1-(2-氯乙基)-2-乙烯基苯 | 90320-63-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(2-氯乙基)-2-乙烯基苯
• 英文名称: 1-chloro-2-(2-vinylphenyl)ethane
• 英文别名: 1-(2-Chloroethyl)-2-ethenylbenzene
• CAS: 90320-63-1
• 化学式: C₁₀H₁₁Cl
• mdl: MFCD19235598
• 分子量: 166.65
• InChiKey: ZFPSFBCOHANCCJ-UHFFFAOYSA-N

物化性质

• 沸点：
  244.5±9.0 °C(Predicted)
• 密度：
  1.044±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4-bromo-4-methyltetrahydrothiopyran 、 1-(2-氯乙基)-2-乙烯基苯 在 四丁基高氯酸铵 作用下， 以 乙二醇二甲醚 为溶剂， 以82 %的产率得到4-((2,3-dihydro-1H-inden-1-yl)methyl)-4-methyltetrahydro-2H-thiopyran
  参考文献：
  名称：

  电还原自由基加成-极性环化级联以获得环烷烃

  摘要：

  与平面芳香支架相比，三维脂肪环系统具有结构复杂性和拓扑多样性高的特点，因此在药物发现中受到越来越多的关注。在此，我们描述了一种温和且通用的电化学方法，用于通过自由基-极性交叉机制从容易获得的烯烃和烷基卤化物模块化合成结构不同的环状化合物，包括单环烷烃、苯并稠环系统和螺环。

  DOI：

  10.1021/acs.orglett.3c03722
• 作为产物：
  描述：

  2-溴苯甲醛乙烯醛 在 盐酸 、 lithium aluminium tetrahydride 、 正丁基锂 、 三丁基膦 作用下， 以 四氯化碳 、 水 为溶剂， 生成 1-(2-氯乙基)-2-乙烯基苯
  参考文献：
  名称：

  新叶酸、1-茚满甲基、2-烯丙基苄基和 2-(2-乙烯基苯基)乙基自由基重排的阿伦尼乌斯参数与从三丁基锡烷中夺氢有关

  摘要：

  已经确定了与从三丁基锡烷中提取氢原子相关的几种自由基重排速率的温度依赖性。2-苯基-2-甲基丙基重排为 1-苯基-2-甲基丙基-2-基（新叶酸重排）相对于夺氢反应由 log (r/M) = (2.48 +/- 0.08) - (8.13) 表示+/-0.16)/theta，theta = 2.3 RT kcal/mol。2-烯丙基苄基重排为2-茚满甲基的重排为log (r/M) = (2.32 +/- 0.16)- (10.47 +/- 0.36/theta, 2-烯丙基苄基重排为2-四烯丙基的用log表示(r/M) = (2.18 +/- 0.28) - (12.47 +/- 0.60)/theta. 1-茚满甲基重排为 2-四烯丙基由 log (r/M) = (2.65 +/- 0.12) 表示) - (11.21 +/- 0.24)/theta. 2-(2-乙烯基苯基)乙基与五元环的闭合发生在

  DOI：

  10.1021/ja00326a013

文献信息

• CHARGE CONTROL RESIN AND MANUFACTURING METHOD OF THE SAME
  申请人：YASUMATSU Masashi

  公开号：US20150025213A1

  公开（公告）日：2015-01-22

  Here is provided a charge control resin which is prompt in charge rising up, excellent in electrostatic charging propensity and easy in manufacturing. This charge control resin contains a polymer as an active ingredient having a constituent unit represented by following Formula (1) in the Formula (1), R 1 is independent of one another, and is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; R 2 is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; g is a number of 1-3; h is a number of 1-3; and M is a hydrogen atom, an alkali metal, a straight-chained or branched alkyl group having 1-18 carbon atoms, an ammonium radical or a mixture of any of these.

  这里提供了一种电荷控制树脂，它在电荷上升方面快速，具有优异的静电充电倾向并且易于制造。该电荷控制树脂包含一种聚合物作为活性成分，该聚合物具有由以下公式（1）表示的组成单元。在公式（1）中，R1互不相同，可以是氢原子、羟基、卤素原子、含羧基的基团、直链或支链烷基（碳数为1-18）或直链或支链烷氧基（碳数为1-18）；R2可以是氢原子、羟基、卤素原子、含羧基的基团、直链或支链烷基（碳数为1-18）或直链或支链烷氧基（碳数为1-18）；g为1-3的数字；h为1-3的数字；M可以是氢原子、碱金属、直链或支链烷基（碳数为1-18）、铵基或任何这些的混合物。
• PIGMENT DISPERSION AND TONER
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20160246200A1

  公开（公告）日：2016-08-25

  A pigment dispersion containing a pigment, a non-water-soluble solvent, a compound in which an specific azo skeleton structure is bonded to a specific polymer having a monomer unit given, and a polymer compound having a monomer unit that contains a structure selected from the partial structures given by the specific formulas (3) and (4).

