2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-十七氟壬基丙-2-烯酸酯 | 307-87-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-十七氟壬基丙-2-烯酸酯
• 中文别名: 2-羰基-6-苯基-3,4-二氢-2H-5,1-苯并噻吖辛因-1(6H)-羧酸
• 英文名称: acrylic acid-(1H,1H-heptadecafluoro-nonyl ester)
• 英文别名: Acrylsaeure-(1H,1H-heptadecafluor-nonylester)；1-Acryloyloxy-1H,1H-heptadecafluor-nonan；2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl acrylate；2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl prop-2-enoate
• CAS: 307-87-9
• 化学式: C₁₂H₅F₁₇O₂
• 分子量: 504.143
• InChiKey: BZYSOYLWVDQYMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  19

安全信息

• 海关编码：
  2916129000

反应信息

• 作为产物：
  描述：

  1H,1H-全氟-1-壬醇 、 丙烯酰氯 生成 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-十七氟壬基丙-2-烯酸酯
  参考文献：
  名称：

  Fluorinated acrylates and polymers

  摘要：

  公开号：

  US02642416A1

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• FLUORORESIN FILM AND FLUORORESIN-LAMINATED ACRYLIC RESIN FILM
  申请人：Kaneka Corporation

  公开号：EP2292692A1

  公开（公告）日：2011-03-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component; and a fuororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸性和耐晒性。本发明涉及一种由(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟(甲基)丙烯酸烷基酯聚合物成分的含氟(甲基)丙烯酸树脂；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。
• Fluororesin-laminated acrylic resin film
  申请人：KANEKA CORPORATION

  公开号：EP2325005A2

  公开（公告）日：2011-05-25

  An object of the present invention is to provide a novel multilayer film that can be employed also for use in interior and exterior members of vehicles, and that has excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin-laminated acrylic resin film, wherein a fluororesin film layer comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和抗污性，例如抗乳酸和抗防晒性。本发明涉及一种氟树脂层压丙烯酸树脂薄膜，其中，在由丙烯酸树脂（A）组成的薄膜层的至少一个面上，层压了由含有含氟烷基（甲基）丙烯酸酯聚合物成分的氟化（甲基）丙烯酸树脂（B）组成的氟树脂薄膜层。
• FLUORINE-CONTAINING (METH)ACRYLIC (CO)POLYMER AND MOLDED BODY FILMS THEREOF
  申请人：Kaneka Corporation

  公开号：EP2537869A1

  公开（公告）日：2012-12-26

  Provided are a fluorine-containing (meth)acrylic (co)polymer that scarcely generates gas when subjected to molding process, and is capable of supplying a molded body excellent in external appearance and transparency; a fluorine-containing (meth)acrylic resin film thereof; and a fluororesin laminated resin film having the same properties. The (co)polymer is a fluorine-containing (meth)acrylic (co)polymer obtained by polymerizing a monomer component including 100 to 70% by weight of a fluoroalkyl (meth)acrylate monomer, and 0 to 30% by weight of a different monomer copolymerizable therewith by effect of a radical polymerization initiator having a solubility in water of 0.1% or less by weight at 25°C, and having 8 to 14 carbon atoms.

  本发明提供了一种含氟（甲基）丙烯酸（共）聚合物，该聚合物在进行成型加工时几乎不产生气体，并且能够提供外观和透明度极佳的成型体；一种含氟（甲基）丙烯酸树脂薄膜；以及一种具有相同性能的氟树脂层压薄膜。该（共）聚合物是一种含氟（甲基）丙烯酸（共）聚合物，通过聚合单体组分获得，该单体组分包括 100 至 70% （重量百分比）的氟烷基（甲基）丙烯酸酯单体和 0 至 30% （重量百分比）的可与之共聚的不同单体，这些单体通过自由基聚合引发剂作用而聚合，自由基聚合引发剂在 25°C 时的水溶解度为 0.1% 或以下（重量百分比），且具有 8 至 14 个碳原子。
• Fluororesin film and fluororesin-laminated acrylic resin film
  申请人：Morita Kouji

  公开号：US10253143B2

  公开（公告）日：2019-04-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl(meth)acrylate polymer component; and a fluororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸和耐防晒性。本发明涉及一种用(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟（甲基）丙烯酸树脂，该树脂含有含氟烷基（甲基）丙烯酸酯聚合物成分；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。