1-乙基-9,10-蒽醌 | 24624-29-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1-乙基-9,10-蒽醌
• 英文名称: 1-ethylanthracene-9,10-dione
• 英文别名: α-ethylanthraquinone；1-ethyl-anthraquinone；1-Aethyl-anthrachinon；ethyl anthraquinone；ethyl-anthraquinone；ethylanthraquinone；1-Ethyl-9,10-anthraquinone
• CAS: 24624-29-1
• 化学式: C₁₆H₁₂O₂
• 分子量: 236.27
• InChiKey: HSKPJQYAHCKJQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2914690090

反应信息

• 作为反应物：
  描述：

  1-乙基-9,10-蒽醌 生成 4-Eth-(E)-ylidene-10-hydroxy-4H-anthracen-9-one
  参考文献：
  名称：

  Grummt, Ulrich-Walter; Friedrich, Manfred, Zeitschrift für Chemie, 1985, vol. 25, # 12, p. 434 - 435

  摘要：

  DOI：
• 作为产物：
  描述：

  1-vinyl-anthraquinone 在 钯 、 溶剂黄146 作用下， 生成 1-乙基-9,10-蒽醌
  参考文献：
  名称：

  THE SYNTHESIS OF CONDENSED RING COMPOUNDS. II. THE REACTION OF 1,3,4-HEXATRIENE WITH 1,4-NAPHTHOQUINONE²

  摘要：

  DOI：

  10.1021/jo01208a012

文献信息

• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• Organocatalyzed benzannulation for the construction of diverse anthraquinones and tetracenediones
  作者：Krishna Bahadur Somai Magar、Likai Xia、Yong Rok Lee

  DOI：10.1039/c5cc00623f

  日期：——

  An efficient one-pot synthesis of anthraquinones and tetracenediones was achieved by l-proline catalyzed benzannulation of commercially available 1,4-naphthoquinones or 1,4-anthracenedione with a variety of α,β-unsaturated aldehydes in good to excellent yield.

  一种高效的一锅法合成蒽醌和四氢蒽二酮的方法是通过商业可获得的1,4-萘醌或1,4-蒽二酮在l-脯氨酸催化下与多种α,β-不饱和醛反应，产率良好至优异。
• Acid- and radical-generating agent and method for generating acid and radical
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10451967B2

  公开（公告）日：2019-10-22

  It is a subject of the present invention to provide an acid- and radical-generating agent which has high sensitivity to an active energy ray having a wavelength of around 300 to 450 nm, and can exert both high acid-generating performance and high radical-generating performance, and has heat resistance; and a method for generating an acid and a radical. The present invention relates to a compound represented by the general formula (A); an acid- and radical-generating agent comprising the compound; and a method for generating an acid and a radical: wherein n pieces of R1 each independently represent an alkyl group, which may have a specific functional group in the chain, or in which a hydrogen atom may be substituted by a halogen atom; an alkoxy group, in which a hydrogen atom may be substituted by a halogen atom; an aryl group or an aryloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; or an arylalkyl group or an arylalkyloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; n pieces of R2 and R3 each independently represent a hydrogen atom, an alkyl group or an alkoxycarbonyl group; R4 to R7 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkenyl group, an aryl group, an alkoxycarbonyl group, a dialkylamino group or a nitro group; Y represents an oxygen atom, a sulfur atom, or a carbonyl group; n pieces of Z each independently represent a sulfonyl group or an alkoxyphosphoryl group; n represents 1 or 2.

  本发明的一个目的是提供一种对波长约为300至450纳米的活性能量射线具有高灵敏度的酸和自由基生成剂，能够发挥高酸生成性能和高自由基生成性能，并具有耐热性；以及一种生成酸和自由基的方法。本发明涉及一种由通式（A）表示的化合物；包括该化合物的酸和自由基生成剂；以及生成酸和自由基的方法：其中n个R1分别独立表示一种烷基基团，该烷基基团可能在链中具有特定的功能基团，或者氢原子可能被卤原子取代；一种烷氧基团，其中氢原子可能被卤原子取代；一种芳基或芳氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；或一种芳基烷基或芳基氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；n个R2和R3分别独立表示氢原子，烷基基团或烷氧羰基团；R4到R7分别独立表示氢原子，卤原子，烷基基团，烷氧基团，烯基基团，芳基，烷氧羰基团，二烷基氨基团或硝基；Y表示氧原子，硫原子或羰基；n个Z分别独立表示磺酰基或烷氧基磷酰基；n表示1或2。
• [EN] PROCESS AND INTERMEDIADES FOR THE PREPARATION OF 7-ALKYLATED STEROIDS<br/>[FR] PROCÉDÉ ET INTERMÉDIAIRES POUR LA PRÉPARATION DE STÉROÏDES 7-ALKYLÉS
  申请人：CRYSTAL PHARMA SAU

  公开号：WO2015181116A1

  公开（公告）日：2015-12-03

  A process for preparing compounds of formula (I), or a salt, solvate or stereoisomer thereof, including Fulvestrant, which process comprises free radical to a compound of formula (III), or a salt, solvate or stereoisomer thereof. The invention also refers to intermediates of said process.

  一种制备式(I)化合物的方法，或者其盐、溶剂合物或立体异构体，包括富马酸苯甲酸酯（Fulvestrant）的方法，该方法包括自由基向式(III)化合物转化的步骤，或者其盐、溶剂合物或立体异构体。该发明还涉及所述方法的中间体。
• EPOXY-OXETANE COMPOUND, METHOD FOR SYNTHESIZING SAME, AND USE OF SAID COMPOUND
  申请人：SHIKOKU CHEMICALS CORPORATION

  公开号：US20200270236A1

  公开（公告）日：2020-08-27

  The purpose of the present invention is to provide: a novel curable compound which can be expected to be used as a raw material for photocurable resins and thermosetting resins; a method for synthesizing said compound; a resin composition containing said compound; and a cured product thereof. This compound is an epoxy-oxetane compound represented by a formula, and this compound has a structure in which two epoxycyclohexyl groups (groups in which an oxirane ring and a cyclohexane ring are condensed) are bonded to an oxetane ring via a connector having one ether bond. In formula (I′), R 1 to R 3 may be the same as, or different from, each other, and each denote a hydrogen atom or a methyl group. n is 1 or 2.

  本发明的目的是提供一种新型可固化化合物，可望用作光固化树脂和热固化树脂的原料；一种合成该化合物的方法；含有该化合物的树脂组合物；以及其固化产物。该化合物是一种由公式表示的环氧-氧杂环己烷化合物，该化合物具有两个环氧环己基团（氧环烷环与环己烷环结合）通过一个具有一个醚键的连接器连接到一个氧杂环己烷环的结构。在公式（I′）中，R1至R3可能相同，也可能不同，每个代表一个氢原子或一个甲基基团。n为1或2。