1,2-乙二醇,二(4-氨基苯酸酯) | 10505-05-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2-乙二醇,二(4-氨基苯酸酯)
• 英文名称: O,O'-bis(p-aminobenzoyl)-1,2-ethylebediol
• 英文别名: 1,2-bis(4-aminobenzoyloxy)ethane；Ethylenglykolbis(4-aminobenzoat)；1,2-bis-(4-amino-benzoyloxy)-ethane；1,2-Bis-(4-amino-benzoyloxy)-aethan；Aethylenglycol bis (p-aminobenzoat)；1,2-Ethylen-bis-(p-aminobenzoat)；Bis(4-aminobenzoic acid)ethylene ester；2-(4-aminobenzoyl)oxyethyl 4-aminobenzoate
• CAS: 10505-05-2
• 化学式: C₁₆H₁₆N₂O₄
• 分子量: 300.314
• InChiKey: VTDXHXOFPBQISQ-UHFFFAOYSA-N

物化性质

• 熔点：
  204-205 °C(Solv: acetone (67-64-1))
• 沸点：
  536.9±35.0 °C(Predicted)
• 密度：
  1.301±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  105
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5-N-辛基噻吩-2-甲醛 、 1,2-乙二醇,二(4-氨基苯酸酯) 以 乙醇 为溶剂， 以42%的产率得到1,2-Bis<4-(5-octyl-2-thienylmethylidenamino)-phenylcarbonyloxy>ethan
  参考文献：
  名称：

  Kossmehl, Gerhard; Budwill, Detlev, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1987, vol. 42, # 4, p. 478 - 488

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(4-硝基苯甲酰)氧乙基 4-硝基苯甲酸酯 在 palladium 10% on activated carbon 、 氢气 作用下， 以 乙酸乙酯 为溶剂， 反应 12.0h， 以1290 mg的产率得到1,2-乙二醇,二(4-氨基苯酸酯)
  参考文献：
  名称：

  统计数据放大了产品对映体纯度的有机催化双Ugi反应：一种连接物裂解方法，可得到高度对映纯的Ugi产品。

  摘要：

  在这里，我们报告了有机催化双重Ugi反应，在单个操作中将对映选择性过程和ee增强相结合，以提供具有非常高ee值的手性Ugi产品。设计分别由碳酸酯和二酯束缚的双异氰化物和双苯胺，以完成这种双多组分反应，形成10个新的化学键（4个CN，2个CC，2个CO和2个NH键）。该策略进一步用于对映体富集的大环化合物的快速构建。

  DOI：

  10.1021/acs.orglett.9b04239

文献信息

• New polyurea resins and their preparation and use
  申请人：IHARA CHEMICAL INDUSTRY Co., Ltd.

  公开号：EP0538850A2

  公开（公告）日：1993-04-28

  Polyurea resins having excellent mechanical properties and high heat resistance can be prepared by the reaction of an aromatic polyamine component and an aliphatic polyisocyanate component, in which the aromatic polyamine component is a combination of a first aromatic polyamine compound which is typically a polyoxyalkylene-bis(aminobenzoate) compound and a second aromatic polyamine compound selected from various classes of aromatic polyamine compounds different from the first aromatic polyamine compound, in a specified weight proportion. The polyurea resin can be imparted with further improved heat resistance when the aliphatic polyisocyanate component is a combination of an aliphatic diisocyanate compound and a cyclic trimer of an aliphatic polyisocyanate compound in a specified weight proportion.

  通过芳香族多胺组分和脂肪族多异氰酸酯组分的反应，可以制备出具有优异机械性能和高耐热性的聚脲树脂，其中芳香族多胺组分是第一芳香族多胺化合物（通常为聚氧亚烷基双（氨基苯甲酸酯）化合物）和第二芳香族多胺化合物（选自不同于第一芳香族多胺化合物的各类芳香族多胺化合物）按特定重量比例的组合。当脂肪族多异氰酸酯组分是脂肪族二异氰酸酯化合物和脂肪族多异氰酸酯化合物环状三聚体按特定重量比例的组合时，聚脲树脂的耐热性能可进一步提高。
• Polyurea covered golf ball
  申请人：ACUSHNET COMPANY

  公开号：EP0630666A2

  公开（公告）日：1994-12-28

  A novel polyurea composition comprising the reaction product of an organic isocyanate and an organic amine, each having at least two functional groups is disclosed. Golf balls employing covers formed of the polyurea composition also are disclosed.

  本发明公开了一种新型聚脲组合物，该组合物包含有机异氰酸酯和有机胺的反应产物，每种有机异氰酸酯和有机胺至少具有两个官能团。此外，还公开了使用该聚脲组合物形成的盖子的高尔夫球。
• Active-matrix liquid crystal display
  申请人：HITACHI, LTD.

