phenyl dimethyldithiophosphinate | 5745-37-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl dimethyldithiophosphinate
• 英文别名: Dimethyldithiophosphinsaeurephenylester；Phenyldimethyldithiophosphinat；Dimethyl-phenylsulfanyl-sulfanylidene-lambda5-phosphane；dimethyl-phenylsulfanyl-sulfanylidene-λ5-phosphane
• CAS: 5745-37-9
• 化学式: C₈H₁₁PS₂
• 分子量: 202.281
• InChiKey: XUGYISLTQVMUKC-UHFFFAOYSA-N

物化性质

• 熔点：
  68 °C
• 沸点：
  173-175 °C(Press: 11 Torr)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  57.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,4'-二氯二苯二硫醚 、 phenyl dimethyldithiophosphinate 在 Rh(H)(PEt₃)₃ 、 1,2-双(二苯基膦)乙烷 作用下， 以 丙酮 为溶剂， 反应 0.5h， 以68%的产率得到p-chlorophenyl dimethyldithiophosphinate
  参考文献：
  名称：

  Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

  摘要：

  Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh3)(4) and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.06.109
• 作为产物：
  描述：

  四甲基二膦烷二硫化物 、 二苯二硫醚 在 Rh(H)(PEt₃)₃ 、 1,2-双(二苯基膦)乙烷 作用下， 以 丙酮 为溶剂， 反应 0.5h， 以91%的产率得到phenyl dimethyldithiophosphinate
  参考文献：
  名称：

  Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

  摘要：

  Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh3)(4) and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.06.109

文献信息

• Equilibrium shift in the rhodium-catalyzed acyl transfer reactions
  作者：Mieko Arisawa、Yui Igarashi、Haruki Kobayashi、Toru Yamada、Kentaro Bando、Takuya Ichikawa、Masahiko Yamaguchi

  DOI：10.1016/j.tet.2011.07.031

  日期：2011.10

  enzene. Acid fluorides were converted into acylphosphine sulfides and thioesters using diphosphine disulfides and disulfides/triphenylphosphine, respectively. Aryl esters were obtained from acid fluorides and phenols in the presence of triphenylsilane. Aryl esters, acylphosphine sulfides, and thioesters were also interconverted in the presence of rhodium complexes. These rhodium-catalyzed acyl transfer

  铑/膦配合物催化酰基氟，芳基酯，酰基膦硫化物和硫代酯之间的平衡酰基转移反应。使用合适的共底物来接受杂原子基团将平衡转移到所需的产物上。使用苯甲酰基五氟苯作为氟化物供体，将酰基膦硫化物和芳基酯转化为酰基氟，并使用（4-甲苯基硫代）五氟苯进行硫酯的氟化反应。分别使用二膦二硫化物和二硫化物/三苯基膦将酰氟转化为酰基膦硫化物和硫酯。在三苯基硅烷的存在下，由酰基氟和苯酚获得芳基酯。在铑配合物的存在下，芳基酯，酰基膦硫化物和硫代酯也可以相互转化。这些铑催化的酰基转移反应在中性条件下进行，无需使用酸或碱。羰基铑中间体参与这些反应是由硫代酯和炔烃的羰基硫化反应提示的。
• PHOSPHORUS-CONTAINING COMPOUND, AND CURABLE EPOXY RESIN COMPOSITION CONTAINING SAME
  申请人：ADEKA CORPORATION

  公开号：US20160152643A1

  公开（公告）日：2016-06-02

  The purpose of the present invention is to provide a phosphorus-containing compound having reactivity with a glycidyl group, specifically a phosphorus-containing compound represented by general formula (I). (In the formula, m represents a numerical value of 1 to 10; R 1 and R 2 independently represent a hydrogen atom, an alkyl group or an aryl group; R 3 represents an alkyl group, an alkanediyl group, an alkanetriyl group, an alkanetetrayl group or an aromatic group; X represents an oxygen atom or a sulfur atom; Y represents an oxygen atom, a sulfur atom or —NR 4 —; and R 4 represents a hydrogen atom, an alkyl group or an aryl group.)

  本发明的目的是提供一种具有与环氧丙烷基反应性的含磷化合物，特别是一种由通式（I）表示的含磷化合物。（其中，m表示1到10的数值；R1和R2独立地表示氢原子、烷基或芳基；R3表示烷基、烷二基基、烷三基基、烷四基基或芳基；X表示氧原子或硫原子；Y表示氧原子、硫原子或—NR4—；而R4表示氢原子、烷基或芳基。）
• Phosphorus-containing compound, and curable epoxy resin composition containing same
  申请人：ADEKA CORPORATION

  公开号：US10562924B2

  公开（公告）日：2020-02-18

  The purpose of the present invention is to provide a phosphorus-containing compound having reactivity with a glycidyl group, specifically a phosphorus-containing compound represented by general formula (I). (In the formula, m represents a numerical value of 1 to 10; R1 and R2 independently represent a hydrogen atom, an alkyl group or an aryl group; R3 represents an alkyl group, an alkanediyl group, an alkanetriyl group, an alkanetetrayl group or an aromatic group; X represents an oxygen atom or a sulfur atom; Y represents an oxygen atom, a sulfur atom or —NR4—; and R4 represents a hydrogen atom, an alkyl group or an aryl group.)

  本发明的目的是提供一种具有与缩水甘油基反应活性的含磷化合物，特别是通式(I)所代表的含磷化合物。(式中，m 代表 1 至 10 的数值；R1 和 R2 独立地代表氢原子、烷基或芳基；R3 代表烷基、烷二基、烷三基、烷四基或芳基；X 代表氧原子或硫原子；Y 代表氧原子、硫原子或-NR4-；R4 代表氢原子、烷基或芳基)。
• TSVETKOV E. N.; CHEPAJKINA T. A.; KABACHNIK M. I., IZV. AN CCCP CEP. XIM., 1979, HO 2, 426-432
  作者：TSVETKOV E. N.、 CHEPAJKINA T. A.、 KABACHNIK M. I.

  DOI：——

  日期：——
• Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides
  作者：Mieko Arisawa、Tetsuya Ono、Masahiko Yamaguchi

  DOI：10.1016/j.tetlet.2005.06.109

  日期：2005.8

  Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh3)(4) and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides. (c) 2005 Elsevier Ltd. All rights reserved.