1-二(丙基硫基)磷酰基氧基丙烷 | 74125-01-2

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 中文名称: 1-二(丙基硫基)磷酰基氧基丙烷
• 中文别名: 2-庚基-4-甲基-1,3-二噁戊环
• 英文名称: dithiophosphoric acid O,S,S'-tripropyl ester
• 英文别名: O,S,S-Tripropyl dithiophosphate；1-bis(propylsulfanyl)phosphoryloxypropane
• CAS: 74125-01-2
• 化学式: C₉H₂₁O₂PS₂
• 分子量: 256.37
• InChiKey: AOTHZQJQFFOUEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  76.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  O,O'-Dipropyldithiophosphoric acid ammonium salt 、 1-二(丙基硫基)磷酰基氧基丙烷 以 丙酮 为溶剂， 生成 O,S-Dipropylphosphorodithioat
  参考文献：
  名称：

  Itskova,A.L. et al., Journal of general chemistry of the USSR, 1971, vol. 41, # 12, p. 2651 - 2654

  摘要：

  DOI：

文献信息

• [EN] PROCESSES FOR CONVERTING CARBOXAMIDES TO THIOCARBOXAMIDES<br/>[FR] PROCÉDÉS POUR CONVERTIR DES CARBOXAMIDES EN THIOCARBOXAMIDES
  申请人：VERTELLUS SPECIALTIES INC

  公开号：WO2016182900A1

  公开（公告）日：2016-11-17

  Process for converting a carboxamide to a thiocarboxamide includes reacting (a) a substrate that comprises a heteroatom-containing moiety and a carboxamide moiety with (b) a dialkyl dithiophosphate and/or a salt thereof. The heteroatom-containing moiety includes a heteroatom selected from the group consisting of N, O, and S. Processes for preparing piperidine-4-thiocarboxamide are described.

  将羧酰胺转化为硫代羧酰胺的过程包括将（a）包含杂原子基团和羧酰胺基团的底物与（b）二烷基二硫代磷酸盐和/或其盐反应。杂原子基团包括从N、O和S组成的杂原子。描述了制备吡啶-4-硫代羧酰胺的过程。
• LUBRICANT COMPOSITION AND DRIVING FORCE TRANSMITTING SYSTEM USING SAME
  申请人：Nippon Oil Corporation

  公开号：EP1816183A1

  公开（公告）日：2007-08-08

  The invention provides a lubricating oil composition comprising a lubricating base oil, a phosphorus compound and at least one organic acid salt selected from among alkaline earth metal sulfonates, alkaline earth metal phenates and alkaline earth metal salicylates, wherein the contents of the phosphorus compound and organic acid salt satisfy the conditions represented by the following formulas (1) to (3). In formulas (1)-(3), W(P) represents the content of phosphorus compound, in terms of phosphorus element, based on the total amount of the lubricating oil composition, and W(M) represents the content of organic acid salt content, in terms of alkaline earth metal elements, based on the total amount of the lubricating oil composition.

  本发明提供了一种润滑油组合物，该组合物由润滑基础油、磷化合物和至少一种选自碱土金属磺酸盐、碱土金属苯酸盐和碱土金属水杨酸盐的有机酸盐组成，其中磷化合物和有机酸盐的含量满足以下公式(1)至(3)所代表的条件。在公式(1)至(3)中，W(P)表示磷化合物的含量（以磷元素计），以润滑油组合物的总量为基础；W(M)表示有机酸盐的含量（以碱土金属元素计），以润滑油组合物的总量为基础。
• Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
  申请人：TAYCA CORPORATION

  公开号：US10208160B2

  公开（公告）日：2019-02-19

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.

