (in particular, a lubricant base oil for traction drives) having a high traction coefficient and a high flash point. The present invention relates to a lubricant base oil for power transmission comprising an alicyclic dicarboxylic acid diester compound represented by general formula (1): wherein R1 to R5 are the same or different, and each represents hydrogen or linear or branched C1-4 alkyl, and two R1, two R2, two R3, two R4, and two R5 may respectively be the same or different; and ring A is wherein R represents C1-3 alkyl, and n represents 0, 1, or 2; when n represents 2, R may be the same or different.

  本发明的目的是提供一种用于动力传输（特别是牵引传动）具有高牵引系数和高闪点的润滑基础油。本发明涉及一种用于动力传输的润滑基础油，包括一个由通式（1）表示的脂环族二羧酸二酯化合物：其中R1至R5相同或不同，每个代表氢或线性或支链C1-4烷基，两个R1、两个R2、两个R3、两个R4和两个R5可以分别相同或不同；环A为：其中R表示C1-3烷基，n表示0、1或2；当n表示2时，R可以相同或不同。
• FLAME RETARDANT HALOGENATED PHENYL ETHER BLENDS
  申请人：Timberlake Larry D.

  公开号：US20100160516A1

  公开（公告）日：2010-06-24

  A flame retardant blend comprises at least first and second halogenated non-polymeric phenyl ethers having the general formula (I): wherein each X is independently Cl or Br, each m is independently an integer of 1 to 5, each p is independently an integer of 1 to 4, n is an integer of 1 to 5 and wherein the values of n for the first and second ethers are different

  一种阻燃混合物包括至少第一和第二卤代非聚合苯醚，其具有通式（I）：其中每个X独立地为Cl或Br，每个m独立地为1至5的整数，每个p独立地为1至4的整数，n为1至5的整数，并且第一和第二醚的n值不同。

表征谱图