1-二(乙硫基)磷酰氧基乙烷 | 2404-78-6

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 中文名称: 1-二(乙硫基)磷酰氧基乙烷
• 中文别名: 2-氮杂二环[3.2.0]庚-2,6-二烯-3-胺
• 英文名称: dithiophosphoric acid O,S,S'-triethyl ester
• 英文别名: Dithiophosphorsaeure-O,S,S'-triaethylester；O,S,S'-Triaethyl-dithiophosphat；O,S,S-Triaethylphosphorodithioat；O.O.S-Triaethyl-dithiophosphat；O,S,S-Triethyl phosphorodithioate；1-bis(ethylsulfanyl)phosphoryloxyethane
• CAS: 2404-78-6
• 化学式: C₆H₁₅O₂PS₂
• 分子量: 214.29
• InChiKey: MKNAVGOWTFZJBQ-UHFFFAOYSA-N

物化性质

• 沸点：
  102-103 °C(Press: 0.3 Torr)
• 密度：
  1.151±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  76.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2931900090

反应信息

• 作为产物：
  描述：

  乙硫醇 在 phosphoryl dichloride fluoride 、 N,N-二甲基苯胺 作用下， 生成 1-二(乙硫基)磷酰氧基乙烷
  参考文献：
  名称：

  Process for the production of fluorophosphonic acid compounds

  摘要：

  公开号：

  US02489917A1

文献信息

• Safened sorptive granular pesticidal resin compositions for controlling soil borne pests and process for the preparation thereof
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0268926A2

  公开（公告）日：1988-06-01

  A pesticidal composition comprising: about 2.0% to 30.0%, by weight, of a pesticide, the technical grade of said pesticide having an acute dermal LD50 value, measured on rats or rabbits, of less than 50 mg/kg; about 5.0% to 20.0%, by weight, of a polyvinyl chloride or polyvinyl chloride/vinyl ester copolymer or homopolymer having a weight average molecular weight of about 200,000 to 400,000 and an inherent viscosity, as determined by ASTMD 1243, of about 1.00 to 1.32; about 5.0% to 15.0%, by weight, of a secondary plasticizing agent; about 0.3% to 2.0%, by weight, of a heat stabilizing agent for said resin; about 0.5% to 2.0%, by weight, of a surface active agent; about 40.0% to 80.0%, by weight, of a solid sorptive carrier; about 0.0% to 2.0%, by weight, of a drying agent and lubricant; and about 0.0% to 6.0%, by weight, of a de­activator; wherein said pesticidal composition is a solid sorptive granular pesticidal resin composition. The compositions are characterized by markendly reduced mammalian toxicity in comparison to the technical grade pesticide.

  一种杀虫剂组合物，按重量计，包括：约 2.0%至 30.0%的杀虫剂，所述杀虫剂的技术等级在大鼠或兔子身上测得的急性经皮半数致死剂量小于 50 毫克/千克；约 5.0%至 20.0%的聚氯乙烯或聚氯乙烯/乙烯基酯共聚物或均聚物，按重量计，所述聚氯乙烯或聚氯乙烯/乙烯基酯共聚物或均聚物的重量平均分子量约为 200,000 至 400,000 且固有分子量小于 50 毫克/千克。以重量计，约 5.0%至 20.0%的聚氯乙烯或聚氯乙烯/乙烯基酯共聚物或均聚物，其重量平均分子量约为 200,000 至 400,000 且按 ASTMD 1243 测定的固有粘度约为 1.00 至 1.32以重量计，约 5.0% 至 15.0% 的二次增塑剂；以重量计，约 0.3% 至 2.0% 的用于所述树脂的热稳定剂；以重量计，约 0.5% 至 2.0% 的表面活性剂；以重量计，约 40.0% 至 80.0%(重量)的固体吸附载体；约0.0%至2.0%(重量)的干燥剂和润滑剂；以及约0.0%至6.0%(重量)的失活剂；其中所述杀虫剂组合物是固体吸附颗粒杀虫剂树脂组合物。 与工业级杀虫剂相比，这些组合物的特点是明显降低了哺乳动物的毒性。
• Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
  申请人：TAYCA CORPORATION

  公开号：US10208160B2

  公开（公告）日：2019-02-19

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.

