2,2'-二(2-羟基乙氧基)-1,1'-联萘基 | 55441-95-7

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2,2'-二(2-羟基乙氧基)-1,1'-联萘基
• 英文名称: (RS)-2,2'-bis(2-hydroxyethoxy)-1,1'-binaphthalene
• 英文别名: 2,2'-bis(2-hydroxyethoxy)-1,1'-binaphthalene；2,2'-bis(2-hydroxyethoxy)-1,1'-binaphthyl；2-[1-[2-(2-Hydroxyethoxy)naphthalen-1-yl]naphthalen-2-yl]oxyethanol
• CAS: 55441-95-7
• 化学式: C₂₄H₂₂O₄
• 分子量: 374.436
• InChiKey: OVJPYIRGUFWANT-UHFFFAOYSA-N

物化性质

• 熔点：
  203-205.5 °C
• 沸点：
  536.2±45.0 °C(Predicted)
• 密度：
  1.252±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2'-二(2-羟基乙氧基)-1,1'-联萘基 在 氯化亚砜 作用下， 以 吡啶 为溶剂， 反应 2.0h， 以64%的产率得到2,2'-bis(2-chloroethoxy)-1,1'-binaphthyl
  参考文献：
  名称：

  大环多官能刘易斯碱—VI 1：聚草二茂铁

  摘要：

  1,1'- Dihydroxyferrocene发生反应以氯醚7 - 11个形成各polyoxaferrocenophanes 2 - 6。这些化合物的行为类似于“冠”醚。

  DOI：

  10.1016/0040-4020(80)80232-8
• 作为产物：
  描述：

  在 盐酸 作用下， 以 甲醇 为溶剂， 反应 1.0h， 生成 2,2'-二(2-羟基乙氧基)-1,1'-联萘基
  参考文献：
  名称：

  使用含有手性 1,1'-联萘的 C1-和 C2-对称 NADH 模型化合物进行不对称还原

  摘要：

  本研究通过使用 C2 对称 NADH 模型化合物处理 Mg 催化的苯甲酰甲酸乙酯不对称还原，其中首次引入轴不对称性（手性 1, 1'-联萘衍生物）作为手性来源，结果与具有相同手性中心的相应 C1 对称模型获得的结果进行了比较。与相应的 C1 对称模型相比，通过使用具有 C2 对称性的 NADH 模型可以获得更好的还原产物 ee。此外，键合的种类以及手性联萘与反应中心之间的距离影响了氢转移的立体化学过程。

  DOI：

  10.1246/bcsj.56.3672

文献信息

• [EN] BINAPHTHYL COMPOUNDS<br/>[FR] COMPOSÉS BINAPHTYLE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019043060A1

  公开（公告）日：2019-03-07

  The present invention relates to binaphthyl compounds of the formula (I), which are suitable as monomers for preparing polycarbonate resins having beneficial optical properties and which can be used for producing optical lenses: Formula (I) where X is C2-C4-alkandiyl or C1-C4-alkandiyl-C(O)-, where C(O) is bound to the oxygen atom of the hydroxyl group and where C2-C4-alkandiyl or C1-C4-alkandiyl, respectively, are unsubstituted or carry a phenyl ring; R and R' are identical or different and selected from mono or polycyclic aryl having from 6 to 36 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 36 atoms, which are ring members, where 1, 2, 3 or 4 of these atoms are selected from nitrogen, sulfur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl and mono- or polycyclic hetaryl are unsubstituted or carry 1 or 2 radicals Ra, which are selected from the group consisting of CN, CH3, OCH3, O-phenyl, O-naphthyl, S-phenyl, S-naphthyl, CI or F; and, if X is C1-C4-alkandiyl-C(O)-, the esters thereof, in particular the C1-C4-aIkyIesters thereof.

  本发明涉及通式(I)的双萘基化合物，其适于作为单体用于制备具有有益光学性能的聚碳酸酯树脂，并可用于生产光学透镜：式(I)中，X为C2-C4-亚烷基或C1-C4-亚烷基-C(O)-，其中C(O)键合于羟基的氧原子上，且所述C2-C4-亚烷基或C1-C4-亚烷基分别为未取代的或带有苯环；R和R'相同或不同，选自具有6至36个碳原子的单环或多环芳基以及具有总共5至36个原子的单环或多环杂芳基，这些原子为环成员，其中1、2、3或4个原子选自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基和单环或多环杂芳基为未取代的或带有1或2个选自CN、CH3、OCH3、O-苯基、O-萘基、S-苯基、S-萘基、Cl或F的基团Ra；并且，如果X为C1-C4-亚烷基-C(O)-，则为其酯，特别是其C1-C4-烷基酯。
• Ortho-phenylenediamine-based open and macrocyclic receptors in selective sensing of H2PO4−, ATP and ADP under different conditions
  作者：Kumaresh Ghosh、Indrajit Saha

  DOI：10.1039/c2ob26995c

  日期：——

  Ortho-phenylenediamine-based open and macrocyclic receptors have been designed and synthesized. The open receptor 1 and the macrocyclic receptor 2 fluorimetrically distinguish H2PO4− from the other anions examined in CH3CN with appreciable binding constant values. As practical applications, they are also sensible to nucleotides in aq. CH3CN (1 : 1, v/v). The receptor 1 shows significant emission change upon complexation of ATP and ADP. ADP is selectively distinguished by a ratiometric change in emission. In contrast, the macrocyclic receptor 2, under similar conditions, shows good binding with ATP over the others.

