1-乙炔基环己烷e硫醇 | 98559-20-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 中文名称: 1-乙炔基环己烷e硫醇
• 中文别名: 5-异噻唑甲醇,3-(2-甲基苯基)-
• 英文名称: 1-ethynyl-cyclohexanethiol
• 英文别名: 1-Aethinyl-cyclohexanthiol；Cyclohexanethiol, 1-ethynyl-；1-ethynylcyclohexane-1-thiol
• CAS: 98559-20-7
• 化学式: C₈H₁₂S
• 分子量: 140.249
• InChiKey: GWJRHWCWQKRESX-UHFFFAOYSA-N

物化性质

• 沸点：
  45 °C(Press: 6.5 Torr)
• 密度：
  0.995 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-氯-1-乙炔基-环己烷 在 sodium hydrogensulfide 、 乙醇 作用下， 生成 1-乙炔基环己烷e硫醇
  参考文献：
  名称：

  US2805257

  摘要：

  公开号：

文献信息

• Quinoxalin-2-one derivatives, compositions which protect useful plants and comprise these derivatives, and processes for their preparation and their use
  申请人：Schaper Wolfgang

  公开号：US20050256000A1

  公开（公告）日：2005-11-17

  Compounds of the formula (I) and salts thereof in which X is O or S; (Y) n =n substituents Y, n is 0, 1, 2, 3 or 4, R 1 is H, OH, NH 2 , (C 1 -C 4 )-alkylamino, di-[(C 1 -C 4 )-alkyl]amino or optionally substituted (C 1 -C 10 )-alkyl, (C 3 -C 10 )-alkenyl, (C 3 -C 10 )-alkynyl or (C 1 -C 10 )-alkoxy, (C 3 -C 10 )-cycloalkyl, (C 4 -C 10 )-cycloalkenyl, aryl or heterocyclyl, R 2 is H or optionally substituted (C 1 -C 10 )-alkyl, (C 3 -C 10 )-alkenyl, (C 3 -C 10 )-alkynyl, (C 3 -C 10 )-cycloalkyl, (C 4 -C 10 )-cycloalkenyl, aryl or heterocyclyl, where the radicals Y are as defined in claim 1 are suitable for use as safeners for crop plants or useful plants against the phytotoxic actions of agrochemicals such as pesticides in these plants.

  该式(I)的化合物及其盐，其中X为O或S；(Y)n=n取代基Y，n为0、1、2、3或4，R1为H、OH、NH2、(C1-C4)-烷基氨基、二-[(C1-C4)-烷基]氨基或可选择取代的(C1-C10)-烷基、(C3-C10)-烯基、(C3-C10)-炔基或(C1-C10)-烷氧基、(C3-C10)-环烷基、(C4-C10)-环烯基、芳基或杂环烷基，R2为H或可选择取代的(C1-C10)-烷基、(C3-C10)-烯基、(C3-C10)-炔基、(C3-C10)-环烷基、(C4-C10)-环烯基、芳基或杂环烷基，其中所述的基Y如权利要求1所定义的适用于作为作物植物或有用植物的安全剂，用于抵抗这些植物中农药等农药的植物毒性作用。
• Heterocyclic amides, method for the production thereof, substances containing said heterocyclic amides, and use thereof as pesticides
  申请人：Schaper Wolfgang

  公开号：US20060173022A1

  公开（公告）日：2006-08-03

  Amides of the formula (I) and salts thereof wherein: A is CH or N; Y is O or S; n is 0 or 1; R 1 is (C 1 -C 4 )-haloalkyl; R 2 and R 3 are identical or different and are hydrogen, (C 1 -C 4 )-alkyl, (C 1 -C 4 )-haloalkyl or halogen; R 4 is hydrogen, (C 1 -C 10 )-alkyl, (C 3 -C 10 )-cycloalkyl, (C 3 -C 10 )-alkenyl or (C 3 -C 10 )-alkynyl, where in the alkyl, cycloalkyl, alkenyl or alkynyl groups mentioned up to three hydrogen atoms may be replaced by halogen, preferably fluorine or chlorine, in the case of fluorine also up to the maximum number; R 5 is G 1 SR 6 , G 1 S(O)R 7 , G 1 S(O) 2 R 8 , G 1 OR 9 , G 1 NR 10 R 11 , G 2 CR 12 ═NOR 13 , G 1 ON═CR 14 R 15 , G 2 CR 12 ═N—NR 16 R 17 , G 1 NR 13 N═CR 14 R 15 , G 1 NR 18 NR 19 R 20 , G 1 ONR 21 R 22 , G 1 NR 23 OR 24 , G 2 CR 10 ═N (+) (O (−) )R 12 , R 25 or G 1 R 26 ; G 1 is a straight-chain or branched (C 2 -C 6 )-alkylene moiety, the distance between the amide nitrogen and the radical R 5 being at least C 2 ; G 2 is a straight-chain or branched (C 1 -C 6 )-alkylene moiety and R 6 to R 26 are as defined in the description; are suitable for controlling pests.

  公式（I）的酰胺及其盐，其中：A为CH或N；Y为O或S；n为0或1；R1为（C1-C4）卤代烷基；R2和R3相同或不同，为氢，（C1-C4）烷基，（C1-C4）卤代烷基或卤素；R4为氢，（C1-C10）烷基，（C3-C10）环烷基，（C3-C10）烯基或（C3-C10）炔基，在所述烷基，环烷基，烯基或炔基中，最多可有三个氢原子被卤素替换，优选为氟或氯，对于氟，也可以替换到最大数量；R5为G1SR6，G1S（O）R7，G1S（O）2R8，G1OR9，G1NR10R11，G2CR12═NOR13，G1ON═CR14R15，G2CR12═N—NR16R17，G1NR13N═CR14R15，G1NR18NR19R20，G1ONR21R22，G1NR23OR24，G2CR10═N（+）（O（−））R12，R25或G1R26；G1为直链或支链（C2-C6）-亚烷基，酰胺氮与基团R5之间的距离至少为C2；G2为直链或支链（C1-C6）-亚烷基，R6到R26如描述中所定义；适用于控制害虫。
• QUINOXALIN-2-ONE DERIVATIVES, COMPOSITIONS WHICH PROTECT USEFUL PLANTS AND COMPRISE THESE DERIVATIVES, AND PROCESSES FOR THEIR PREPARATION AND THEIR USE
  申请人：Schaper Wolfgang

  公开号：US20110143939A1

  公开（公告）日：2011-06-16

  Compounds of the formula (I) and salts thereof in which X, R 1 , R 2 , Y and n have the meanings indicated in the description, are suitable for use as safeners for crop plants or useful plants against the phytotoxic actions of agrochemicals such as pesticides in these plants.

  式(I)的化合物及其盐，其中X、R1、R2、Y和n的含义如描述中所示，适用于作为农作物或有用植物的安全剂，以防止农药等农业化学品对这些植物的植物毒性作用。