Bis(hex-5-enyl) 5-[4-[3,5-bis(hex-5-enoxycarbonyl)phenyl]phenyl]benzene-1,3-dicarboxylate | 1082540-27-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis(hex-5-enyl) 5-[4-[3,5-bis(hex-5-enoxycarbonyl)phenyl]phenyl]benzene-1,3-dicarboxylate
• CAS: 1082540-27-9
• 化学式: C₄₆H₅₄O₈
• 分子量: 734.93
• InChiKey: WEIBXNVMOZZHSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  54
• 可旋转键数：
  30
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  dihex-5-enyl 5-iodoisophthalate 、 1,4-苯二硼酸 在 palladium diacetate 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 生成 Bis(hex-5-enyl) 5-[4-[3,5-bis(hex-5-enoxycarbonyl)phenyl]phenyl]benzene-1,3-dicarboxylate
  参考文献：
  名称：

  Molecular Design and Preparation of Bis-isophthalate Electrochromic Systems having Controllable Color and Bistability

  摘要：

  New electrochromic systems based on bis-isophthalates were designed and prepared. They showed electrochromism behavior by two-electron reduction. The displayed colors showed greatly enhanced bistability and were dependent on the length of the conjugated bridge between the two isophthalate groups. We believe that the connection of two electrochromic systems with a conjugated bridge is a good basic strategy to obtain new bistable electrochromic systems.

  DOI：

  10.1021/ol802208x

文献信息

• ELECTROCHROMIC MATERIALS AND ELECTROCHROMIC DEVICES USING THE SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP2157151B1

  公开（公告）日：2017-04-12
• US8274213B2
  申请人：——

  公开号：US8274213B2

  公开（公告）日：2012-09-25
• US9228124B2
  申请人：——

  公开号：US9228124B2

  公开（公告）日：2016-01-05
• Molecular Design and Preparation of Bis-isophthalate Electrochromic Systems having Controllable Color and Bistability
  作者：W. Sharmoukh、Kyoung Chul Ko、So Yeon Park、Ju Hong Ko、Ji Min Lee、Changho Noh、Jin Yong Lee、Seung Uk Son

  DOI：10.1021/ol802208x

  日期：2008.12.4

  New electrochromic systems based on bis-isophthalates were designed and prepared. They showed electrochromism behavior by two-electron reduction. The displayed colors showed greatly enhanced bistability and were dependent on the length of the conjugated bridge between the two isophthalate groups. We believe that the connection of two electrochromic systems with a conjugated bridge is a good basic strategy to obtain new bistable electrochromic systems.