  本发明提供了一种用于生产导电聚合物的氧化剂掺杂剂及其溶液，它们能够生产导电聚合物，适用于生产泄漏电流较低的电解质电容器。此外，还提供了使用其中任一种制备的导电聚合物。还提供了一种具有低泄漏电流的电解质电容器。氧化剂掺杂剂包括：有机铁磺酸盐；以及至少一种选自磷酸、磷酸盐、磷酸、亚磷酸盐、硼酸、硼酸盐、硫代磷酸、硫代磷酸、二硫代磷酸和二硫代磷酸组成的组。溶液包括溶解在水、醇或水与醇混合物中的氧化剂掺杂剂。导电聚合物是通过单体（如噻吩或其衍生物）的氧化聚合而制备的。导电聚合物用作电解质，以提供电解质电容器。
• Method for preparing an electrolyte capacitor
  申请人：TAYCA CORPORATION

  公开号：US10336859B2

  公开（公告）日：2019-07-02

  The method for preparing an electrolyte capacitor includes: providing an oxidant dopant agent for preparing the conductive polymer including: ferric naphthalenesulfonate; and at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate. The method also includes preparing a conductive polymer by using the oxidant dopant agent to obtain an electrolyte comprising the conductive polymer.

  制备电解质电容器的方法包括：提供用于制备导电聚合物的氧化剂掺杂剂，包括：萘磺酸铁；以及至少一种选自磷酸盐、亚磷酸盐、硼酸盐、硫代磷酸盐和二硫代磷酸盐的化合物。该方法还包括使用氧化剂掺杂剂制备导电聚合物，以获得包含导电聚合物的电解液。
• [EN] NOVEL COLLECTORS FOR FROTH FLOTATION OF MINERALS
  申请人：THE DOW CHEMICAL COMPANY

  公开号：WO1987003221A1

  公开（公告）日：1987-06-04

  (EN) A collector composition for use in froth flotation processes comprises two collectors. One of the collectors is preferably an omega-(hydrocarbylthio)-alkylamine, S-(omega-aminoalkyl) hydrocarbyl thioate, N-(hydrocarbyl)-alpha, omega-alkanediamine, (omega-aminoalkyl) hydrocarbon amide, omega-(hydrocarbyloxy)-alkylamine, omega-aminoalkyl hydrocarbonate, omega-(hydrocarbylthio)alkylamide or mixture thereof. The second collector is a thiocarbonate, a thionocarbamate, a thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, xanthogen formate, xanthic ester or mixture thereof. The collector composition floats a broad range of metal-containing minerals.(FR) Une composition collectrice, destinée à être utilisée dans les procédés de flottation par écumage, comprend deux collecteurs. L'un des collecteurs est de préférence constitué de: oméga-(hydrocarbylthio)-alkylamine, thioate de S-(oméga-aminoalkyle) hydrocarbyle, N-(hydrocarbyle)-alpha, oméga-alkanédiamine, amide de (oméga-aminoalkyle) hydrocarbure, oméga-(hydrocarbyloxy)-alkylamine, hydrocarbonate d'oméga-aminoalkyle, oméga-hydrocarbylthio)alkylamide, ou d'un mélange de ces compositions. Le second collecteur est constitué de: thiocarbonate, thionocarbamate, thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, formiate xanthogénique, ester xanthique, ou d'un mélange de ces compositions. Ladite composition collectrice permet la flottation d'une gamme étendue de minéraux contenant du métal.

  一种用于泡沫浮选过程的collector组合物包含两种collector。其中一种collector优选为ω-(烃基硫代)-烷基胺、S-(ω-氨基烷基)烃基硫醇酸盐、N-(烃基)-α,ω-二元烷基胺、(ω-氨基烷基)烃基酰胺、ω-(烃基氧基)-烷基胺、ω-氨基烷基烃基碳酸盐、ω-(烃基硫代)烷基酰胺或它们的混合物。另一种collector为硫碳酯、硫氮碳酸酯、硫磷酯、硫碳酰亚胺、硫磷甲酸酯、巯基化合物、酮酸甘油酯、二硫化物乙酸酯或它们的混合物。该collector组合物可浮选含有金属的各种矿物。