申请人:IDEMITSU PETROCHEMICAL CO., LTD.
公开号:EP0744439A1
公开(公告)日:1996-11-27
A polypropylene resin composition is herein disclosed which is obtainable by blending (A) 100 parts by weight of a polypropylene resin comprising (a) 100 to 20% by weight of a homopolymer of propylene and/or a propylene copolymer containing 4% by weight or less of another olefin unit in which in a pentad fraction by 13C-NMR, [rrrr/(1-mmmm)]×100 is in the range of 20 to 60%, a Tm measured by a DSC is 150°C or more, and a melt enthalpy is 100 J/g or less, and (b) 0 to 80% by weight of a propylene copolymer containing 10 to 80% by weight of an olefin unit other than propylene, with (B) 0.01 to 5 parts by weight of an octyltin salt of a fatty acid, an alkylenebisfatty acid amide, a fatty acid ester of a polyvalent alcohol, or a metal salt of an aliphatic monocarboxylic acid.
The employment of this polypropylene resin composition permits, under a good moldability by the calender molding machine, the manufacture of films and sheets having less thickness unevenness, excellent appearance and heat resistance and such flexibility as in molded articles of a plastic polyvinyl chloride.
本文公开了一种聚丙烯树脂组合物,该组合物可通过混合以下物质获得:(A) 100 份(按重量计)聚丙烯树脂,该树脂包含(a) 100%至 20%(按重量计)的丙烯均聚物和/或丙烯共聚物,该丙烯均聚物和/或丙烯共聚物含有 4%(按重量计)或更少的另一种烯烃单元,在 13C-NMR 测量的五元组分中,[rrrr/(1-mmm)]×100 在 20%至 60%的范围内,通过 DSC 测量的 Tm 为 150°C 或更高,熔体焓为 100 J/g、[rrrr/(1-mmm)]×100在20%至60%的范围内,用DSC测量的Tm为150℃或以上,熔体焓为100焦耳/克或以下,以及(b)0至80%(重量)的丙烯共聚物,其中含有10%至80%(重量)的丙烯以外的烯烃单元,以及(B)0.01 至 5 份(重量)脂肪酸的辛基锡盐、亚烷基二脂肪酸酰胺、多价醇的脂肪酸酯或脂族单羧酸的金属盐。
使用这种聚丙烯树脂组合物,可以在压延成型机的良好成型条件下,制造出厚度不均匀度较小、外观和耐热性极佳的薄膜和片材,其柔韧性与聚氯乙烯塑料成型品相当。