p,p'-N(CH3)2-Diphenyloxid | 62849-42-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p,p'-N(CH3)2-Diphenyloxid
• 英文别名: bis-(4-dimethylamino-phenyl)-ether；Bis-(4-dimethylamino-phenyl)-aether；Tetra-N-methyl-4,4'-oxy-di-anilin；4,4'-Oxybis(N,N-dimethylaniline)；4-[4-(dimethylamino)phenoxy]-N,N-dimethylaniline
• CAS: 62849-42-7
• 化学式: C₁₆H₂₀N₂O
• 分子量: 256.348
• InChiKey: QQSANSAGYFSGNN-UHFFFAOYSA-N

物化性质

• 熔点：
  61-62 °C(Solv: ethanol (64-17-5))
• 沸点：
  385.1±27.0 °C(Predicted)
• 密度：
  1.086±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  15.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 4,4-二硝基二苯醚 在 甲酸 、 三乙胺 作用下， 以 水 、 叔丁醇 为溶剂， 反应 44.0h， 以80%的产率得到p,p'-N(CH3)2-Diphenyloxid
  参考文献：
  名称：

  使用可重复使用的氧化钴纳米粒子通过还原胺化反应方便地合成N-甲基和N-烷基胺

  摘要：

  N-甲基和N-烷基胺代表重要的精细化学品和散装化学品，已广泛用于学术研究和工业生产中。值得注意的是，这些结构基序存在于大量生命科学分子中，并在调节其活动中起着至关重要的作用。因此，通过使用富含地球的金属基催化剂开发一种方便，经济高效的胺合成和官能化方法的研究具有科学意义。在这方面，我们在此报告了一种便捷的还原胺化工艺，该工艺通过使用氮掺杂的石墨烯活化的纳米级Co 3 O 4选择性合成N-甲基化和N-烷基化的胺。基于催化剂。从廉价且易于获得的硝基芳烃或胺和甲醛水溶液或存在甲酸的甲酸开始，这种经济高效的还原胺化方案可合成各种N-甲基和N-烷基胺，氨基酸衍生物和现有药物分子。

  DOI：

  10.1002/cctc.201701617

文献信息

• Alkyl formates as reagents for reductive amination of carbonyl compounds
  作者：Oleg I. Afanasyev、Ilia Cherkashchenko、Anton Kuznetsov、Fedor Kliuev、Sergey Semenov、Olga Chusova、Gleb Denisov、Denis Chusov

  DOI：10.1016/j.mencom.2020.01.037

  日期：2020.1

  Alkyl formates in the presence of basic additives can serve as a reagent in the direct reductive amination of carbonyl compounds. The developed procedure can be applied to various aldehydes and ketones with electron donating and electron withdrawing groups.

  在碱性添加剂存在下，烷基甲酸酯可以用作羰基化合物直接还原胺化反应的试剂。所开发的方法可以用于具有给电子和吸电子基团的各种醛和酮。
• ADHESIVE COMPOSITIONS FOR BACK-COATING DENTAL PLATE AND HARDENING COMPOSITIONS FOR DENTAL USE
  申请人：TOKUYAMA CORPORATION

  公开号：EP1348416A1

  公开（公告）日：2003-10-01

  An adhesive composition for a denture base relining material which comprises an organic solvent containing no halogen atoms such as ethyl acetate, ethyl formate or acetone, a polymer such as a copolymer of methyl methacrylate and ethyl methacrylate, and a radical polymerizable monomer such as tetramethylolmethane tetramethacrylate; and a curable composition which comprises a radical polymerizable monomer, an organic peroxide such as benzoyl peroxide, a tertiary amine compound such as diethyl-p-toluidine or dipropyl-p-toluidine, and a hydroxycarboxylic acid such as malic acid or citric acid. The adhesive composition for a denture base relining material does not contain a halogen-atom-containing organic solvent whose harmful effect has been pointed out. Further, the composition has satisfactory adhesive properties and good operability and causes no degradation in the appearance of a denture base even if it sticks to an area on the surface of the denture base other than a contact area. The dental curable composition is widely used as dental materials having little surface unpolymerized layer and good curability, e.g., dental cement, a composite resin, a resin for crown and a denture base relining material.

