1,1,2,2-四氟-2-[(1,1,2,2-四氟-3-丁烯基)氧基]-乙烷磺酰氟 | 84271-38-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 磺酰卤
• 中文名称: 1,1,2,2-四氟-2-[(1,1,2,2-四氟-3-丁烯基)氧基]-乙烷磺酰氟
• 英文名称: 3-oxa-1,1,2,2,4,4,5,5-octafluoro-6-heptene sulfonyl fluoride
• 英文别名: 1,1,2,2-Tetrafluoro-2-[(1,1,2,2-tetrafluoro-3-butenyl)oxy]-ethanesulfonyl fluoride；1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluorobut-3-enoxy)ethanesulfonyl fluoride
• CAS: 84271-38-5
• 化学式: C₆H₃F₉O₃S
• 分子量: 326.14
• InChiKey: DHOWBDGXIQWUSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,1,2,2-四氟-2-[(1,1,2,2-四氟-3-丁烯基)氧基]-乙烷磺酰氟 在 sodium tetrahydroborate 、 硫酸 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 4.5h， 生成
  参考文献：
  名称：

  [EN] PARTIALLY FLUORINATED SULFINIC ACID MONOMERS AND THEIR SALTS
  [FR] MONOMÈRES ACIDES SULFINIQUES PARTIELLEMENT FLUORÉS ET LEURS SELS

  摘要：

  公开号：

  WO2012082551A3
• 作为产物：
  描述：

  1,1,2,2-四氟-4-碘- 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 反应 4.0h， 生成 1,1,2,2-四氟-2-[(1,1,2,2-四氟-3-丁烯基)氧基]-乙烷磺酰氟
  参考文献：
  名称：

  [EN] PARTIALLY FLUORINATED SULFINIC ACID MONOMERS AND THEIR SALTS
  [FR] MONOMÈRES ACIDES SULFINIQUES PARTIELLEMENT FLUORÉS ET LEURS SELS

  摘要：

  公开号：

  WO2012082551A3

文献信息

• Fluoroalkanesulfonyl azide monomers and copolymers thereof
  申请人：——

  公开号：US20020049343A1

  公开（公告）日：2002-04-25

  Fluorinated olefins and fluorinated vinyl ethers, each having sulfonyl azide groups, are useful monomers in preparing fluoropolymers having functional side groups. Such functional side groups are useful in curing the fluoropolymers and also for enhancing the adhesion of the fluoropolymers to other substrates.

  含有磺酰叠氮基团的氟代烯烃和氟代乙烯醚是制备具有功能侧基的氟聚合物的有用单体。这些功能侧基对于固化氟聚合物和增强氟聚合物与其他基材的粘附性都很有用。
• Fluorinated ionic polymers
  申请人：——

  公开号：US20040039142A1

  公开（公告）日：2004-02-26

  Described herein are monomers of the formula CH 2 ═CH(CF 2 ) 2n OCF 2 CF 2 SO 2 N − (M + )SO 2 R f where n≧1 and M + =H + or an alkali metal cation, and R f is C1-4 perfluoroalkyl optionally substituted by one or more ether oxygens, and polymers made therefrom.

  本文描述了以下化合物的单体公式：CH2═CH(CF2)2nOCF2CF2SO2N−(M+)SO2Rf，其中n≧1，M+=H+或碱金属阳离子，Rf是C1-4全氟烷基，可选地带有一个或多个醚氧基，以及由此制备的聚合物。
• PARTIALLY FLUORINATED SULFINIC ACID MONOMERS AND THEIR SALTS
  申请人：Qiu Zai-Ming

