1,4-二癸基磺酸基琥珀酸酯钠盐 | 23524-64-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 1,4-二癸基磺酸基琥珀酸酯钠盐
• 中文别名: 1,4-二癸基磺酸根琥珀酸钠
• 英文名称: sodium 1,2-bis(decyloxycarbonyl)ethanesulfonate
• 英文别名: sodium didecyl sulfosuccinate；di-(n-decyl)sodium sulfosuccinate；didecyl sulfosuccinate sodium salt；sodium 1,4-didecyl sulfonatosuccinate；Butanedioic acid, sulfo-, 1,4-didecyl ester, sodium salt；sodium;1,4-didecoxy-1,4-dioxobutane-2-sulfonate
• CAS: 23524-64-3
• 化学式: C₂₄H₄₅O₇S*Na
• 分子量: 500.673
• InChiKey: VGLKJXXKLNRSOD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.66
• 重原子数：
  33
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  118
• 氢给体数：
  0
• 氢受体数：
  7

安全信息

• 海关编码：
  2914509090

反应信息

• 作为反应物：
  描述：

  1,4-二癸基磺酸基琥珀酸酯钠盐 在 盐酸 作用下， 以 异丙醇 为溶剂， 反应 3.0h， 以95.4%的产率得到di(decyloxy)sulfosuccinic acid
  参考文献：
  名称：

  Gol'din, G. S.; Averbakh, K. O.; Nekrasova, L. A., Journal of applied chemistry of the USSR, 1992, vol. 65, # 9.2, p. 1663 - 1668

  摘要：

  DOI：
• 作为产物：
  描述：

  马来酸二癸酯 在 sodium hydrogensulfite 作用下， 以 水 为溶剂， 反应 3.0h， 以16%的产率得到1,4-二癸基磺酸基琥珀酸酯钠盐
  参考文献：
  名称：

  在水溶液中由氨基甲基（羟基）芳烃前体生成甲基醌

  摘要：

  从有机合成和生物学的观点来看，邻醌甲基化物（QMs）是重要的反应性中间体。已经研究了作为QM前体的N，N-二烷基-9-氨基甲基-10-菲咯啉及其萘类似物的光化学和热转化。这些前体容易与烷基乙烯基醚反应，分别得到2-烷氧基二苯并[ f，h ]苯并二氢吡喃酮和2-烷氧基苯并[ f ]苯并二氢吡喃。通过在反应溶剂中存在水分子并通过形成阴离子胶束和囊泡来加速QM的热和光化学生成。

  DOI：

  10.1016/j.tet.2005.04.037

文献信息

• Raman and IR spectroscopic studies of the interaction between counterion and polar group in self-assembled systems of AOT-homologous “sodium dialkyl sulfosuccinates’'
  作者：Yasuyuki Nagasoe、Naoki Ichiyanagi、Hirofumi Okabayashi、Sandrine Nave、Julian Eastoe、Charmian J. O'Connor

  DOI：10.1039/a904815d

  日期：——

  Headgroup–counterion interactions have been studied for a homologous series of sodium dialkyl sulfosuccinates (SDAS) with propyl, butyl, hexyl, octyl, decyl, undecyl and dodecyl chains as Aerosol-OT analogues. Raman scattering and IR absorption spectra were recorded and compared with those for dimethyl sulfosuccinate monohydrate, diethyl sulfosuccinate trihydrate and diheptyl sulfosuccinate dihydrate, whose crystal structures are known. The spectral features of the C2O and SO3- stretch modes directly reflect the interaction between the polar group and the Na+ ion and depend strongly upon the environment of hydration. The results may be summarized as follows. For the SDAS monohydrates in the solid state, there exists a strong interaction between the β C2O group and the Na+ ion, as a consequence of coordination of the β C2O to the Na+ ion, resulting in splitting of the C2O stretch modes. In particular, the common Raman (IR) bands observed at 1705–1707 (1706–1708) and 1730–1732 (1732–1733) cm-1 may be assigned to the β C2O group coordinated to the Na+ counterion and the hydrated α C2O group, respectively. The extent of splitting of these bands is a measure of the strength of this C2O···Na+ interaction. Coordination of the β C2O to the Na+ ion also affects the C2O deformation modes of the O–C2O linkage. An increased hydration number and longer hydrocarbon chains induce a weak interaction between the C2O group and the Na+ ion. The SO3-···Na+ interaction reflects the SO3- stretch modes, depending upon the extent of hydration. Furthermore, for the SDAS samples in the organic and aqueous microphases, Raman (IR) bands characteristic of the C2O and SO3-1 groups have been used successfully to account for the interaction between the polar group and the Na+ ion.

  头基–对离子相互作用已被研究一系列同系物的硫酸二烷基琥珀酸钠（SDAS），其烷基链包括丙基、丁基、己基、辛基、癸基、十一烷基和十二烷基，作为气溶胶-OT的类似物。记录并比较了拉曼散射和红外吸收光谱，并与已知晶体结构的单水合二甲基琥珀酸、三水合二乙基琥珀酸和二水合二庚基琥珀酸的光谱特征进行了比较。C=O和SO₃⁻的伸缩模式的光谱特征直接反映了极性基团与Na⁺离子之间的相互作用，并且强烈依赖于水合环境。结果可总结如下：在固态的SDAS单水合物中，β C=O基团与Na⁺离子之间存在强相互作用，这是由于β C=O与Na⁺离子的配位，导致C=O伸缩模式的分裂。特别是，在1705–1707 cm⁻¹（1706–1708 cm⁻¹）和1730–1732 cm⁻¹（1732–1733 cm⁻¹）观察到的常见拉曼（红外）特征带可以分别归因于与Na⁺对离子配位的β C=O基团和水合的α C=O基团。这些特征带的分裂程度是C=O· · ·Na⁺相互作用强度的衡量。β C=O与Na⁺离子的配位还影响O–C=O连接的C=O变形模式。增加的水合数和较长的烃链会导致C=O基团与Na⁺离子之间的弱相互作用。SO₃⁻· · ·Na⁺的相互作用反映了SO₃⁻的伸缩模式，依赖于水合程度。此外，对于有机和水相微相中的SDAS样品，C=O和SO₃⁻基团特征的拉曼（红外）特征带已成功用于解释极性基团与Na⁺离子之间的相互作用。
• Thermoplastic resin composition
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0635548A1

