1,3-双{4-(10H-吩恶嗪-10-基)苯甲酰基}苯 | 1618669-36-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 中文名称: 1,3-双{4-(10H-吩恶嗪-10-基)苯甲酰基}苯
• 英文名称: 1,3-bis{4-(10H-phenoxazine-10-yl)benzoyl}benzene
• 英文别名: 1,3-Phenylenebis((4-(10H-phenoxazin-10-yl)phenyl)methanone)；[3-(4-phenoxazin-10-ylbenzoyl)phenyl]-(4-phenoxazin-10-ylphenyl)methanone
• CAS: 1618669-36-5
• 化学式: C₄₄H₂₈N₂O₄
• 分子量: 648.717
• InChiKey: HPBARVRVPBVXFH-UHFFFAOYSA-N

物化性质

• 密度：
  1.319±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  50
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  吩噁嗪 、 1,3-亚苯基双[(4-溴苯基)甲酮] 在 二(三叔丁基膦)钯 、 potassium carbonate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以96%的产率得到1,3-双{4-(10H-吩恶嗪-10-基)苯甲酰基}苯
  参考文献：
  名称：

  发光的蝴蝶：二苯甲酮衍生物对全色延迟荧光OLED的有效激子收获。

  摘要：

  在单重态和三重态激发态之间具有较小能隙的蝴蝶形发光二苯甲酮衍生物可用于实现高效的全色延迟荧光。在发光层中掺杂了这些二苯甲酮衍生物的有机发光二极管（OLED）可以产生从蓝色到橙红色和白色的电致发光，最大外部量子效率高达14.3％。三重态激子可通过延迟的荧光通道有效收集。

  DOI：

  10.1002/anie.201402992

文献信息

• ORGANOMETALLIC COMPLEX AND APPLICATION THEREOF IN ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20190241590A1

  公开（公告）日：2019-08-08

  Disclosed are an organometallic complex comprising a new six-membered N-heterocyclic ligand, and an application thereof in an organic electronic device, especially in a phosphorescent organic light-emitting diode. The present invention further relates to an organic electronic device comprising the organometallic complex according to the present invention, especially an organic light-emitting diode, and an application thereof in display and illumination technology. In the present invention, the device structure is optimized and the concentration of the metal complex in the substrate is changed, so that the device achieves the optimal performance, and an OLED device having high efficiency, high luminance and high stability is achieved, thereby providing a better choice of materials for full-colour display and illumination application.

  揭示了一种含有新的六元N-杂环配体的有机金属络合物，以及其在有机电子器件中的应用，特别是在磷光有机发光二极管中的应用。本发明还涉及一种含有根据本发明的有机金属络合物的有机电子器件，特别是有机发光二极管，以及其在显示和照明技术中的应用。在本发明中，优化了器件结构并改变了基板中金属络合物的浓度，使得器件实现了最佳性能，并实现了具有高效率、高亮度和高稳定性的OLED器件，从而为全彩显示和照明应用提供了更好的材料选择。
• NITROGEN-CONTAINING FUSED HETEROCYCLIC RING COMPOUND AND APPLICATION THEREOF
  申请人：GUANGZHOU CHINAPAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200223857A1

  公开（公告）日：2020-07-16

  The present invention relates to a nitrogen-containing fused heterocyclic ring compound and application thereof. The compound has the structural formula (I): using the described compound, it is possible to fabricate a device having higher stability and a longer service life.

  本发明涉及一种含氮融合杂环环化合物及其应用。该化合物具有结构式（I）：利用所述化合物，可以制造具有更高稳定性和更长寿命的设备。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP3035401A1

  公开（公告）日：2016-06-22

  An organic electroluminescent device having an anode, a cathode, and a light emitting layer between the anode and the cathode, in which the light emitting layer contains a first organic compound, a second organic compound, and a third organic compound that satisfy the following expression (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light emitting material, is capable of enhancing the light emission efficiency. ES1 (A), ES1 (B) and ES1 (C) represent a lowest singlet excitation energy level of the first, second and third organic compound, respectively. ES1A>ES1B>ES1C

  一种有机电致发光器件具有阳极、阴极以及位于阳极和阴极之间的发光层，其中发光层包含满足以下表达式（A）的第一种有机化合物、第二种有机化合物和第三种有机化合物，第二种有机化合物是一种延迟荧光材料，第三种有机化合物是一种发光材料，该器件能够提高发光效率。ES1（A）、ES1（B）和 ES1（C）分别代表第一、第二和第三种有机化合物的最低单激发能级。ES1A>ES1B>ES1C
• ORGANIC LIGHT-EMITTING ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP3171421A1

  公开（公告）日：2017-05-24

  An organic light-emitting device containing a host material, a delayed fluorescent material and a light-emitting material satisfying ES1(H)>ES1(F)>ES1(D) has a high light emission efficiency. ES1(H) represents a lowest excited singlet energy level of the host material, ES1(F) represents a lowest excited singlet energy level of the delayed fluorescent material, and ES1(D) represents a lowest excited singlet energy level of the light-emitting material.

  一种含有宿主材料、延迟荧光材料和发光材料的有机发光器件具有很高的光发射效率，该器件满足ES1(H)>ES1(F)>ES1(D)的要求。ES1(H)代表主材料的最低激发单线能级，ES1(F)代表延迟荧光材料的最低激发单线能级，ES1(D)代表发光材料的最低激发单线能级。
• Organic compound
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US10804470B2

  公开（公告）日：2020-10-13

  An organic compound, applications thereof, an organic mixture, and an organic electronic device. The structure of the organic compound is represented by formula (1), and definitions of substituent groups in the formula (1) are the same as those in the specifications.

  一种有机化合物、其应用、一种有机混合物和一种有机电子设备。有机化合物的结构用式（1）表示，式（1）中取代基的定义与说明书中的相同。