  公开号：US20130253220A1

  公开（公告）日：2013-09-26

  Described herein is a composition according to formula I or its precursor, formula II: CX 1 X 3 ═CX 2 —(R 1 ) p —CZ1Z2-SO 2 M (I) wherein X 1 , X 2 , and X 3 are independently selected from H, F, Cl, Br, I, CF 3 and CH 3 , and wherein at least one of X 1 , X 2 , or X 3 is a H; R 1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF 3 , and a perfluoroalkyl group; p is 0 or 1; and M is a cation; and CX 4 X 1 X 3 —CX 5 X 2 —(R 1 ) p —CZ1Z2-SO 2 M (II) wherein X 1 , X 2 , and X 3 are independently selected from H, F, Cl, Br, I, CF 3 and CH 3 , wherein at least one of X 1 , X 2 , or X 3 is a H, and X 4 and X 5 are independently selected from H, F, Cl, Br and I; R 1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF 3 , and a perfluoroalkyl group, p is 0 or 1; and M is selected from F, and a cation.

  本文描述了一个由公式I或其前体公式II组成的化合物：CX1X3═CX2—(R1)p—CZ1Z2-SO2M（I），其中X1、X2和X3独立地选择自H、F、Cl、Br、I、CF3和CH3，且其中至少一个是H；R1是连接基团；Z1和Z2独立地选择自F、Cl、Br、I、CF3和全氟烷基；p为0或1；M为阳离子；以及CX4X1X3—CX5X2—(R1)p—CZ1Z2-SO2M（II），其中X1、X2和X3独立地选择自H、F、Cl、Br、I、CF3和CH3，其中至少一个是H，X4和X5独立地选择自H、F、Cl、Br和I；R1是连接基团；Z1和Z2独立地选择自F、Cl、Br、I、CF3和全氟烷基，p为0或1；M选择自F和阳离子。
• Partially fluorinated sulfinic acid monomers and their salts
  申请人：Qiu Zai-Ming

  公开号：US09187416B2

  公开（公告）日：2015-11-17

  Described herein is a composition according to formula I or its precursor, formula II: CX1X3═CX2—(R1)p—CZ1 Z2-SO2M (I) wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3 and CH3, and wherein at least one of X1, X2, or X3 is a H; R1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF3, and a perfluoroalkyl group; p is 0 or 1; and M is a cation; and CX4X1X3—CX5X2—(R1)p—CZ1Z2-SO2M (II) wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3 and CH3, wherein at least one of X1, X2, or X3 is a H, and X4 and X5 are independently selected from H, F, Cl, Br and I; R1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF3, and a perfluoroalkyl group, p is 0 or 1; and M is selected from F, and a cation.

  本文描述了一种按照公式I或其前体公式II的组合物：CX1X3═CX2—(R1)p—CZ1Z2-SO2M（I），其中X1、X2和X3独立地选自H、F、Cl、Br、I、CF3和CH3，且其中至少一个为H；R1是连接基团；Z1和Z2独立地选自F、Cl、Br、I、CF3和全氟烷基；p为0或1；M是阳离子；以及CX4X1X3—CX5X2—(R1)p—CZ1Z2-SO2M（II），其中X1、X2和X3独立地选自H、F、Cl、Br、I、CF3和CH3，其中至少一个为H，X4和X5独立地选自H、F、Cl、Br和I；R1是连接基团；Z1和Z2独立地选自F、Cl、Br、I、CF3和全氟烷基，p为0或1；M选自F和阳离子。
• Fluorinated alkyl ether-containing ethylenes, precursors thereto, and copolymers thereof with tetrafluoroethylene
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0124378A1

  公开（公告）日：1984-11-07

  Copolymers of TFE with fluorinated alkyl ethylenes which contain ether linkages are provided. The copolymers are thermally stable and useful as electrical insulation. Some of the copolymers contain functional groups and are hydrolyzable to fluorinated copolymers which contain acid functional groups. Novel monomers and precursors thereof are also provided.

  提供了含有醚键的 TFE 与氟化烷基乙烯的共聚物。这种共聚物具有热稳定性，可用作电绝缘材料。其中一些共聚物含有官能团，可水解为含酸官能团的氟化共聚物。此外，还提供了新型单体及其前体。