1-(5,5-二氧代吩噻嗪-10-基)乙酮 | 1220-99-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 中文名称: 1-(5,5-二氧代吩噻嗪-10-基)乙酮
• 英文名称: 1-(5,5-dioxido-10H-phenothiazin-10-yl)ethan-1-one
• 英文别名: 1-(5,5-dioxido-10H-phenothiazin-10-yl)ethanone；N-acetylphenothiazine 5,5-dioxide；NSC-403471；10-acetyl-10H-phenothiazine 5,5-dioxide；10-acetyl-phenothiazine-5,5-dioxide；10-Acetyl-phenothiazin-5,5-dioxid；10H-Phenothiazine, 10-acetyl-, 5,5-dioxide；1-(5,5-dioxophenothiazin-10-yl)ethanone
• CAS: 1220-99-1
• 化学式: C₁₄H₁₁NO₃S
• 分子量: 273.312
• InChiKey: UNVGDZPNNRQUNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  62.8
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2934300000

反应信息

• 作为反应物：
  描述：

  1-(5,5-二氧代吩噻嗪-10-基)乙酮 在 硫酸 、 水 、 硝酸 作用下， 生成 3-nitrophenothiazine 5,5-dioxide
  参考文献：
  名称：

  Selective Inhibitors of Monoamine Oxidase. 2. Arylamide SAR

  摘要：

  Monoamine oxidase (MAO) exists in two forms distinguishable by substrate specificity. Inhibition of MAO A is believed to be responsible for the antidepressant activity of MAO inhibitors. A group of N-arylacetamides are highly specific inhibitors of MAO A, some with IC50 values in the 10-100 nM range. The requirements for high activity and specificity include a nearly linear tricyclic aromatic portion but a larger and a smaller central ring component. The amide group, which is best acetamido, is optimally placed para to the smaller central group. The size and shape of the aromatic moiety appear to be the major influence on activity and specificity for MAO A.

  DOI：

  10.1021/jm00039a021
• 作为产物：
  描述：

  甲基吩噻嗪-10-基甲酮 在 双氧水 、 溶剂黄146 作用下， 以95%的产率得到1-(5,5-二氧代吩噻嗪-10-基)乙酮
  参考文献：
  名称：

  利用d–pπ键实现超长有机磷光

  摘要：

  开发具有超长使用寿命的纯有机材料是有吸引力的，但具有挑战性。在这里，我们报告了一种简洁的化学方法来调节电子结构以增强磷光。在将吩噻嗪模型系统中引入d–pπ键后，与参比PPMO相比，DOPPMO的磷光寿命提高了19倍。在磷光吩噻嗪中获得了高达876 ms的记录磷光寿命。理论计算和单晶分析表明，d–pπ键不仅降低了T 1的（n，π*）比例的状态，但也赋予刚性分子环境多种分子间的相互作用，从而实现长寿命的磷光。这一发现对延长磷光寿命和扩大磷光材料的范围做出了宝贵的贡献。

  DOI：

  10.1002/anie.201901546

文献信息

• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。
• Oxetane compound, actinic ray curable composition, ink composition for ink jet recording, and image formation method
  申请人：KONICA MINOLTA MEDICAL & GRAPHIC, INC.

  公开号：US20040252171A1

  公开（公告）日：2004-12-16

  Disclosed is an oxetane compound represented by the following formula (I), (II), (III), (IV) or (V): 1

  揭示了以下式子（I），（II），（III），（IV）或（V）所代表的氧杂环化合物：1
• Ink composition for ink jet printing and image forming method
  申请人：Ookubo Kimihiko

  公开号：US20050209365A1

  公开（公告）日：2005-09-22

  An ink composition for ink jet printing is disclosed, containing a compound represented by the following formula (a-1) or (a-2) and an alicyclic epoxy compound represented by the following formula (b). An image forming method by use thereof is also disclosed.

  公开了一种用于喷墨打印的油墨组合物，包含以下式子（a-1）或（a-2）所代表的化合物和以下式子（b）所代表的脂环状环氧化合物。同时还公开了使用该油墨组合物的图像形成方法。
• ACTIVE RAY-CURABLE COMPOSITION, ACTIVE RAY-CURABLE INK AND IMAGE-FORMING METHOD
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1829936A1

  公开（公告）日：2007-09-05

  Disclosed is an actinic ray curable ink containing pigment, a photolytic acid generating agent and an epoxy compound represented by the following formula (1-1) or (1-2),

  本发明公开了一种含颜料、光解酸生成剂和由下式（1-1）或（1-2）表示的环氧化合物的光固化油墨、
• POLYMERIZABLE ACTINIC RADIATION CURABLE COMPOSITION, POLYMERIZATION METHOD, ACTINIC RADIATION CURABLE INK AND IMAGE FORMATION METHOD, AND INK JET RECORDING APPARATUS AND EPOXY COMPOUND
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1840148A1

  公开（公告）日：2007-10-03

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of -O-, -S-, -SO-, SO2- -CBr2-, -C(CBr3)2-, and -C(CF3)2-; R1 to R18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合的光辐射固化组合物，包含一种光酸生成化合物和一种由式 (1) 表示的环氧化合物： 其中 X 代表二价基团，选自由-O-、-S-、-SO-、SO2-、-CBr2-、-C(CBr3)2-和-C(CF3)2-组成的组；R1 至 R18 各自独立地代表氢原子、卤素原子、具有 1-8 个碳原子的烃基，条件是烃基可能含有氧原子或卤素原子，或具有 1-8 个碳原子的取代或未取代的烷氧基。