  公开号：EP0806698A1

  公开（公告）日：1997-11-12

  An active-matrix liquid crystal display device employing the in-plane switching mode in which an electric field substantially parallel to the substrate surface is applied to the liquid crystals, characterized by weak torsional anchoring of the liquid crystal molecules (6) and the alignment layer surface at the liquid crystal/alignment layer interface to an extent that the extrapolation length which expresses the strength of said torsional anchoring will become not less than 10% of the gap between the substrates. For obtaining such weak torsional anchoring, an organic alignment layer (5) comprising a polymer and/or oligomer having long-chain alkylene and/or fluoro groups, or an inorganic alignment layer formed by oblique evaporation technique, or a photo-reactive alignment layer formed by linearly polarized light irradiation is used.

  一种采用平面内开关模式的有源矩阵液晶显示装置，在这种模式下，电场基本上平行于基板表面施加到液晶上，其特征是液晶分子（6）和配向层表面在液晶/配向层界面处的扭转锚定很弱，以至于表示所述扭转锚定强度的外推长度将不小于基板之间间隙的 10%。为获得这种微弱的扭转锚定，可使用由具有长链亚烷基和/或氟基团的聚合物和/或低聚物组成的有机配位层 (5)，或通过斜蒸发技术形成的无机配位层，或通过线偏振光照射形成的光反应配位层。
• Composition for forming polishing layer of chemical mechanical polishing pad, chemical mechanical polishing pad and chemical mechanical polishing method
  申请人：JSR Corporation

  公开号：EP2083027A2

  公开（公告）日：2009-07-29

  Provided is a composition for forming a polishing layer of a chemical mechanical polishing pad having polishing characteristics such as a high polishing rate, an excellent planarity of the polished object and less scratches of the polished object. The above composition for forming a polishing layer of a chemical mechanical polishing pad comprises (A) a polyurethane having a carbon-carbon double bond on a side chain and (B) a cross-linking agent. The polyurethane (A) is preferably a thermoplastic polyurethane (A') obtained by mixing at least the following components (a11) to (a13) and component (a2) in a proportion satisfying the following conditions (1) and (2) and reacting them: (a11) an oligomer which has one or more hydroxyl groups and one or more carbon-carbon double bonds and which has a number average molecular weight of 500 to 2500, (a12) an oligomer which has two or more hydroxyl groups and either one or both of an ether bond and an ester bond and which has a number average molecular weight of 500 to 2500 and is different from the component (a11), (a13) a monomer having two hydroxyl groups and (a2) a monomer having two isocyanate groups; and (1) a value of M-1/M-OH is 0.85 to 1.10, and (2) a value of M-2/M-OH is 0.45 to 0.80, wherein M-1 is the number of isocyanate groups contained in the component (a2), M-2 is the number of hydroxyl groups contained in the component (a13) and M-OH is the total number of hydroxyl groups contained in the components (a11), (a12) and (a13).

  本发明提供了一种用于形成化学机械抛光垫抛光层的组合物，该组合物具有抛光率高、被抛光物体平面度好、被抛光物体划痕少等抛光特性。 上述用于形成化学机械抛光垫抛光层的组合物包括 (A) 侧链上具有碳碳双键的聚氨酯和 (B) 交联剂。聚氨酯(A)最好是热塑性聚氨酯(A')，其制备方法是将至少下列组分(a11)至(a13)和组分(a2)按满足下列条件(1)和(2)的比例混合并进行反应： (a11) 具有一个或多个羟基和一个或多个碳碳双键且平均分子量在 500 至 2500 之间的低聚物，(a12) 具有两个或多个羟基和一个醚键或两个醚键和一个酯键且平均分子量在 500 至 2500 之间且不同于组分(a11)的低聚物，(a13) 具有两个羟基的单体和(a2) 具有两个异氰酸酯基团的单体；(1) M-1/M-OH 的值为 0.(2) M-2/M-OH 的值为 0.45 至 0.80，其中 M-1 为组分 (a2) 所含异氰酸酯基团的数目，M-2 为组分 (a13) 所含羟基基团的数目，M-OH 为组分 (a11)、(a12) 和 (a13) 所含羟基基团的总数。
• Golf balls having a foam center
  申请人：Acushnet Company

  公开号：US10080928B2

  公开（公告）日：2018-09-25

  Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed composition selected from thermoset compositions and thermoplastic compositions. The core layers have different hardness and specific gravity levels. The specific gravity (density) of the foam inner core is preferably less than the density of the outer core layer.

  提供了含有双核心结构的多层高尔夫球。球芯结构包括内芯（中心），内芯由泡沫组合物组成，最好是发泡聚氨酯。外芯层最好由选自热固性组合物和热塑性组合物的非发泡组合物形成。芯层具有不同的硬度和比重。泡沫内芯的比重（密度）最好小于外芯层的密度。