1,8-二羟基-4-硝基-5-(N-(对苯乙醇)氨基)蒽醌 | 15791-78-3

• 物质功能分类: 染料及颜料 - 染料 - 分散染料
• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1,8-二羟基-4-硝基-5-(N-(对苯乙醇)氨基)蒽醌
• 中文别名: 分散蓝27；分散蓝GFL；分散兰27；分散蓝 27
• 英文名称: 1,8-dihydroxy-4-[4-(2-hydroxyethyl)phenylamino]-5-nitroanthracene-9,10-dione
• 英文别名: Teratop Blue GLF；Disperse Blue 27；1,8-dihydroxy-5-nitro-4-[4'-(2'-hydroxyethyl)anilino]anthraquinone；8-Hydroxy-4-nitro-9,10-dioxo-5-[4-(2-oxonioethyl)anilino]anthracen-1-olate；8-hydroxy-4-nitro-9,10-dioxo-5-[4-(2-oxonioethyl)anilino]anthracen-1-olate
• CAS: 15791-78-3
• 化学式: C₂₂H₁₆N₂O₇
• 分子量: 420.378
• InChiKey: VOCYGZAHYQXJOF-UHFFFAOYSA-N

物化性质

• 沸点：
  537.59°C (rough estimate)
• 密度：
  1.4379 (rough estimate)
• 物理描述：
  Disperse blue 27 is a dark blue to black powder. (NTP, 1992)
• 溶解度：
  50 to 100 mg/mL at 64° F (NTP, 1992)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  153
• 氢给体数：
  4
• 氢受体数：
  8

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : 1,8-Dihydroxy-4-[[4-(2-hydroxyethyl)phenyl]amino]-
5-nitroanthraquinone
CAS-No. : 15791-78-3
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritating to eyes, respiratory system and skin.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Warning
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R36/37/38 Irritating to eyes, respiratory system and skin.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C22H16N2O7
Molecular Weight : 420,37 g/mol
Component Concentration
1,8-Dihydroxy-4-[[4-(2-hydroxyethyl)phenyl]amino]-5-nitroanthraquinone
CAS-No. 15791-78-3 -
EC-No. 239-891-8

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Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- log Pow: 3,707
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. The
preceding data, or interpretation of data, was determined using Quantitative Structure Activity Relationship
(QSAR) modeling.
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. Causes skin irritation.
Eyes Causes serious eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: CB6710000

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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SECTION 15 - REGULATORY INFORMATION
N/A

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  1,8-二羟基-4-硝基-5-(N-(对苯乙醇)氨基)蒽醌 、 3-异丙烯基-α,α-二甲基苄基异氰酸酯 在 dibutyltin dilaurate 作用下， 以 甲苯 为溶剂， 反应 3.0h， 生成 2-[4-[(4,5-dihydroxy-8-nitro-9,10-dioxoanthracen-1-yl)amino]phenyl]ethyl N-[2-(3-prop-1-en-2-ylphenyl)propan-2-yl]carbamate
  参考文献：
  名称：

  Ethylenically-unsaturated blue anthraquinone dyes

  摘要：

  本发明涉及某些新颖的着色剂化合物，其中含有一个或多个乙烯基不饱和的光聚合基团，可以与乙烯基不饱和单体共聚合（或固化），以产生着色组合物，例如着色丙烯酸聚合物。在其中共聚合了现有着色剂的适当组合物包括，例如，由丙烯酸酯和甲基丙烯酸酯制成的聚合物，着色聚苯乙烯以及从其他乙烯基不饱和单体衍生的类似着色聚合材料。本发明还涉及制备光聚合着色剂化合物的过程。乙烯基不饱和着色剂化合物可以适用于涂覆于木材，玻璃，金属，热塑性塑料等表面的涂层中。

  公开号：

  US20050044644A1

文献信息

• ETHYLENICALLY-UNSATURATED BLUE ANTHRAQUINONE DYES
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP1658339A1

  公开（公告）日：2006-05-24
• COLORING AGENTS NATURALISED WITH THE 6'-DEOXY-6'-(PIPERAZINYL)LACTOSE MOIETY
  申请人：Universita' Degli Studi di Firenze

  公开号：EP2992053B1

  公开（公告）日：2018-11-28
• DYE MIXTURES
  申请人：Griffin Bruce Owen

  公开号：US20090263655A1

  公开（公告）日：2009-10-22

  The present invention discloses mixtures of dyes, dye compositions comprising them and the use of said mixtures and compositions, optionally in combination with UV absorbers, to dye or print textile materials, particularly hydrophobic textile materials such as polyester, that must meet stringent lightfastness requirements. Fibers dyed with the inventive dye mixtures exhibit exceptional high temperature light fastness and good all-round fastness properties.
• US3948664A
  申请人：——

  公开号：US3948664A

  公开（公告）日：1976-04-06
• US7172634B2
  申请人：——

  公开号：US7172634B2

  公开（公告）日：2007-02-06