benzophenone-3,3'-dicarboxylic acid chloride | 6472-69-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzophenone-3,3'-dicarboxylic acid chloride
• 英文别名: Benzoyl chloride, 3,3'-carbonylbis-；3-(3-carbonochloridoylbenzoyl)benzoyl chloride
• CAS: 6472-69-1
• 化学式: C₁₅H₈Cl₂O₃
• 分子量: 307.133
• InChiKey: RDFXKHUFUZUURT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  benzophenone-3,3'-dicarboxylic acid chloride 、 2-乙基苯胺 生成 3,3'-Bis(N-phenethyl)carbamoyl-benzophenone
  参考文献：
  名称：

  Symmetrically disubstituted aromatic compounds and pharmaceutical compositions for inhibiting poly (ADP-ribose) glycohydrolase, and methods for their use

  摘要：

  描述了对称二取代芳香化合物和含有这种化合物的药物组合物，这些化合物抑制和/或调节聚(ADP核糖)甘油水解酶（也称为PARG）的活性。本发明还涉及使用这些化合物和组合物进行治疗或预防以及通过给予有效量的这些化合物来治疗本文描述的疾病和紊乱的方法。

  公开号：

  US20020132852A1
• 作为产物：
  描述：

  3,3'-二甲基二苯甲酮 在 chromium(VI) oxide 、 氯化亚砜 、 硫酸 、 溶剂黄146 作用下， 以 水 为溶剂， 生成 benzophenone-3,3'-dicarboxylic acid chloride
  参考文献：
  名称：

  Photochemistry of meta-substituted and para-substituted aromatic polycarbonyl compounds

  摘要：

  DOI：

  10.1021/jo00216a018

文献信息

• [EN] SYMMETRICALLY DISUBSTITUTED AROMATIC COMPOUNDS AND PHARMACEUTICAL COMPOSITIONS FOR INHIBITING POLY (ADP-RIBOSE) GLYCOHYDROLASE, AND METHODS FOR THEIR USE<br/>[FR] COMPOSES AROMATIQUES SYMETRIQUEMENT DISUBSTITUES ET COMPOSITIONS PHARMACEUTIQUES PERMETTANT D'INHIBER LA POLY (ADP-RIBOSE) GLYCOHYDROLASE, ET PROCEDES D'UTILISATION ASSOCIES
  申请人：GUILFORD PHARM INC

  公开号：WO2002057211A1

  公开（公告）日：2002-07-25

  Symmetrically disubstituted aromatic compounds and pharmaceutical compositions containing such compounds that inhibit and/or modulate the activity of poly(ADP-ribose) glycohydrolase, also known as PARG, are described. The invention is also directed to the therapeutic or prophylactic use of such compounds and compositions, and to methods of treating diseases and disorders described herein, by administering effective amounts of such compounds.

  本文描述了对称二取代芳香族化合物和含有此类化合物的制药组合物，这些化合物可以抑制和/或调节聚(ADP-核糖)酰基水解酶的活性，也称为PARG。本发明还涉及使用这些化合物和组合物的治疗或预防用途，以及通过给予有效量的这些化合物来治疗本文所述的疾病和障碍的方法。
• Spirodilactam polymers
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0359340A2

  公开（公告）日：1990-03-21

  Linear, alternating copolymers and terpolymers of a 1,6-diaza[4,4]spirodilactam and a primary diamine and process for preparing such copolymers and terpolymers by reacting a dioxaspirononane dione or a precursor thereof with a primary diamine, optionally in the presence of a tri- or tetracarboxylic acid.

  1,6-二氮杂[4,4]螺二内酰胺与伯胺的线性交替共聚物和三元共聚物，以及通过二氧天冬氨酰二酮或其前体与伯胺反应（可选择在有三或四羧酸存在的情况下）制备此类共聚物和三元共聚物的工艺。
• CROSSLINKABLE AROMATIC RESINS HAVING PROTONIC ACID GROUPS AND ION CONDUCTIVE POLYMER MEMBRANES BINDERS AND FUEL CELLS MADE BY USING THE SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1457511A1

  公开（公告）日：2004-09-15

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由直接键合在芳香环上的 C1 至 C10 烷基和羰基或碳碳双键或三键组成。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂，是优选的。
• Crosslinkable aromatic resin having protonic acid group, and ion conductive polymer membrane, binder and fuel cell using the resin
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20040191602A1

  公开（公告）日：2004-09-30

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C 1 to C 10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由 C 1 至 C 10 烷基和/或主链上有 1 至 3 个碳原子的亚烷基，其中至少有一个直接与芳香环键合的碳原子与氢、羰基或碳碳双键或三键键合。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂是首选。
• Non-ionic Template Synthesis of Amide-linked Rotaxanes: Axles with Benzophenone and Cinnamic Acid Units
  作者：Thomas Dünnwald、Amir Hossain Parham、Fritz Vögtle

  DOI：10.1055/s-1998-2029

  日期：1998.3