1-苄基-4-(4-苄基苯基)苯 | 572910-05-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-苄基-4-(4-苄基苯基)苯
• 英文名称: 4,4'-dibenzyldiphenyl
• 英文别名: 4,4'-Dibenzyl-biphenyl；4,4'-Dibenzylbiphenyl；1-benzyl-4-(4-benzylphenyl)benzene
• CAS: 572910-05-5
• 化学式: C₂₆H₂₂
• 分子量: 334.461
• InChiKey: JBPBZQRUTGSRAC-UHFFFAOYSA-N

物化性质

• 熔点：
  113 °C
• 沸点：
  487.4±40.0 °C(Predicted)
• 密度：
  1.066±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-苄基-4-(4-苄基苯基)苯 在 氯磺酸 作用下， 反应 6.0h， 生成 4-[[5,5-Dioxo-7-[(4-sulfophenyl)methyl]dibenzothiophen-3-yl]methyl]benzenesulfonic acid
  参考文献：
  名称：

  Regioselective 2A,2D-disulfonyl capping of β-cyclodextrin for practical bifunctionalization on the secondary hydroxyl face

  摘要：

  A useful technique to bifunctionalize the secondary hydroxyl face of P-cyclodextrin is described. Regioselective 2(A),2(D)-disulfonylation of beta -cyclodextrin was achieved by reacting P-cyclodextrin with a combination of a novel disulfonyl imidazole reagent and molecular sieves in DMF. The resulting disulfonate was converted to 2(A),3(A),2(D),3(D)-dimannoepoxy-beta -C, cyclodextrin and 3(A),3(D)-diamino-3(A),3(D)-dideoxy-(2(A) S,3(A)S) (2(D)S,3(A)S)-beta -cyclodextrin, which contains two functional groups on the periphery of the molecule. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01025-5
• 作为产物：
  描述：

  4-溴二苯基甲烷 在 乙醚 、 magnesium 作用下， 生成 1-苄基-4-(4-苄基苯基)苯
  参考文献：
  名称：

  SOME NUCLEUS ALKYL DERIVATIVES OF PHENETHYLAMINE^* †

  摘要：

  DOI：

  10.1021/jo01225a001

文献信息

• Busch; Weber, Journal fur praktische Chemie (Leipzig 1954), 1936, vol. <2> 146, p. 1,23
  作者：Busch、Weber

  DOI：——

  日期：——
• Wolf, Chemische Berichte, 1881, vol. 14, p. 2031
  作者：Wolf

  DOI：——

  日期：——
• SOME NUCLEUS ALKYL DERIVATIVES OF PHENETHYLAMINE^* †
  作者：JOHN H. SPEER、ARTHUR J. HILL

  DOI：10.1021/jo01225a001

  日期：1937.5
• Regioselective 2A,2D-disulfonyl capping of β-cyclodextrin for practical bifunctionalization on the secondary hydroxyl face
  作者：Katsunori Teranishi

  DOI：10.1016/s0040-4039(01)01025-5

  日期：2001.8

  A useful technique to bifunctionalize the secondary hydroxyl face of P-cyclodextrin is described. Regioselective 2(A),2(D)-disulfonylation of beta -cyclodextrin was achieved by reacting P-cyclodextrin with a combination of a novel disulfonyl imidazole reagent and molecular sieves in DMF. The resulting disulfonate was converted to 2(A),3(A),2(D),3(D)-dimannoepoxy-beta -C, cyclodextrin and 3(A),3(D)-diamino-3(A),3(D)-dideoxy-(2(A) S,3(A)S) (2(D)S,3(A)S)-beta -cyclodextrin, which contains two functional groups on the periphery of the molecule. (C) 2001 Elsevier Science Ltd. All rights reserved.