COATING MATERIAL FOR PARTIAL-DISCHARGE RESISTANCE, INSULATING COATING FILM FOR PARTIAL-DISCHARGE RESISTANCE, ELECTRICAL WIRE, AND DYNAMO-ELECTRIC MACHINE
申请人:Sumitomo Seika Chemicals Co., Ltd.
公开号:EP3848424A1
公开(公告)日:2021-07-14
There is provided a partial discharge-resistant paint that is excellent in the dispersibility of alumina particles, has an industrially suitable viscosity, and can form a coating that is excellent in partial discharge resistance and insulating properties. A partial discharge-resistant paint comprising at least one heat-resistant resin selected from the group consisting of a polyamide resin, a polyimide resin, a polyimide resin precursor, a polyamide-imide resin, a polyetherimide resin, and a polyester-imide resin; alumina particles having an aspect ratio of 2 to 99, and represented by the formula: Al2O3·nH2O; at least one selected from the group consisting of an organophosphorous compound, a sulfonic acid compound, an amic acid compound, a triazole compound, a compound represented by formula (A) below, a compound represented by formula (B) below, a compound represented by formula (C) below, citric acid, ethylenediaminetetraacetic acid, and an ethylenediaminetetraacetic acid derivative; and a solvent, wherein the solvent comprises 90% by mass or more of a solvent having a boiling point of 100°C or more at a pressure of 1 atm, the alumina particle content is 10 to 30% by mass relative to a total of 100% by mass of the heat-resistant resin and the alumina particles, and a total content of the heat-resistant resin and the alumina particles is 10 to 30% by mass.
本发明提供了一种耐局部放电涂料,该涂料在氧化铝颗粒的分散性方面表现优异,具有工业上合适的粘度,并能形成耐局部放电和绝缘性能优异的涂层。一种耐局部放电涂料,包含至少一种耐热树脂,该树脂选自由聚酰胺树脂、聚酰亚胺树脂、聚酰亚胺树脂前体、聚酰胺-酰亚胺树脂、聚醚酰亚胺树脂和聚酯-酰亚胺树脂组成的组;氧化铝颗粒,其长径比为 2 至 99,并由式表示:Al2O3-nH2O;至少一种选自有机磷化合物、磺酸化合物、胺基酸化合物、三唑化合物、下式(A)代表的化合物、下式(B)代表的化合物、下式(C)代表的化合物、柠檬酸、乙二胺四乙酸和乙二胺四乙酸衍生物组成的组;和溶剂,其中溶剂包括 90% 或更多质量的溶剂,该溶剂在 1 atm 压力下的沸点为 100°C 或更高,相对于耐热树脂和氧化铝颗粒总计 100%的质量,氧化铝颗粒的含量为 10%至 30%,耐热树脂和氧化铝颗粒的总含量为 10%至 30%。