  一种颜料分散液，包含颜料、非水溶性溶剂、一种特定的聚合物，其中该聚合物具有给定的单体单元，以及一种聚合物化合物，该聚合物化合物具有包含从特定公式（3）和（4）给定的部分结构中选择的结构的单体单元。
• Graft copolymer and process for producing the same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0490269A1

  公开（公告）日：1992-06-17

  There is provided a process for producing a styrenic graft copolymer which comprises coplymerizing a styrenic monomer and a styrenic monomer having a hydrocarbon radical with an unsaturated bond in the presence of a catalyst comprising as primary ingredient (A) a transition metal compound and (B) a contact product of an organoaluminum compound and a condensation agent or (C) a compound which produces an ionic complex by reacting with the above-mentioned transition metal compound and subsequently graft polymerizing an ethylenically unsaturated monomer onto the resultant styrenic copolymer. The above-described styrenic graft copolymer is greatly improved in terms of compatibility, adhesivity, coatability and wettability while preserving heat resistance and chemical resistance thereof, and thus effective as a variety of constructional materials and compatibilizing agents. Furthermore, the composition or multi-layer material comprising the above-mentioned styrenic graft copolymer is widely utilized in a variety of application field including film, sheet, especially stampable sheet, container, packaging material, automobile parts, electrical and electronic parts, etc.

  提供了一种生产苯乙烯接枝共聚物的工艺，该工艺包括在催化剂存在下，使苯乙烯单体和具有不饱和键烃基的苯乙烯单体共聚，催化剂的主要成分包括(A)过渡金属化合物和(B)有机铝化合物与缩合剂的接触产物或(C)通过与上述过渡金属化合物反应产生离子络合物的化合物，然后将乙烯基不饱和单体接枝聚合到生成的苯乙烯共聚物上。上述过渡金属化合物反应生成离子络合物的化合物，然后将乙烯不饱和单体接枝聚合到生成的苯乙烯共聚物上。 上述苯乙烯接枝共聚物在保持其耐热性和耐化学性的同时，在相容性、粘合性、涂覆性和润湿性方面得到了极大的改善，因此可以有效地用作各种建筑材料和相容剂。此外，由上述苯乙烯接枝共聚物组成的组合物或多层材料可广泛应用于各种应用领域，包括薄膜、片材，尤其是可冲压片材、容器、包装材料、汽车零件、电子电气零件等。
• STYRENIC COPOLYMER AND PRODUCTION THEREOF
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0511407A1

  公开（公告）日：1992-11-04

  A styrenic copolymer having at least one structural unit represented by general formula (I) and either a structural unit represented by general formula (II) or a structural unit represented by general formula (IX), the content of the unit (II) or the unit (IX) being 0.01 to 99.9 mole %. In these formulae each symbol is as defined in the specification. This copolymer is highly syndiotactic in the stereoregularity of the chain composed of the structural units (I) and is excellent in the adhesion and compatibility with other resins.

  一种苯乙烯共聚物，至少有一个结构单元由通式(I)和一个结构单元由通式(II)或一个结构单元由通式(IX)表示，单元(II)或单元(IX)的含量为 0.01 至 99.9 摩尔%。在这些式子中，每个符号都与说明书中的定义相同。这种共聚物由结构单元（I）组成的链具有高度的立体均匀性，与其他树脂的粘合性和相容性极佳。
• Graft copolymer, process for production thereof and resin composition containing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0559108A1

  公开（公告）日：1993-09-08

  There are disclosed a graft copolymer formed by grafting a styrenic monomer onto a high polymer having double bonds in the side chain to constitute highly syndiotactic polystyrenic chain as the graft component, the graft copolymer having a content of graft component of 0.005 to 99% by weight and a reduced viscosity of 0.01 to 30 dl/g as measured at a concentration of 0.05 g/dl in 1,2,4-trichlorobenzene at 135°C or a melt index of 0.001 to 500 g/10 minutes as measured at 300°C under a load of 2.16 kg; a process for efficiently producing the above graft copolymer using a catalyst comprising specific components; and a resin composition comprising the above graft copolymer, a highly syndiotactic styrenic polymer or other thermoplastic resin and, when necessary, an inorganic or organic filler. The above graft copolymer and resin composition are excellent in resistance to heat and chemicals, electrical properties, moldability, compatibility, impact resistance, etc.

  本发明公开了一种接枝共聚物，该接枝共聚物是通过将苯乙烯单体接枝到侧链中具有双键的高聚物上而形成的，作为接枝组分，该接枝共聚物的接枝组分含量为 0.005 至 99%（重量百分比），在浓度为 0.05克/分升，在135℃的1,2,4-三氯苯中测得，或在300℃、载荷为2.16公斤的条件下测得，熔融指数为0.001至500克/10分钟；使用由特定组分组成的催化剂高效生产上述接枝共聚物的工艺；以及由上述接枝共聚物、高对位苯乙烯聚合物或其他热塑性树脂以及必要时无机或有机填料组成的树脂组合物。上述接枝共聚物和树脂组合物具有优异的耐热性、耐化学性、电气性能、成型性、相容性、抗冲击性等。