o,o-dimethyl phenylsulfonylamidophosphate | 4140-56-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o,o-dimethyl phenylsulfonylamidophosphate
• 英文别名: dimethyl N-benzenesulfonylamidophosphate；dimethyl(phenylsulfonyl)amidophosphate；benzenesulfonyl-amidophosphoric acid dimethyl ester；Benzolsulfonyl-amidophosphorsaeure-dimethylester；N--benzolsulfonamid；Dimethyl-(phenylsulfonyl)-phosphoramidat；Dimethyl phenylsulfonylamidophosphate；N-dimethoxyphosphorylbenzenesulfonamide
• CAS: 4140-56-1
• 化学式: C₈H₁₂NO₅PS
• mdl: MFCD00707541
• 分子量: 265.227
• InChiKey: WIBBFOBNDQNRMY-UHFFFAOYSA-N

物化性质

• 熔点：
  108-109 °C
• 沸点：
  360.3±25.0 °C(Predicted)
• 密度：
  1.371±0.06 g/cm3(Predicted)
• 溶解度：
  33.9 [ug/mL]

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  90.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  o,o-dimethyl phenylsulfonylamidophosphate 在 sodium iodide 作用下， 以 丙酮 为溶剂， 生成 NoName_967
  参考文献：
  名称：

  N-Alkyl (aryl) sulfonylphosphoramidate monoesters

  摘要：

  DOI：

  10.1021/jo00434a026
• 作为产物：
  描述：

  苯磺酰基叠氮化物 在 盐酸 作用下， 以 乙醚 、 乙腈 为溶剂， 生成 o,o-dimethyl phenylsulfonylamidophosphate
  参考文献：
  名称：

  N-Alkyl (aryl) sulfonylphosphoramidate monoesters

  摘要：

  DOI：

  10.1021/jo00434a026

文献信息

• New copper(II) 1D polymer containing dimethyl(phenylsulfonyl)amidophosphate: Synthesis, crystal structure and magnetic properties
  作者：Olesia V. Moroz、Victor A. Trush、Irina S. Konovalova、Oleg V. Shishkin、Yurii S. Moroz、Serhiy Demeshko、Vladimir M. Amirkhanov

  DOI：10.1016/j.poly.2009.02.012

  日期：2009.5

  Abstract The reaction of sodium dimethyl(phenylsulfonyl)amidophosphate NaL (HL = C6H5SO2NHP(O)(OCH3)2) with Cu(NO3)2 · 6H2O and o-bpe (1,2-bis(pyridine-2-yl)ethane) in appropriate ratios, afford the formation of 1D coordination polymer [Cu(L)2 · o-bpe]n in good yield. The crystal structures of HL (1) and [Cu(L)2 · o-bpe]n (2) are reported. In the crystal package the molecules of 1 are linked by intermolecular

  摘要二甲基（苯磺酰基）氨基磷酸钠NaL（HL = C6H5SO2NHP（O）（OCH3）2）与Cu（NO3）2·6H2O和邻-bpe（1,2-双（吡啶-2-基）乙烷）的反应以适当的比例，可以形成高产率的一维配位聚合物[Cu（L）2·o-bpe] n。报道了HL（1）和[Cu（L）2·o-bpe] n（2）的晶体结构。在晶体包装中，1的分子通过分子间的氢键连接，该分子间的氢键是由作为受体的磷酰基氧原子和作为供体的酰胺基团的氮原子形成的。2的晶体结构表明在一维聚合物链中存在被o-bpe配体桥接的不饱和Cu（L）2单元。Cu（II）原子扭曲了4 + 2八面体CuO4N2环境，该环境由属于两个去质子化螯合配体的磺酰基和磷酰基的氧原子以及桥接的o-bpe配体的氮原子形成。对2的磁性研究表明，铜离子之间存在弱的链内反铁磁交换相互作用。
• Mizhiritskii, M. D.; Reikhsfel'd, V. O., Journal of general chemistry of the USSR, 1986, vol. 56, p. 1373 - 1382
  作者：Mizhiritskii, M. D.、Reikhsfel'd, V. O.

  DOI：——

  日期：——
• Kirsanow; Schewtschenko, Zhurnal Obshchei Khimii, 1954, vol. 24, p. 474,482,882,883;engl.Ausg.S.483,490,879,880
  作者：Kirsanow、Schewtschenko

  DOI：——

  日期：——
• Kremlev, M. M.; Kharchenko, A. V.; Shaposhnikov, S. I., Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, # 7, p. 1452 - 1453
  作者：Kremlev, M. M.、Kharchenko, A. V.、Shaposhnikov, S. I.

  DOI：——

  日期：——
• Structure and sensitized near-infrared luminescence of Yb(III) complexes with sulfonylamidophosphate type ligand
  作者：Paula Gawryszewska、Olesia V. Moroz、Victor A. Trush、Dagmara Kulesza、Vladimir M. Amirkhanov

  DOI：10.1016/j.jphotochem.2010.06.033

  日期：2011.1

  A series of new lanthanide complexes with dimethyl(phenylsulfonyl)amidophosphate (HSP) was synthesized (Na[Ln(SP)(4)]}(n) (Ln1), [Ln(SP)(3)phen] (Ln2) and [Ln(SP)(3)bpy]center dot H2O (Ln3) (where Ln = Gd-III, Er-III, Yb-III and Lu-III; phen = 1,10-phenantroline; and bpy = 2,2'-bipyridine) and the crystal structures of [Er(SP)(3)phen] and [Yb(SP)(3)bpy]center dot H2O were resolved. Absorption (at 295, 4 K), emission (at 295, 77, 4 K) and IR (at 295 K) spectra as well as luminescence decay time measurements were used to characterize the photophysical properties of single crystals. Effective energy transfer from a [SP](-) ligand to the Yb-III ion was demonstrated despite a large energy gap Delta E = E-trip - E-2F5/2. Replacing one molecule of the [SP](-) ligand with the phen or bpy molecule caused reduction of the emission decay time from 35 mu s for Yb1 to 20 and 15.5 mu s for Yb2 and Yb3, respectively at the temperature of 295 K. Using the absorption spectra tau(rad) (1.1 ms-Yb1, 943 mu s-Yb2 and 914 mu s-Yb3) and Q(Ln)(Ln) (3.14%-Yb1, 2.19%-Yb2, 1.64%-Yb3) were estimated. On the basis of low temperature, high-resolution absorption and luminescence spectra, the ligand-field splittings of the excited and ground states of Yb-III complexes were determined. (C) 2010 Elsevier B.V. All rights reserved.