1-乙基-2,2,5,5-四甲基吡咯烷 | 63886-58-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 中文名称: 1-乙基-2,2,5,5-四甲基吡咯烷
• 英文名称: 1-Ethyl-2,2,5,5-tetramethyl-pyrrolidin
• 英文别名: 1-ethyl-2,2,5,5-tetramethyl-pyrrolidine；1-Ethyl-2,2,5,5-tetramethylpyrrolidine
• CAS: 63886-58-8
• 化学式: C₁₀H₂₁N
• 分子量: 155.283
• InChiKey: GKPKSLODPGIJAO-UHFFFAOYSA-N

物化性质

• 沸点：
  148.6±8.0 °C(Predicted)
• 密度：
  0.799±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• PROCESS FOR THE PREPARATION OF POLYPROPYLENE-B-POLY(ETHYLENE-co-PROPYLENE)
  申请人：Chisso Petrochemical Corporation

  公开号：EP1033376A1

  公开（公告）日：2000-09-06

  A process for preparing polypropylene-b-poly(ethylene-co-propylene) by the use of a tubular continuous polymerizer in the presence of an olefin-polymerizing catalyst comprising a solid catalyst component (1) composed of titanium and halogen; an organosilicon compound (2); and, if necessary, at least one electron-donating compound (3) selected from the group consisting of organosilicon compounds represented by the general formula: RnSi(OR')4-n (wherein R and R' are each independently a C1-C10 hydrocarbon group; and n is an integer of 1 to 3) and nitrogenous heterocyclic compounds, wherein the solid catalyst component (1) is preliminarily brought into contact with the organosilicon compound (2) in the presence of the electron-donating compound (3), and then a polypropylene segment is formed through polymerization, followed by formation of a poly(ethylene-co-propylene) segment at the end of the polypropylene segment through polymerization. The process enables efficient preparation of the polymer with a reduced content of inorganic contaminants, even when the polymer is one having a weight-average molecular weight of as high as 100,000 or more.

  一种在烯烃聚合催化剂存在下使用管式连续聚合器制备聚丙烯-b-聚(乙烯-共丙烯)的工艺，烯烃聚合催化剂包括由钛和卤素组成的固体催化剂组分(1)；有机硅化合物(2)；以及必要时至少一种电子供体化合物(3)，该化合物选自由通式如下的有机硅化合物组成的组：RnSi(OR')4-n（其中 R 和 R'各自独立地为 C1-C10 烃基；n 为 1 至 3 的整数）和含氮杂环化合物，其中固体催化剂组分（1）在电子赋 予化合物（3）的存在下与有机硅化合物（2）初步接触，然后通过聚合形成聚丙烯段，接着通过聚合在聚丙烯段的末端形成聚（乙烯-共丙烯）段。即使聚合物的重量平均分子量高达 100,000 或更高，该工艺也能高效制备出无机污染物含量较低的聚合物。
• SOLID TITANIUM CATALYST COMPONENT, CATALYST FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1816146A1

  公开（公告）日：2007-08-08

  The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

  本发明提供了一种生产α-烯烃聚合物的工艺，该工艺包括在烯烃聚合催化剂存在下，使(a)C3或更高的α-烯烃聚合或共聚，烯烃聚合催化剂包括固体钛催化剂组分(I)，固体钛催化剂组分(I)含有钛、镁、卤素和具有两个或更多醚键的特定结构的化合物，以及具有高催化活性的有机金属催化剂组分(II)。在这一工艺中，特别是甚至在（a）高级烯烃的（共）聚合过程中，也不需要进行脱矿物质处理。使用本发明催化剂聚合得到的 4-甲基-1-戊烯基聚合物在触感、透明度、耐热性和可释放性方面都很出色，这种聚合物特别适合用作离型膜。
• Solid Titanium Catalyst Component, Olefin Polymerization Catalyst, And Process For Producing Olefin Polymer
  申请人：Matsumoto Tetsuhiro

  公开号：US20080004412A1

  公开（公告）日：2008-01-03

  The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C 3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.
• SOLID TITANIUM CATALYST COMPONENT, OLEFIN POLYMERIZATION CATALYST, AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：TANAKA Tooru

  公开号：US20100298517A1

  公开（公告）日：2010-11-25

  The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C 3 or higher a-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.
• US20140343241A1
  申请人：——

  公开号：US20140343241A1

  公开（公告）日：2014-11-20