1,2,3,4-丁烷四羧酸-1,2,3-三(2,2,6,6-四甲基-4-哌啶基)-4-十三烷酯 | 84696-71-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1,2,3,4-丁烷四羧酸-1,2,3-三(2,2,6,6-四甲基-4-哌啶基)-4-十三烷酯
• 英文名称: 2-O,3-O,4-O-tris(2,2,6,6-tetramethylpiperidin-4-yl) 1-O-tridecyl butane-1,2,3,4-tetracarboxylate
• CAS: 84696-71-9
• 化学式: C₄₈H₈₇N₃O₈
• 分子量: 834.2
• InChiKey: AOQPXBOBUMGDLG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  59
• 可旋转键数：
  26
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  141
• 氢给体数：
  3
• 氢受体数：
  11

文献信息

• Crystalline polyolefin composition
  申请人：Chisso Corporation

  公开号：EP0416321A1

  公开（公告）日：1991-03-13

  A crystalline polyolefin composition which provides molded articles having improved stiffness characteristics is disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I): wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar1 and Ar2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium. A crystalline polyolefin composition which provides molded articles having improved stiffness charateristics is also disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I) shown above, (B ) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with potassium, strontium or barium, (2) a hydroxy-higher fatty acid salt with potassium, strontium or barium, (3) an aliphatic polycarboxylic acid salt with lithium, sodium, potassium, strontium or barium, (4) a salt of an aliphatic hydroxy acid having form 2 to 6 carbon atoms with lithium, sodium, potassium, magnesium, strontium or barium, (5) an aromatic carboxylic acid salt with lithium, sodium, strontium, barium or aluminum, (6) a glutamic acid salt with lithium, sodium, potassium, strontium or barium, (7) an aliphatic phosphoric acid salt with sodium, potassium, calcium, strontium or barium, (8) a lithium, sodium, potassium or barium salt of a cyclic phosphorus compound represented by formula (II): wherein Ar3 and Ar4, which may be the same or different, each represents an arylene group, an alkylarylene group, a cycloalkylarylene group, an arylarylene group or an aralkylarylene group; M represents lithium, sodium, potassium or barium; and m represents an atomic valence of M, (9) magnesium or aluminum hydroxide, (10) magnesium oxide, (11) magnesium or calcium carbonate and (12) hydrotalcite, and (C) from 0.01 to 1 part by weight of an aliphatic amine.

  本发明公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，该组合物包括按重量计100份的结晶聚烯烃、(A)按重量计0.001至1份的由式(I)代表的亚磷酸氟化合物： 其中 R 代表具有 1 至 4 个碳原子的亚烷基或硫原子；Ar1 和 Ar2 可以相同或不同，各自代表烷基芳基或环烷基芳基；n 代表 0 或 1，以及 (B) 0.(1) 锂或钠的脂肪族一羧酸盐，(2) 锂、钠或钾的二硫代氨基甲酸盐、(3) 锂、钠或钾的 2-巯基苯并噻唑盐， (4) 锂、钠或钾的 2-巯基苯并咪唑盐， (5) 锂、钠或钾的苯并三唑盐。 本发明还公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，其成分包括 100 份（重量）结晶聚烯烃、(A) 0.001 至 1 份（重量）由上文式(I)代表的亚磷酸氟化合物、(B ) 0.(1)钾、锶或钡的脂肪族一羧酸盐；(2)钾、锶或钡的羟基高级脂肪酸盐；(3)锂、钠、钾、锶或钡的脂肪族多羧酸盐；(4)锂、钠、钾、镁、锶或钡的具有 2 至 6 个碳原子的脂肪族羟基酸盐、(5) 锂、钠、锶、钡或铝的芳香族羧酸盐； (6) 锂、钠、钾、锶或钡的谷氨酸盐、(7) 含有钠、钾、钙、锶或钡的脂肪族磷酸盐， (8) 由式（II）代表的环磷化合物的锂、钠、钾或钡盐： 其中 Ar3 和 Ar4 可以相同或不同，各自代表芳基、烷芳基、环烷芳基、芳基芳基或芳基芳基；M 代表锂、钠、钾或钡；m 代表 M 的原子价，(9) 氢氧化镁或铝，(10) 氧化镁，(11) 碳酸镁或碳酸钙和 (12) 水滑石，以及 (C) 0.01至1份重量的脂肪族胺。
• Automotive interior compound
  申请人：Borealis AG

  公开号：EP2386602A1

  公开（公告）日：2011-11-16

  Composition having a melt flow rate MFR2 (230 °C) measured according to ISO 1133 in the range of 15 to 30 g/10min, said composition comprises a heterophasic propylene copolymer (H-PP1), a high melt flow polypropylene (HMF-PP), a styrenic block copolymer (SBC) and a mineral filler (F), wherein (a) the heterophasic propylene copolymer (H-PP1) has a xylene cold soluble (XCS) content measured according to ISO 6427 in the range of 22.0 to 50.0 wt.-% and comprises (a1) a polypropylene matrix (M1) and (a2) an elastomeric copolymer (E1) comprising units derived from - propylene and - ethylene and/or C4 to C12 α-olefin, (b) the melt flow rate MFR2 (230 °C) measured according to ISO 1133 of the high melt flow polypropylene (HMF-PP) is higher than the melt flow rate MFR2 (230 °C) measured according to ISO 1133 of the heterophasic propylene copolymer (H-PP1), and (c) the high melt flow polypropylene (HMF-PP) has melt flow rate MFR2 (230 °C) measured according to ISO 1133 of at least 40.0 g/10min.

