1-甲基-2-(丙氧基甲基)苯 | 91967-69-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-甲基-2-(丙氧基甲基)苯
• 英文名称: 2-Tolylmethyl-propylether
• 英文别名: Benzene, 1-methyl-2-(propoxymethyl)-；1-methyl-2-(propoxymethyl)benzene
• CAS: 91967-69-0
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: XGRDQHGLZFSIDQ-UHFFFAOYSA-N

物化性质

• 沸点：
  74 °C(Press: 6 Torr)
• 密度：
  0.9315 g/cm3
• 保留指数：
  1262

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  邻甲苯基溴化镁 、 氯甲基丙基醚 生成 1-甲基-2-(丙氧基甲基)苯
  参考文献：
  名称：

  Lapkin,I.I.; Mukhina,R.G., Journal of general chemistry of the USSR, 1961, vol. 31, p. 3732 - 3736

  摘要：

  DOI：

文献信息

• Lanthanide(III) Triflate-Catalyzed Thermal- and Microwave-Assisted Synthesis of Benzyl Ethers from Benzyl Alcohols
  作者：Anthony Handlon、Yu Guo

  DOI：10.1055/s-2004-836063

  日期：——

  The lanthanide(III) trifluoromethanesulfonate-catalyzed condensation of benzyl alcohols with primary and secondary ­alcohols is described. This reaction proceeds readily with benzyl ­alcohols that have an alkyl or aryl substituent at the α-, ortho-, or para-position using microwave radiation or heating. The intra­molecular variant of this reaction leads to cyclic benzofurans.

  三氟甲磺酸镧(III)催化苄醇与一、二级醇的缩合反应被报道。该反应在微波辐射下或加热下可顺利进行，苄醇在α位、邻位或对位带有烷基或芳基取代基。该反应的分子内变体则生成苯并呋喃。
• Thermosetting resin composition
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0342943A1

  公开（公告）日：1989-11-23

  The present invention relates to thermosetting resin compositions comprising a bismaleimide compound represented by the formula (I) and an aromatic amine resin represented by the general formula (II) and to processes for preparing the same.

  本发明涉及热固性树脂组合物，该组合物包含由式（I）表示的双马来酰亚胺化合物和由通式（II）表示的芳香族胺树脂 和通式 (II) 所代表的芳香胺树脂组成的热固性树脂组合物。 及其制备工艺。
• Dental composition and use thereof
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10010488B2

  公开（公告）日：2018-07-03

  A dental composition comprising a polymerizable monomer (1), initiator, filler component(s) in an amount of more than about 20 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, nitrogen, and oxygen, a bisphenol moiety. The invention is also directed to the use of the dental composition as or for producing a dental filling material, dental cement, crown and bridge material, inlay, onlay, veneer, orthodontic device or dental mill blank.

  一种牙科组合物，包括可聚合单体 (1)、引发剂、填料成分，其用量占组合物总重量的 20% 以上，重量百分比 (%)。%，可聚合单体 (1) 的特征如下：具有正好两个(甲基)丙烯酸酯活性分子，具有不对称的骨架作为(甲基)丙烯酸酯活性分子之间的连接，两个(甲基)丙烯酸酯活性分子作为烷基酯连接到不对称的单体骨架上，不对称的骨架包括一个酚类芳香分子，可聚合单体(1)不含有酸性分子、碳、氢、氮和氧以外的其他原子、双酚分子。本发明还涉及牙科组合物作为或用于生产牙科填充材料、牙科粘合剂、牙冠和牙桥材料、嵌体、镶嵌体、贴面、正畸装置或牙科铣床坯料的用途。
• DENTAL COMPOSITION AND USE THEREOF
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20170165152A1

  公开（公告）日：2017-06-15

  A dental composition comprising a polymerizable monomer (1), initiator, filler component(s) in an amount of more than about 20 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, nitrogen, and oxygen, a bisphenol moiety. The invention is also directed to the use of the dental composition as or for producing a dental filling material, dental cement, crown and bridge material, inlay, onlay, veneer, orthodontic device or dental mill blank
• Lapkin,I.I.; Mukhina,R.G., Journal of general chemistry of the USSR, 1961, vol. 31, p. 3732 - 3736
  作者：Lapkin,I.I.、Mukhina,R.G.

  DOI：——

  日期：——