  一种用于义齿基托衬垫材料的粘合剂组合物，它包括不含卤素原子的有机溶剂，如乙酸乙酯、甲酸乙酯或丙酮；聚合物，如甲基丙烯酸甲酯和甲基丙烯酸乙酯的共聚物；以及可自由基聚合的单体，如四甲基丙烯酸甲酯；和一种固化组合物，它包括一种可自由基聚合的单体、一种有机过氧化物（如过氧化苯甲酰）、一种叔胺化合物（如二乙基对甲苯胺或二丙基对甲苯胺）和一种羟基羧酸（如苹果酸或柠檬酸）。 用于义齿基托衬垫材料的粘合剂组合物不含已指出其有害影响的含卤原子有机溶剂。此外，该组合物具有令人满意的粘接性能和良好的可操作性，即使粘在义齿基托表面接触区以外的区域，也不会造成义齿基托外观的下降。这种牙科固化组合物被广泛用作表面未聚合层少且固化性好的牙科材料，例如牙科粘合剂、复合树脂、牙冠用树脂和义齿基托衬垫材料。
• Photosensitive heat resistant resin precursor composition
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1388758A1

  公开（公告）日：2004-02-11

  A photosensitive resin precursor composition exhibiting an excellent film thickness uniformity contains: a heat resistant resin precursor polymer; a radiation sensitive compound; and a solvent expressed by formula (1): R1 represents an alkyl group having a carbon number in the range of 1 to 3. R2, R3, R4, and R5 each represent hydrogen or an alkyl group having a carbon number in the range of 1 to 3, and 1 represents an integer in the range of 0 to 3.

  一种具有优异膜厚均匀性的光敏树脂前体组合物包含：一种耐热树脂前体聚合物；一种辐射敏感化合物；以及一种由式（1）表示的溶剂： R1 代表碳数在 1 至 3 之间的烷基。R2、R3、R4 和 R5 分别代表氢或碳原子数在 1 至 3 之间的烷基，1 代表 0 至 3 之间的整数。
• POLYAMIC ACID SOLUTION COMPOSITION HAVING CARBON BLACK DISPERSED THEREIN, PROCESS FOR PRODUCTION OF SEMICONDUCTIVE POLYIMIDE RESIN BELT USING THE COMPOSITION, AND SEMICONDUCTIVE POLYIMIDE RESIN BELT
  申请人：Gunze Limited

  公开号：EP2218755A1

  公开（公告）日：2010-08-18

  The present invention provides a carbon black-dispersed polyamic acid solution composition having a high solids content and a high carbon black content. The invention further provides an intermediate transfer belt using the polyamic acid solution composition. The carbon black-dispersed polyamic acid solution composition is obtained by uniformly dispersing carbon black in a polyamic acid solution obtained by reacting biphenyltetracarboxylic dianhydride and an aromatic diamine in an organic polar solvent. The biphenyltetracarboxylic dianhydride includes 2,3,3',4'-biphenyltetracarboxylic dianhydride and 3,3',4,4'-biphenyltetracarboxylic dianhydride. The aromatic diamine includes 4,4'-diaminodiphenyl ether and p-phenylenediamine. The polyamic acid solution has a solids content of 25 weight% or more.

  本发明提供了一种具有高固体含量和高炭黑含量的炭黑分散聚酰胺酸溶液组合物。本发明进一步提供了一种使用该聚酰胺酸溶液组合物的中间传输带。分散炭黑的聚酰胺酸溶液组合物是通过将炭黑均匀分散在由联苯四羧酸二酐和芳香族二胺在有机极性溶剂中反应得到的聚酰胺酸溶液中而得到的。联苯四羧酸二酐包括 2,3,3',4'-联苯四羧酸二酐和 3,3',4,4'-联苯四羧酸二酐。芳香族二胺包括 4,4'-二氨基二苯醚和对苯二胺。聚酰胺酸溶液的固体含量为 25 重量%或以上。
• Core-shell structured anionic nano microemulsion system, and preparation and application thereof
  申请人：PetroChina Company Limited

  公开号：US11174424B2

  公开（公告）日：2021-11-16

  The invention discloses a core-shell structured anionic nano microemulsion system, and preparation and application thereof. The system comprises an anionic Gemini surfactant, an oil phase material, a solubilizer and water; wherein the microemulsion has a core-shell structure, with the outer shell being an anionic Gemini surfactant, and the inner core being an oil phase material. The anionic Gemini surfactant is N,N,N′,N′-dodecyl tetrasubstituted diphenyl ether sulfonate having the structural formula: The anionic nano-microemulsion system of the present invention is homogeneous and transparent, has a spherical core-shell structure, has a nanometer size (3 to 40 nm) as droplets, has a narrow particle size distribution, is not easy to agglomerate, has good stability, and has an ultra-low interfacial tension and a capability of reducing viscosity of crude oil.

  本发明公开了一种核壳结构阴离子纳米微乳液体系及其制备和应用。该体系包括阴离子双子座表面活性剂、油相材料、增溶剂和水；其中微乳液具有核壳结构，外壳为阴离子双子座表面活性剂，内核为油相材料。阴离子 Gemini 表面活性剂为 N,N,N′,N′-十二烷基四取代二苯醚磺酸盐，其结构式为 本发明的阴离子纳米微乳液体系均匀透明，具有球形核壳结构，液滴大小为纳米级（3 至 40 纳米），粒度分布窄，不易团聚，稳定性好，具有超低的界面张力和降低原油粘度的能力。