A polyamide and/or polyimide is prepared by using N,N'- dimethylethyleneurea or N,N'-dimethylpropyleneurea as a solvent for polycondensation of a polycarboxylic acid and a diisocyanate at a temperature above 100°C in the presence of an alkali metal carbonate, alkali metal hydrogencarbonate, alkali metal hydroxide or an alkali metal salt of a polycarboxylic acid. Where an alkali metal salt of a polycarboxylic acid is employed, the salt is preferably of an acid having the same or a similar structure to the polycarboxylic acid participating in the polycondensation reaction.
The present invention provides an aqueous dispersion mixture comprising; an aqueous dispersion (A) that comprises a crystalline polyolefin (a) as a dispersoid thereof; an aqueous dispersion (B) that comprises a crystalline polyurethane (b) as a dispersoid thereof; and an aqueous dispersion (C) that comprises a non-crystalline polyurethane (c) as a dispersoid thereof, wherein the crystalline polyolefin (a) is a non-chlorine modified polyolefin , wherein the crystalline polyurethane (b) has a crystal melting heat amount equal to or larger than 3 J/g measured by differential scanning calorimetry, wherein the non-crystalline polyurethane (c) has a crystal melting heat amount smaller than 3 J/g measured by differential scanning calorimetry, and wherein the aqueous dispersion (B) comprises a non-volatile content of 30 parts by mass to 100 parts by mass and the aqueous dispersion (C) comprises a non-volatile content of 20 parts by mass to 80 parts by mass, relative to a non-volatile content of 100 parts by mass of the aqueous dispersion (A).
Water dispersible polyamides having carboxylic acid groups are disclosed. These are made by reacting polycarboxyl is acids or anhydrides thereof with amine containing monomer or an amide terminated polyamide under reaction conditions such that a few of the carboxylic acid groups are residual and can promote dispersion in water. These polyamides after dispersion can be chain extended to higher molecular weight polymers or can be terminally functionalized with reactive groups such as isocyanate, epoxy, vinyl, acetoacetonate, or silanol groups. Composites and hybrids of these polyamides with vinyl polymers are also disclosed and claimed.
The present invention provides an aqueous dispersion mixture comprising; an aqueous dispersion (A) that comprises a crystalline polyolefin (a) as a dispersoid thereof; an aqueous dispersion (B) that comprises a crystalline polyurethane (b) as a dispersoid thereof; and an aqueous dispersion (C) that comprises a non-crystalline polyurethane (c) as a dispersoid thereof, wherein the crystalline polyolefin (a) is a non-chlorine modified polyolefin, wherein the crystalline polyurethane (b) has a crystal melting heat amount equal to or larger than 3 J/g measured by differential scanning calorimetry, wherein the non-crystalline polyurethane (c) has a crystal melting heat amount smaller than 3 J/g measured by differential scanning calorimetry, and wherein the aqueous dispersion (B) comprises a non-volatile content of 30 parts by mass to 100 parts by mass and the aqueous dispersion (C) comprises a non-volatile content of 20 parts by mass to 80 parts by mass, relative to a non-volatile content of 100 parts by mass of the aqueous dispersion (A).
Multifunctional polyamides for protective coatings
申请人:Huntsman Advanced Materials Americas LLC
公开号:US10414855B2
公开(公告)日:2019-09-17
The present disclosure relates to a curing agent component for a curable resin which includes a multifunctional polyamide obtained from the reaction of a polyamine and a polycarboxylic acid. The curing agent component may be used as part of a two component curable system for the curing of curable resins including epoxy resins.