1,4,7,10-四氧杂-13-氮杂环十五烷,13-(9-蒽基甲基)- | 109297-65-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1,4,7,10-四氧杂-13-氮杂环十五烷,13-(9-蒽基甲基)-
• 英文名称: 1,4,7,10-tetraoxa-13-(anthracen-9-ylmethyl)-13-monoazacyclopentadecane
• 英文别名: 1-(9'-methylanthracenyl)-4,7,10,13-tetraoxa-1-azacyclopentadecane；13-(9-Anthrylmethyl)-13-aza-1,4,7,10-tetraoxacyclopentadecane；N-(9-anthrylmethyl)-1-monoaza-15-crown-5；N-(9-anthrylmethyl)monoaza-15-crown-5；15-crown-5；13-(Anthracen-9-ylmethyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane
• CAS: 109297-65-6
• 化学式: C₂₅H₃₁NO₄
• 分子量: 409.525
• InChiKey: VVNGVGNWCSPIHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  40.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 1,4,7,10-四氧杂-13-氮杂环十五烷,13-(9-蒽基甲基)- 在 氢溴酸 作用下， 以 溶剂黄146 为溶剂， 反应 2.0h， 以52%的产率得到9'-methyl(4,7,10,13-tetraoxa-1-azacyclopentadecanyl)-10'-bromomethylanthracene
  参考文献：
  名称：

  同时存在过渡金属离子和碱金属离子时信号系统的荧光增强：电势与逻辑门。

  摘要：

  在蒽的9位和10位上横向不对称的配体和大环的连接导致荧光信号系统L1，该信号系统在同时存在碱金属和过渡金属离子的情况下增强了荧光。

  DOI：

  10.1039/b413274b
• 作为产物：
  描述：

  9-氯甲基蒽 、 氮杂-15-冠醚-5 在 potassium carbonate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以68%的产率得到1,4,7,10-四氧杂-13-氮杂环十五烷,13-(9-蒽基甲基)-
  参考文献：
  名称：

  Bissell, Richard A.; Calle, Emilio; Silva, A. Prasanna de, Journal of the Chemical Society. Perkin transactions II, 1992, # 9, p. 1559 - 1564

  摘要：

  DOI：

文献信息

• Control of peroxyoxalate chemiluminescence by nitrogen-containing ligand quenching: turning off and on by ligand–metal ion host–guest interactions
  作者：Takayuki Maruyama、Yasuyuki Fujie、Noriyuki Oya、Eisuke Hosaka、Aki Kanazawa、Daisuke Tanaka、Yoshiyuki Hattori、Jiro Motoyoshiya

  DOI：10.1016/j.tet.2011.06.078

  日期：2011.9

  The control of peroxyoxalate chemiluminescence (PO-CL) by the coordination of nitrogen-containing ligands and metal cations was investigated. Turning the CL off and on was done by PO-CL using 15-monoazacrown-5-tethered anthracene and alkali metal ions. CL quenching and regeneration was also observed in the separated molecular system of 15-monoazacrown-5 and the fluorophores. CL quenching by a number of ligands bearing dipicolylamino groups was evaluated by these PO-CL reactions and found to be closely related to their oxidation potentials, which is dependent on the Weller rate law for electron exchange and this provides strong support for the existence of the CIEEL PO-CL process. When Zn2+ or Cu2+ are added to the PO-CL system quenched by the ligand, N-[2-(2,2'-dipicolylamino)ethyl]aniline, CL was turned on because the electron donating ability of the ligands was modulated. This was controlled by the coordination of the studied metal ions and, therefore, this system results in CL because of host-guest interactions. (C) 2011 Elsevier Ltd. All rights reserved.
• Fluorescence enhancement of a signaling system in the simultaneous presence of transition and alkali metal ions: a potential AND logic gate
  作者：Bamaprasad Bag、Parimal K. Bharadwaj

  DOI：10.1039/b413274b

  日期：——

  Attachment of a laterally non-symmetric cryptand and a macrocycle at the 9- and 10-positions of anthracene leads to a fluorescent signaling system L1 which gives fluorescence enhancement in the simultaneous presence of alkali and transition metal ions.

  在蒽的9位和10位上横向不对称的配体和大环的连接导致荧光信号系统L1，该信号系统在同时存在碱金属和过渡金属离子的情况下增强了荧光。
• Bissell, Richard A.; Calle, Emilio; Silva, A. Prasanna de, Journal of the Chemical Society. Perkin transactions II, 1992, # 9, p. 1559 - 1564
  作者：Bissell, Richard A.、Calle, Emilio、Silva, A. Prasanna de、Silva, Saliya A. de、Gunaratne, H. Q. Nimal、et al.

  DOI：——

  日期：——