  公开（公告）日：1995-01-25

  A thermoplastic resin composition comprising (a) a polyphenylene sulfide resin, (b) a polyphenylene ether resin, (c) a specific organophosphorus compound, and (d) a basic compound is disclosed. The composition exhibits improved compatibility between resinous components (a) and (b) and therefore provides a molded article having high mechanical strength and excellent appearance.

  本发明公开了一种热塑性树脂组合物，该组合物由 (a) 聚苯硫醚树脂、(b) 聚苯醚树脂、(c) 特定有机磷化合物和 (d) 碱性化合物组成。该组合物改善了树脂成分（a）和（b）之间的相容性，从而提供了一种具有高机械强度和出色外观的成型品。
• METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER
  申请人：Daikin Industries, Ltd.

  公开号：EP2623519A1

  公开（公告）日：2013-08-07

  Provided is a method for producing a fluoropolymer in the presence of a specific non-fluorinated compound having surface activity. The method shows a high polymerization rate, and suppresses formation of sticking polymerization materials after production of a polymer product. The method includes aqueous dispersion polymerization of a fluoroolefin in the presence of a compound (1) represented by formula (1): wherein R1 and R2 are the same as or different from each other, and each represent a C4 to C12 non-fluorinated saturated hydrocarbon group; and M is an alkali metal, an ammonium salt, or an amine salt.

  本发明提供了一种在具有表面活性的特定非氟化合物存在下生产含氟聚合物的方法。该方法聚合率高，可抑制聚合物产品生产后形成粘连聚合材料。该方法包括氟烯烃在由式（1）表示的化合物（1）存在下的水分散聚合： 其中 R1 和 R2 彼此相同或不同，且各自代表 C4 至 C12 非氟化饱和烃基；以及 M 是碱金属、铵盐或胺盐。
• METHOD FOR PRODUCING FLUORINE-CONTAINING COPOLYMER
  申请人：Daikin Industries, Ltd.

  公开号：EP2692750A1

  公开（公告）日：2014-02-05

  The present invention provides a method for producing a copolymer containing a perhaloolefin and vinyl acetate by a novel emulsion polymerization method. The present invention relates to a method for producing a perhaloolefin-vinyl acetate copolymer by emulsion polymerization of at least a perhaloolefin having two carbon atoms and vinyl acetate in the presence of a hydrocarbon emulsifier or in the absence of an emulsifier, provided that the hydrocarbon emulsifier excludes a compound (1) represented by the formula (1): [Chem. 1] wherein R1 and R2 are the same as or different from each other and each represent a C4 to 12 unfluorinated saturated hydrocarbon group; M represents an alkali metal, an ammonium salt, or an amine salt.

  本发明提供了一种通过新型乳液聚合法生产含有全卤烯烃和醋酸乙烯共聚物的方法。本发明涉及一种通过乳液聚合法生产全卤烯烃-醋酸乙烯酯共聚物的方法，该方法是在烃类乳化剂存在或不存在乳化剂的情况下，将至少一种具有两个碳原子的全卤烯烃和醋酸乙烯酯进行乳液聚合，条件是烃类乳化剂不包括由式（1）表示的化合物（1）： [化学式 1］ 其中 R1 和 R2 彼此相同或不同，各自代表 C4 至 12 未氟化的饱和烃基；M 代表碱金属、铵盐或胺盐。
• METHOD FOR PRODUCING BINDER COMPOSITION FOR ELECTRICAL STORAGE DEVICES
  申请人：Asahi Glass Company, Limited

  公开号：EP2911225A1

  公开（公告）日：2015-08-26

  To provide a method for producing a binder composition for a storage battery device, which is excellent in the dispersion stability, whereby properties of an electrode to be obtained are excellent. A method for producing a binder composition for a storage battery device, which comprises an emulsion polymerization step of emulsion polymerizing a monomer mixture containing a fluorinated vinyl monomer in the presence of the following anionic emulsifying agent (A), an aqueous medium and a radical polymerization initiator to obtain a latex containing a fluorinated polymer, and a post addition step of adding the following anionic emulsifying agent (B) to the latex: anionic emulsifying agent (A): an anionic emulsifying agent having no phenyl group in its molecule, anionic emulsifying agent (B): an anionic emulsifying agent having a phenyl group in its molecule.

  提供一种用于生产蓄电池装置的粘结剂组合物的方法，该方法具有优异的分散稳定性，从而可获得性能优异的电极。 一种用于生产蓄电池装置粘结剂组合物的方法，包括乳液聚合步骤，即在以下阴离子乳化剂（A）、水介质和自由基聚合引发剂存在的情况下，乳液聚合含有氟化乙烯基单体的单体混合物，以获得含有氟化聚合物的胶乳；以及后添加步骤，即向胶乳中添加以下阴离子乳化剂（B）： 阴离子乳化剂（A）：分子中没有苯基的阴离子乳化剂、 阴离子乳化剂（B）：分子中含有苯基的阴离子乳化剂。