  本发明提供了一种用于生产导电聚合物的氧化剂掺杂剂及其溶液，它们能够生产导电聚合物，适用于生产泄漏电流较低的电解质电容器。此外，还提供了使用其中任一种制备的导电聚合物。还提供了一种具有低泄漏电流的电解质电容器。氧化剂掺杂剂包括：有机铁磺酸盐；以及至少一种选自磷酸、磷酸盐、磷酸、亚磷酸盐、硼酸、硼酸盐、硫代磷酸、硫代磷酸、二硫代磷酸和二硫代磷酸组成的组。溶液包括溶解在水、醇或水与醇混合物中的氧化剂掺杂剂。导电聚合物是通过单体（如噻吩或其衍生物）的氧化聚合而制备的。导电聚合物用作电解质，以提供电解质电容器。
• Method for preparing an electrolyte capacitor
  申请人：TAYCA CORPORATION

  公开号：US10336859B2

  公开（公告）日：2019-07-02

  The method for preparing an electrolyte capacitor includes: providing an oxidant dopant agent for preparing the conductive polymer including: ferric naphthalenesulfonate; and at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate. The method also includes preparing a conductive polymer by using the oxidant dopant agent to obtain an electrolyte comprising the conductive polymer.

  制备电解质电容器的方法包括：提供用于制备导电聚合物的氧化剂掺杂剂，包括：萘磺酸铁；以及至少一种选自磷酸盐、亚磷酸盐、硼酸盐、硫代磷酸盐和二硫代磷酸盐的化合物。该方法还包括使用氧化剂掺杂剂制备导电聚合物，以获得包含导电聚合物的电解液。
• Composite membrane and method for making the same
  申请人：——

  公开号：US20010050252A1

  公开（公告）日：2001-12-13

  A composite membrane and method for making the same, comprising a porous support and a polyamide surface. The subject membrane provides improved flux and/or rejection rates. The subject membrane is further capable of operating at lower operating pressures. The subject method includes reacting a polyfunctional amine with a polyfunctional acyl halide to form a polyamide. The method includes the step of contacting a complexing agent with the polyfunctional acyl halide prior substantial reaction between the polyfunctional acyl halide and a polyfunctional amine. The subject process is easily adapted to commercial scale manufacturing processes and is particularly suited for making nanofiltration and reverse osmosis composite membranes.

  一种复合膜及其制造方法，包括多孔支架和聚酰胺表面。该膜提高了通量和/或排斥率。该膜还能在较低的工作压力下工作。该方法包括将多官能团胺与多官能团酰基卤反应生成聚酰胺。该方法包括在多官能酰基卤与多官能胺发生实质性反应之前，将络合剂与多官能酰基卤接触。该主题工艺很容易适用于商业规模的制造工艺，尤其适用于制造纳滤和反渗透复合膜。
• [EN] NOVEL COLLECTORS FOR FROTH FLOTATION OF MINERALS
  申请人：THE DOW CHEMICAL COMPANY

  公开号：WO1987003221A1

  公开（公告）日：1987-06-04

  (EN) A collector composition for use in froth flotation processes comprises two collectors. One of the collectors is preferably an omega-(hydrocarbylthio)-alkylamine, S-(omega-aminoalkyl) hydrocarbyl thioate, N-(hydrocarbyl)-alpha, omega-alkanediamine, (omega-aminoalkyl) hydrocarbon amide, omega-(hydrocarbyloxy)-alkylamine, omega-aminoalkyl hydrocarbonate, omega-(hydrocarbylthio)alkylamide or mixture thereof. The second collector is a thiocarbonate, a thionocarbamate, a thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, xanthogen formate, xanthic ester or mixture thereof. The collector composition floats a broad range of metal-containing minerals.(FR) Une composition collectrice, destinée à être utilisée dans les procédés de flottation par écumage, comprend deux collecteurs. L'un des collecteurs est de préférence constitué de: oméga-(hydrocarbylthio)-alkylamine, thioate de S-(oméga-aminoalkyle) hydrocarbyle, N-(hydrocarbyle)-alpha, oméga-alkanédiamine, amide de (oméga-aminoalkyle) hydrocarbure, oméga-(hydrocarbyloxy)-alkylamine, hydrocarbonate d'oméga-aminoalkyle, oméga-hydrocarbylthio)alkylamide, ou d'un mélange de ces compositions. Le second collecteur est constitué de: thiocarbonate, thionocarbamate, thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, formiate xanthogénique, ester xanthique, ou d'un mélange de ces compositions. Ladite composition collectrice permet la flottation d'une gamme étendue de minéraux contenant du métal.

  一种用于泡沫浮选过程的collector组合物包含两种collector。其中一种collector优选为ω-(烃基硫代)-烷基胺、S-(ω-氨基烷基)烃基硫醇酸盐、N-(烃基)-α,ω-二元烷基胺、(ω-氨基烷基)烃基酰胺、ω-(烃基氧基)-烷基胺、ω-氨基烷基烃基碳酸盐、ω-(烃基硫代)烷基酰胺或它们的混合物。另一种collector为硫碳酯、硫氮碳酸酯、硫磷酯、硫碳酰亚胺、硫磷甲酸酯、巯基化合物、酮酸甘油酯、二硫化物乙酸酯或它们的混合物。该collector组合物可浮选含有金属的各种矿物。