1,4-Bis(diphenylphosphino)-1,4-butandion | 89243-77-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-Bis(diphenylphosphino)-1,4-butandion
• 英文别名: 1,4-Bis(diphenylphosphanyl)butane-1,4-dione
• CAS: 89243-77-6
• 化学式: C₂₈H₂₄O₂P₂
• 分子量: 454.445
• InChiKey: HVLBSFLTIOGUEW-UHFFFAOYSA-N

物化性质

• 熔点：
  70 °C
• 沸点：
  602.2±65.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  丁二酰氯 、 二苯基(三甲基硅基)膦 以 乙醚 为溶剂， 反应 1.0h， 以58.5%的产率得到1,4-Bis(diphenylphosphino)-1,4-butandion
  参考文献：
  名称：

  Lindner, Ekkehard; Kern, Herbert, Chemische Berichte, 1984, vol. 117, # 1, p. 355 - 365

  摘要：

  DOI：

文献信息

• Metallic complexes covalently bound to conjugated polymers and electronic devices containing such compositions
  申请人：——

  公开号：US20040072018A1

  公开（公告）日：2004-04-15

  The present invention relates to polymeric metal complexes comprising metallic complexes covalently bound to conjugated polymers and luminescent materials containing such polymeric metal complexes. The invention further relates to electronic devices in which the active layer includes such polymeric metal complexes.

  本发明涉及聚合物金属配合物，其包括共价结合到共轭聚合物和含有这种聚合物金属配合物的发光材料的金属配合物。本发明还涉及包括这种聚合物金属配合物的活性层的电子器件。
• Process for the hydroformylation of an olefin
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0272608A1

  公开（公告）日：1988-06-29

  A process for the hydroformylation of an olefin, which comprises hydroformylating an olefinic compound by reacting it with carbon monoxide and hydrogen in a hydroformylation reaction zone in the presence of a catalyst solution containing rhodium and an oxide of an organic trivalent phosphorus compound to form an aldehyde having a carbon number larger by one than that of the olefinic compound; adding an organic trivalent phosphorus compound to the reaction mixture, followed by distillation to separate a distillate containing the aldehyde from a high-boiling residue containing rhodium; oxidizing the high-boiling residue at the same time as or subsequent to the distillation to convert the organic trivalent phosphorus compound to its oxide; and recycling the oxidized residue to the hydroformylation reaction zone as a recycling catalyst solution, wherein the hydroformylation reaction is conducted under a condition such that the proportion of an alcohol content supplied as contained in the recycling catalyst solution is maintained at a level of not higher than 14% by weight based on the total amount of the olefinic compound and the catalyst solution supplied to the hydroformylation reaction zone.

  一种烯烃的加氢甲酰化工艺，包括在含有铑和有机三价磷化合物氧化物的催化剂溶液存在下，在加氢甲酰化反应区使烯烃化合物与一氧化碳和氢气反应，生成碳原子数比烯烃化合物大 1 的醛，从而使烯烃化合物加氢甲酰化；向反应混合物中加入有机三价磷化合物，然后进行蒸馏，从含有铑的高沸点残渣中分离出含有醛的蒸馏物；在蒸馏的同时或之后氧化高沸点残留物，将有机三价磷化合物转化为其氧化物；以及 将氧化残留物作为循环催化剂溶液循环到加氢甲酰化反应区，其中加氢甲酰化反应是在这样的条件下进行的：根据提供给加氢甲酰化反应区的烯烃化合物和催化剂溶液的总量，循环催化剂溶液中所含的醇含量比例保持在不高于 14% （按重量计）的水平。
• Photoactive lanthanide complexes with phosphine oxides, phosphine oxide-sulfides, pyridine N-oxides, and phosphine oxide-pyridine N-oxides, and devices made with such complexes
  申请人：——

  公开号：US20030144487A1

  公开（公告）日：2003-07-31

  The present invention is generally directed to luminescent lanthanide compounds with phosphine oxide, phosphine oxide-sulfide, pyridine N-oxide, and phosphine oxide-pyridine N-oxide ligands. It also relates to electronic devices in which the active layer includes a lanthanide complex.

  本发明一般涉及具有氧化膦、氧化膦-硫化物、吡啶 N-氧化物和氧化膦-吡啶 N-氧化物配体的发光镧系化合物。本发明还涉及活性层包括镧系配合物的电子设备。
• Polymers having attached luminescent metal complexes and devices made with such polymers
  申请人：——

  公开号：US20030148142A1

  公开（公告）日：2003-08-07

  The present invention is generally directed to a polymeric metal complex comprising a polymeric material having a plurality of a first-type functional groups, wherein at least a portion of the functional groups are coordinated to at least one metal containing complex, polymeric-metal complex salts comprising at least one polymeric material having a plurality of first-type functional groups having a charge, and at least one metal complex having an opposite charge. It further relates to devices that are made with the polymeric metal complex or the polymeric-metal complex salt.

  本发明一般涉及一种聚合金属络合物，该络合物由具有多个第一型官能团的聚合材料组成，其中至少有一部分官能团与至少一种含金属的络合物配位；还涉及聚合金属络合物盐，该盐由至少一种具有多个第一型官能团的聚合材料和至少一种具有相反电荷的金属络合物组成。本发明还涉及使用聚合金属络合物或聚合金属络合物盐制造的设备。
• LINDNER, E.;KERN, H., CHEM. BER., 1984, 117, N 1, 355-365
  作者：LINDNER, E.、KERN, H.

  DOI：——

  日期：——