2,2,3,3,4,4,5,5,6,6,7,7,7-十三氟庚基丙烯酸酯 | 559-11-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2,2,3,3,4,4,5,5,6,6,7,7,7-十三氟庚基丙烯酸酯
• 英文名称: 1,1-dihydroperfluoroheptyl acrylate
• 英文别名: acrylic acid-(1H,1H-tridecafluoro-heptyl ester)；1-Acryloyloxy-1H,1H-tridecafluor-heptan；Acrylsaeure-(1H,1H-tridecafluor-heptylester)；2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl acrylate；1H,1H-tridecafluoroheptyl acrylate；2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl prop-2-enoate
• CAS: 559-11-5
• 化学式: C₁₀H₅F₁₃O₂
• 分子量: 404.128
• InChiKey: XJAVADKMAMZXPW-UHFFFAOYSA-N

物化性质

• 密度：
  1.5995 (estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  15

安全信息

• 海关编码：
  2916129000

反应信息

• 作为产物：
  描述：

  全氟-1-庚醇 、 丙烯酰氯 生成 2,2,3,3,4,4,5,5,6,6,7,7,7-十三氟庚基丙烯酸酯
  参考文献：
  名称：

  Fluorinated acrylates and polymers

  摘要：

  公开号：

  US02642416A1

文献信息

• Optical Element for Correcting Color Blindness
  申请人：Harding Brett T.

  公开号：US20130032758A1

  公开（公告）日：2013-02-07

  Described herein are devices, compositions, and methods for improving color discernment.

  本文描述了用于改善色彩辨识的设备、组合物和方法。
• EXTERNAL PREPARATION FOR THE SKIN AND COPOLYMER TO BE USED THEREIN
  申请人：POLA CHEMICAL INDUSTRIES, INC.

  公开号：EP1452161A1

  公开（公告）日：2004-09-01

  An object of the present invention is to provide an external preparation for the skin, which shows an excellent effect of sufficiently protecting the living body against irritants that exist in the external environments, and a polymer material to be preferably used therein. Provided is an external preparation for the skin obtained mixing a copolymer which comprises constituent units derived from monomers of the general formula (I), (II) and, if necessary, (IV) with the content of units (I) ranging from 5 to 25 wt % based on the total amount of all the constituent units, preferably with the contents of units (I), (II) and (IV) being 5 to 9.8 wt %, 30.2 to 45 wt %, and 50 to 60 wt %respectively, with other optional components. In the formula, R1 is H or C1-3 alkyl; R2 is C5-12 alkyl having 8 to 21 fluorine atoms; R3 is H or C1-3 alkyl; R4 is optionally hydroxylated C2-4 alkylene; R5 is H, a C1-20 aromatic group, a C1-20 aliphatic hydrocarbon group, or C1-20 acyl; and n is 4 to 50.

  本发明的目的是提供一种外用制剂，该制剂表现出优异的效果，能够充分保护生物体免受存在于外部环境中的刺激物的侵害，并提供一种最好用于其中的聚合物材料。提供了一种外用制剂，该制剂通过将包含来自通式（I）、（II）和（必要时）（IV）单体的组分单元的共聚物与单体（I）的含量在所有组分单元的总量中占5至25重量％的范围内混合，最好是单体（I）、（II）和（IV）的含量分别为5至9.8重量％、30.2至45重量％和50至60重量％，并添加其他可选组分而获得。在通式中，R1是H或C1-3烷基；R2是具有8到21个氟原子的C5-12烷基；R3是H或C1-3烷基；R4是可选择羟基化的C2-4烷基；R5是H、C1-20芳香族基、C1-20脂肪族碳氢基或C1-20酰基；n为4至50。
• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Non-hydrous soft contact lens and process for producing the same
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0228193A1

  公开（公告）日：1987-07-08

  A non-hydrous soft contact lens comprising a copolymer comprising, as monomer units, 49.9 to 95 mole % of an acrylate represented by Formula (I) shown below, 0 to 10 mole % of acrylic acid or the specified ester thereof, 4.9 to 50 mole % of a methacrylate represented by Formula (II) shown below, and 0.1 to 10 mole % of a crosslinking monomer. wherein R1 is at least one selected from the group consisting of a particular straight chain fluoroalkyl group and a particular straight chain alkyl group. wherein R2 is a particular straight chain fluoroalkyl group. The present soft contact lens requires no sterilization by boiling, and has good resistance to stain, good oxygen premea- bility, good elastic recovery and good shape stability. A process for producing the above non-hydrous soft contact lens to treatment(s) of esterification and/or transesterification, is also disclosed.

  一种非水性软性隐形眼镜，包括一种共聚物，其单体单元为 49.9 至 95 摩尔%的丙烯酸酯（如下图式(I)所示）、0 至 10 摩尔%的丙烯酸或其特定酯、4.9 至 50 摩尔%的甲基丙烯酸酯（如下图式(II)所示）和 0.1 至 10 摩尔%的交联单体。 其中 R1 至少选自特定直链氟烷基和特定直链烷基组成的组。 其中 R2 是一个特定的直链氟烷基。 本发明的软性隐形眼镜无需煮沸消毒，具有良好的抗污性、良好的耐氧性、良好的弹性恢复性和良好的形状稳定性。 此外，还公开了一种通过酯化和/或反酯化处理生产上述非水性软性隐形眼镜的工艺。
• FLUORORESIN FILM AND FLUORORESIN-LAMINATED ACRYLIC RESIN FILM
  申请人：Kaneka Corporation

  公开号：EP2292692A1

  公开（公告）日：2011-03-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component; and a fuororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸性和耐晒性。本发明涉及一种由(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟(甲基)丙烯酸烷基酯聚合物成分的含氟(甲基)丙烯酸树脂；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。