  基于正苯二胺的开放型和宏环型受体被设计和合成。开放型受体1和宏环型受体2在CH3CN中通过荧光法能够明显区分H2PO4−与其他所考察的阴离子，并具有可观的结合常数值。作为实际应用，它们在1:1（v/v）的水-CH3CN溶液中对核苷酸也表现出良好的感应。受体1在与ATP和ADP形成复合物时，荧光发射发生显著变化。ADP通过发射强度的比率变化被选择性区分。相对而言，宏环型受体2在类似条件下对ATP表现出良好的结合能力。
• [EN] TRIARYLMETHANE COMPOUNDS<br/>[FR] COMPOSÉS DE TRIARYLMÉTHANE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019154727A1

  公开（公告）日：2019-08-15

  The present invention relates to triarylmethane compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. (I) where R1, R2 are e.g. hydrogen; Y is an alkylene group having 2, 3 or 4 carbon atoms, Ar is selected from mono-or polycyclic aryl and mono-or polycyclic hetaryl; X1, X2, X3, X4 are CH, C-Rx or N, provided that in each ring at most two of X1, X2, X3, X4 are N; Rx is e.g. halogen, CN or CH=CH2. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I).

  本发明涉及具有以下式（I）的三芳基甲烷化合物，该化合物适用作为制备具有有益光学性能的热塑性树脂的单体，并可用于生产光学器件。其中R1，R2例如是氢；Y是具有2、3或4个碳原子的烷基基团，Ar选自单环或多环芳基和单环或多环杂芳基；X1、X2、X3、X4是CH、C-Rx或N，要求在每个环中最多有两个是N；Rx例如是卤素、CN或CH=CH2。该发明还涉及包含具有上述式（I）化合物的聚合单元的热塑性树脂。
• [EN] POLYCYCLIC COMPOUNDS<br/>[FR] COMPOSÉS POLYCYCLIQUES
  申请人：REUTER CHEMISCHE APPBAU E K

  公开号：WO2020079225A1

  公开（公告）日：2020-04-23

  The present invention relates to compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. In Formula (I), A1, A2 are selected from mono- or bicyclic aromatic radicals and mono- or bicyclic heteroaromatic radicals; X represents e.g. a single bond, O, NH, CR6R7; Y is e.g. absent or represents a single bond, O, NH, CR8R9; R1, R2 are hydrogen, a radical Ar' or a radical Ra; R3 is Alk, O-Alk'-, O-Alk'-[O-Alk']o, O-CH2-Ar-C(O)-, O-C(O)-Ar-C(O)-or O-Alk-C(O)-,where in the last five moieties the left O is bound to A1 and A2, respectively; m, n are 0, 1 or 2; o is an integer from 1 to 10; R4, R5 are e.g. selected from CN and a radical Ra; R6, R8 are e.g. selected from hydrogen, a radical Ar' and a radical Ra; R7, R9 are e.g. selected from hydrogen, C1-C4-alkyl and a radical Ar'; Ra is selected from the group consisting of C≡C-R11 and Ar-C≡C-R11; R11 is e.g. selected from hydrogen, methyl, mono- or polycyclic aryl having from 6 to 26 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 26 atoms, which are ring members, where 1, 2, 3 or 4 of the ring atoms of hetaryl are selected from nitrogen, sulphur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl are unsubstituted or substituted; and Ar is e.g. phenylene or naphthylene. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I) and to optical devices made of such resins.

  本发明涉及公式（I）的化合物，这些化合物适用作为单体制备具有有益光学性能的热塑性树脂，并可用于制造光学器件。在公式（I）中，A1、A2选自单环或双环芳香基团和单环或双环杂芳基团；X代表例如单键，O，NH，CR6R7；Y例如缺失或代表单键，O，NH，CR8R9；R1、R2为氢，基团Ar'或基团Ra；R3为Alk，O-Alk'-，O-Alk'-[O-Alk']o，O-CH2-Ar-C(O)-，O-C(O)-Ar-C(O)-或O-Alk-C(O)-，在最后五个基团中，左侧的O分别与A1和A2结合；m、n为0、1或2；o为1到10的整数；R4、R5例如选自CN和基团Ra；R6、R8例如选自氢，基团Ar'和基团Ra；R7、R9例如选自氢，C1-C4-烷基和基团Ar'；Ra选自C≡C-R11和Ar-C≡C-R11的组，R11例如选自氢，甲基，含有6到26个碳原子的单环或多环芳基和含有总共5到26个原子的单环或多环杂芳基，其中环原子中的1、2、3或4个来自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基是未取代或取代的；Ar例如苯基或萘基。该发明还涉及包含公式（I）化合物聚合单元的热塑性树脂以及由这种树脂制成的光学器件。
• Synthesis and NMR Spectroscopic Investigation of a Macrocyclic Diphosphine Ligand and its nickel(II) and palladium(II) complexes
  作者：Michael Widhalm、Hermann Kalchhauser、Hanspeter Kählig

  DOI：10.1002/hlca.19940770138

  日期：1994.2.9

  The preparation of a macrocyclic diphosphine ligand 5 incorporating a binaphthyl unit and its NiII and PdII complexes, 6 and 7, is described. A complete assignment of 1H,- 13C-, and 31P-NMR data on the basis of 2D NMR spectroscopy (1H, 1H-, 13C, 1H-, 31P, 1H-, 31P, 13C-COSY) was possible for 5, and also – in part – for 6 and 7.

  描述了结合有联萘单元及其Ni II和Pd II复合物6和7的大环二膦配体5的制备。的完整分配1 H， - 13 C-和31 P-NMR数据2D NMR光谱的基础上（1 H，1 H-，13 C，1 H-，31 P，1 H-，31 P，13 C-COSY）可能适用于5，也可以部分适用于6和7。