2,4-二-叔-丁基-5-乙基苯酚 | 19245-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4-二-叔-丁基-5-乙基苯酚
• 英文名称: 5-ethyl-2,4-di-tert-butyl-phenol
• 英文别名: 5-Hydroxy-1-aethyl-2.4-di-tert.-butyl-benzol；5-Aethyl-2,4-di-tert-butyl-phenol；4,6-Di-tert-butyl-3-ethyl-phenol；2,4-Di-tert-butyl-5-ethylphenol；2,4-ditert-butyl-5-ethylphenol
• CAS: 19245-41-1
• 化学式: C₁₆H₂₆O
• 分子量: 234.382
• InChiKey: OATMJDXPGMCSRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2907199090

反应信息

• 作为反应物：
  描述：

  2,4-二-叔-丁基-5-乙基苯酚 、 异氰酸苯酯 在 Petroleum ether 作用下， 生成 phenyl-carbamic acid-(5-ethyl-2,4-di-tert-butyl-phenyl ester)
  参考文献：
  名称：

  Phenyl Isocyanate Derivatives of Certain Alkylated Phenols. Melting Points and X-Ray Powder Diffraction Data

  摘要：

  DOI：

  10.1021/i560129a007
• 作为产物：
  描述：

  3-乙基苯酚 、 异丁烯 在 硫酸 作用下， 生成 2,4-二-叔-丁基-5-乙基苯酚 、 2-叔-丁基-5-乙基苯酚
  参考文献：
  名称：

  THE INFLUENCE OF LOCATION OF SUBSTITUENT GROUPS ON THE VAPOR PRESSURE OF ALKYLATED PHENOLS

  摘要：

  DOI：

  10.1021/jo01152a008

文献信息

• HALOALKYLSULFONE SUBSTITUTED COMPOUNDS USEFUL FOR TREATING OBESITY AND DIABETES
  申请人：Olesen Preben Houlberg

  公开号：US20100041657A1

  公开（公告）日：2010-02-18

  The present invention relates to compounds of formula I, in which at least one of R5, R6 and R7 is SR12, S(O)R12 or S(O)2R12 group where R12 is a C1-6haloalkyl group, that act, as chemical uncouplers. Compounds of the invention are useful in the treatment, including prevention, of obesity, diabetes and a number of diseases or conditions associated therewith.

  本发明涉及公式I的化合物，其中R5，R6和R7中至少有一个是SR12，S（O）R12或S（O）2R12基团，其中R12是C1-6卤代烷基基团，可作为化学解偶联剂。本发明的化合物在治疗，包括预防肥胖症，糖尿病以及与之相关的许多疾病或病况方面非常有用。
• Colorants and polyester shaped articles mass-colored therewith
  申请人：Nippon Ester Company Ltd.

  公开号：EP0266754A2

  公开（公告）日：1988-05-11

  A heat resistant colorant for mass-coloring polyesters such as polyethylene terephthalate, comprising pigments and/or dyes and 42-2,000 parts per 100 parts of pigments and/or dyes by weight of a dispersing medium having a hydroxyl value not exceeding 25 mgKOH/g. The dispersing medium comprises a liquid dispersing medium, such as polyether, polyether-ester and the like, and a liquid aliphatic polyester dispersing medium. The colorants of the invention are easily blended and uniformly dispersed in a shape grade polyester, without causing degradation of the polyester, and the polyester shaped articles, such as fibers and films, mass-colored by the colorant are excellent in stability during the manufacture and are uniform in quality.

  一种用于聚酯（如聚对苯二甲酸乙二酯）大规模着色的耐热着色剂，包括颜料和/或染料，以及每 100 份颜料和/或染料重量中含 42-2000 份羟基值不超过 25 mgKOH/g 的分散介质。分散介质包括液体分散介质，如聚醚、聚醚酯等，以及液体脂肪族聚酯分散介质。本发明的着色剂易于混合并均匀地分散在定型级聚酯中，不会导致聚酯降解，而且由着色剂大量着色的聚酯定型制品（如纤维和薄膜）在制造过程中稳定性极佳，质量均匀。
• Recovery of epsilon-caprolactam from aqueous mixtures
  申请人：DSM N.V.

  公开号：EP0826665A1

  公开（公告）日：1998-03-04

  Process to separate ε-caprolactam from an aqueous mixture containing ε-caprolactam and at least 0.5 wt% oligomers, wherein the separation is performed by extraction using an organic extraction agent. The aqueous mixture may be obtained in a process to prepare ε-caprolactam starting from 6-aminocapronitrile or in a process to prepare ε-caprolactam starting from 6-aminocaproic acid.

  从含有ε-己内酰胺和至少0.5 wt%低聚物的水性混合物中分离ε-己内酰胺的工艺，其中分离是通过使用有机萃取剂萃取进行的。水性混合物可以在以 6-氨基己腈为原料制备ε-己内酰胺的工艺中获得，也可以在以 6-氨基己酸为原料制备ε-己内酰胺的工艺中获得。
• Process to prepare epsilon-caprolactam
  申请人：DSM N.V.

  公开号：EP0826666A1

  公开（公告）日：1998-03-04

  Process to prepare ε-caprolactam, in which in a step (a) a compound with the general formula:         O=CH-(CH2)4-C(O)-R     (1) in which R is -OH, -NH2 or O-R', in which R' is an organic group with 1 to 10 carbon atoms, is contacted with ammonia and hydrogen in a suitable solvent at elevated pressure in the presence of a hydrogenation catalyst to a mixture of primary amino compounds and ε-caprolactam, followed by a separate second step (b) in which the primary amino compounds are reacted to ε-caprolactam, wherein the solvent in step (a) is water or an aqueous medium, the yield to ε-caprolactam in step (a) is more than 10%, calculated on the initial molar amount of the compound according to formula (1), that ε-caprolactam is separated from the aqueous mixture obtained in step (a) by extraction and that the aqueous mixture resulting from the extraction, containing the primary amino compounds, is used in step (b).

  制备ε-己内酰胺的工艺，其中在步骤(a)中，通式为： O=CH-(CH2)4-C(O)-R (1) 其中 R 为-OH、-NH2 或 O-R'，其中 R'为 1 至 10 个碳原子的有机基团，在氢化催化剂存在下，在高压下于适当溶剂中与氨和氢接触，生成伯氨基化合物和 ε-己内酰胺的混合物，然后进行单独的第二步 (b)，使伯氨基化合物与 ε-己内酰胺反应、其中步骤(a)中的溶剂是水或水介质，步骤(a)中ε-己内酰胺的产率按式(1)化合物的初始摩尔量计算大于 10%，ε-己内酰胺通过萃取从步骤(a)中得到的水性混合物中分离出来，萃取得到的含有伯氨基化合物的水性混合物用于步骤(b)。
• Biodiesel
  申请人：LANXESS Deutschland GmbH

  公开号：EP3053992A1

  公开（公告）日：2016-08-10

  Die vorliegende Erfindung betrifft einen Biodiesel mit erhöhter Oxidationsstabilität umfassend Carbodiimide und Antioxidationsmittel wie insbesondere phenolische Antioxidationsmittel.

  本发明涉及一种氧化稳定性更强的生物柴油，其中包含碳二亚胺和抗氧化剂，特别是酚类抗氧化剂。