1-十六烷基-3-甲基咪唑三氟甲基磺酸盐 | 404001-54-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 中文名称: 1-十六烷基-3-甲基咪唑三氟甲基磺酸盐
• 中文别名: 1-十六烷基-3-甲基咪唑三氟甲烷磺酸盐
• 英文名称: 1-hexadecyl-3-methylimidazol-1-ium trifluoromethanesulfonate
• 英文别名: 1-hexadecyl-3-methylimidazolium triflate；1-Hexadecyl-3-methylimidazolium triflate；1-hexadecyl-3-methylimidazol-3-ium;trifluoromethanesulfonate
• CAS: 404001-54-3
• 化学式: CF₃O₃S*C₂₀H₃₉N₂
• 分子量: 456.613
• InChiKey: ACAVWXLPLYKIQQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.85
• 重原子数：
  30
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  74.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-hexadecyl-3-methyl-3H-imidazol-1-ium; bromide 、 potassium trifluoromethansulfonate 反应 0.25h， 生成 1-十六烷基-3-甲基咪唑三氟甲基磺酸盐
  参考文献：
  名称：

  Synthesis of imidazolium and pyridinium-based ionic liquids and application of 1-alkyl-3-methylimidazolium salts as pre-catalysts for the benzoin condensation using solvent-free and microwave activation

  摘要：

  An efficient one-pot procedure for the synthesis of ionic liquids based on nitrogen-containing heterocycles, imidazolium or pyridinium under 'green chemistry' conditions has been described Imidazolium salts and DBU have been found to catalyze efficiently the berizoin condensation giving good yields within very short reaction time using solvent-free microwave activation conditions (C) 2009 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.tet.2009.11.110

文献信息

• Thermoregulated Microemulsions by Cyclodextrin Sequestration: A New Approach to Efficient Catalyst Recovery
  作者：Loïc Leclercq、Matthieu Lacour、Samantha H. Sanon、Andreea R. Schmitzer

  DOI：10.1002/chem.200900763

  日期：2009.6.22

  The combination of imidazolium surfactants with α‐cyclodextrins (CDs, in green) was used as a control element in the thermoregulated aqueous olefin hydroformylation. The self‐assembly of the imidazolium surfactants (red) favors the micellization process at high temperatures, whereas at lower temperatures the complexation of the surfactant monomers into the α‐CDs is favored.

  咪唑鎓表面活性剂与α-环糊精（CD，绿色）的组合用作温度调节烯烃加氢甲酰化反应中的控制元素。咪唑类表面活性剂（红色）的自组装有利于高温下的胶束化过程，而在较低温度下，表面活性剂单体向α-CDs的络合是有利的。
• FREESTANDING ION GEL AND METHOD FOR PREPARING THE SAME
  申请人：Research & Business Foundation Sungkyunkwan University

  公开号：US20210054127A1

  公开（公告）日：2021-02-25

  Disclosed is preparation of a freestanding ion gel having high stability and high ionic conductivity based on surface-activity ionic liquids. Further, disclosed is a solid electrolyte using the ion gel. A method for preparing the freestanding ion gel include mixing a surface-activity ionic liquid having an alkyl group having 8 or greater carbon atoms, a crosslinking agent, water and oil with each other to form a bicontinuous microemulsion mixture; ii) adding an initiator to the mixture; and iii) curing the mixture using ultraviolet (UV) or thermal energy to form a freestanding ion gel.
• Synthesis of imidazolium and pyridinium-based ionic liquids and application of 1-alkyl-3-methylimidazolium salts as pre-catalysts for the benzoin condensation using solvent-free and microwave activation
  作者：Audrey Aupoix、Bruce Pégot、Giang Vo-Thanh

  DOI：10.1016/j.tet.2009.11.110

  日期：2010.2

  An efficient one-pot procedure for the synthesis of ionic liquids based on nitrogen-containing heterocycles, imidazolium or pyridinium under 'green chemistry' conditions has been described Imidazolium salts and DBU have been found to catalyze efficiently the berizoin condensation giving good yields within very short reaction time using solvent-free microwave activation conditions (C) 2009 Elsevier Ltd All rights reserved