  根据 ISO 1133 测量，熔体流动速率 MFR2（230 °C）在 15 至 30 克/10 分钟范围内的组合物、 所述组合物包括杂相丙烯共聚物 (H-PP1)、高熔体流动性聚丙烯 (HMF-PP)、苯乙烯嵌段共聚物 (SBC) 和矿物填料 (F)，其中 (a) 异相丙烯共聚物(H-PP1)的二甲苯冷溶性(XCS)含量根据 ISO 6427 测定在 22.0 至 50.0 wt.-%之间，并包括 (a1) 聚丙烯基体（M1）和 (a2) 弹性共聚物 (E1)，该共聚物由以下单元组成 - 丙烯和 - 乙烯和/或 C4 至 C12 α-烯烃的单元组成、 (b) 高熔体流动聚丙烯（HMF-PP）根据 ISO 1133 测得的熔体流动速率 MFR2（230 ℃）高于杂相丙烯共聚物（H-PP1）根据 ISO 1133 测得的熔体流动速率 MFR2（230 ℃）、 以及 (c) 根据 ISO 1133 测量，高熔体流动性聚丙烯（HMF-PP）的熔体流动性 MFR2（230 ℃）至少为 40.0 克/10 分钟。
• Bimodal talc filled heterophasic polypropylene
  申请人：Borealis AG

  公开号：EP2410008A1

  公开（公告）日：2012-01-25

  Polypropylene composition comprising polypropylene and at least two different mineral fillers wherein the first mineral filler has a lower particle size d50 determined by sedimentation technique compared to the particle size d50 of the second mineral filler, and the second mineral filler has a lamellarity index of at least 2.90, wherein further the weight ratio of the first mineral filler to the second mineral filler is in the range of 10/90 to below 30/70 or more than 70/30 to 90/10.

  由聚丙烯和至少两种不同矿物填料组成的聚丙烯组合物，其中 与第二种矿物填料的粒径 d50 相比，第一种矿物填料通过沉降技术测定的粒径 d50 较小，且第二种矿物填料的薄片指数至少为 2.90、 其中第一矿物填料与第二矿物填料的重量比在 10/90 至低于 30/70 的范围内，或大于 70/30 至 90/10。
• Automotive material with high quality perception
  申请人：Borealis AG

  公开号：EP2650329A1

  公开（公告）日：2013-10-16

  A composition with a melt flow rate MFR2 (230°C) in the range of 5 to 40 g/10min, wherein said composition comprises at least one heterophasic propylene copolymer, a high density polyethylene and an inorganic antiblocking agent in an amount of 0.5 to 5 wt.-%.

  一种组合物，其熔体流动速率 MFR2（230°C）在 5 至 40 克/10 分钟的范围内，其中所述组合物包含至少一种杂相丙烯共聚物、高密度聚乙烯和一种无机抗阻塞剂，含量为 0.5 至 5 wt.-%。
• THERMOPLASTIC RESIN COMPOSITION AND ARTICLE MANUFACTURED USING THE SAME
  申请人：Lotte Advanced Materials Co., Ltd.

  公开号：EP3342817A1

  公开（公告）日：2018-07-04

  Disclosed herein is a thermoplastic resin composition. The thermoplastic resin composition includes: a thermoplastic resin including a rubber-modified vinyl graft copolymer and an aromatic vinyl copolymer resin; a light stabilizer including a hindered amine light stabilizer (HALS) and a benzotriazole UV stabilizer; and zinc oxide having an average particle diameter of 0.5 µm to 3 µm and a BET specific surface area of 1 m2/g to 10 m2/g. The thermoplastic resin composition has good properties in terms of weather resistance, impact resistance, appearance, and antibacterial resistance.

  本文公开了一种热塑性树脂组合物。该热塑性树脂组合物包括：热塑性树脂，包括橡胶改性乙烯基接枝共聚物和芳香族乙烯基共聚物树脂；光稳定剂，包括受阻胺光稳定剂（HALS）和苯并三唑紫外线稳定剂；以及氧化锌，其平均颗粒直径为 0.5 µm 至 3 µm，BET 比表面积为 1 m2/g 至 10 m2/g。这种热塑性树脂组合物具有良好的耐候性、抗冲击性、外观和抗菌性。