3-(p-tolylthio)phthalonitrile | 1132806-20-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3-(p-tolylthio)phthalonitrile
• 英文别名: 3-(4-Methylphenyl)sulfanylbenzene-1,2-dicarbonitrile
• CAS: 1132806-20-2
• 化学式: C₁₅H₁₀N₂S
• 分子量: 250.324
• InChiKey: CXYURFCWASBLCR-UHFFFAOYSA-N

物化性质

• 沸点：
  438.2±45.0 °C(predicted)
• 密度：
  1.25±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  72.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(p-tolylthio)phthalonitrile 、 1,2-二氰基苯 在 三氯化硼 作用下， 以 对二甲苯 为溶剂， 反应 0.5h， 以7%的产率得到chloro-[1-(p-tolylthio)-7,12:14,19-diimino-21,5-nitrilo-5H-tribenzo[c,h,m][1,6,11]-triazacyclopentadecinato-(2)-κN22,κN23,κN24]-boron(III)
  参考文献：
  名称：

  A diastereoselective process induced in a curved aromatic molecule: oxidation of thioether-substituted subphthalocyanines

  摘要：

  Different sulfoxide-substituted subphthalocyanines have been synthesized by oxidation reaction of the corresponding thioether precursors. We have observed for the first time that when the oxidation takes place close to the macrocyclic core, the intrinsically chiral subphthalocyanine can induce a high degree of diastereoselectivity in this process. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.11.126

文献信息

• RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES
  申请人：3M Innovative Properties Company

  公开号：EP3601215A1

  公开（公告）日：2020-02-05
• METAL PHTHALOCYANINE DYE MIXTURE, CURABLE COMPOSITION, COLOR FILTER, AND METHOD FOR PRODUCING COLOR FILTER
  申请人：Mizukawa Yuki

  公开号：US20110020738A1

  公开（公告）日：2011-01-27

  The invention aims to provide a metal phthalocyanine dye mixture having excellent solubility in an organic solvent, which can be formed into a thin film. Provided are a metal phthalocyanine dye mixture contains at least phthalonitrile, a compound represented by the following formula (I), a compound represented by the following formula (II), and a metal or a metal compound, and a curable composition containing the metal phthalocyanine dye mixture, a color filter containing the curable composition, and a method for producing the color filter: wherein, in formulae (I) and (II), R 1 represents a substituent; n represents an integer of from 0 to 3; X represents —S—, —SO 2 —, or —SO 2 N(R 4 )—; R 4 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, or a heterocyclic ring group; R 2 represents an alkyl group, an alkenyl group, an aryl group, or a heterocyclic ring group; R 3 represents a substituent; m represents an integer of from 0 to 3; and Z represents —SO 3 M or —(X 1 -A) group; wherein X 1 has the same definition as X; A represents an optionally substituted group having at least one selected from —COOM, —SO 3 M, —SO 2 NH—R 5 , —SO 2 NHCOR 6 , —CONHSO 2 —R 7 , and —SO 2 NHSO 2 —R 8 ; M represents a hydrogen atom, or an alkali metal or organic base group for neutralization of charges; and R 5 , R 6 , R 7 , and R 8 each independently represents an alkyl group, an alkenyl group, an aryl group, or a heterocyclic ring group.
• US8445167B2
  申请人：——

  公开号：US8445167B2

  公开（公告）日：2013-05-21
• [EN] RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES<br/>[FR] MÉLANGES DE RÉSINES CONTENANT UN DILUANT RÉACTIF DE PHTALONITRILE ET UNE RÉSINE DE DIPHTALONITRILE, PRÉIMPRÉGNÉS ET ARTICLES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2018175025A1

  公开（公告）日：2018-09-27

  The present disclosure provides a resin blend. The resin blend includes at least one diluent containing a single phthalonitrile functional group and at least one diphthalonitrile resin. Also provided are prepregs including the resin blend impregnated into continuous reinforcing fibers or a cloth. Similarly, the present disclosure provides a molding compound including chopped reinforcing fibers distributed in the resin blend. An article is also provided, which includes polymerization product of the resin blend. An alternative article includes a substrate and a layer of the resin blend disposed on the substrate. The diluent typically improves processability of the resin blend and lowers the softening temperature of the polymerization product of the resin blend.
• A diastereoselective process induced in a curved aromatic molecule: oxidation of thioether-substituted subphthalocyanines
  作者：David González-Rodríguez、Tomás Torres

  DOI：10.1016/j.tetlet.2008.11.126

  日期：2009.2

  Different sulfoxide-substituted subphthalocyanines have been synthesized by oxidation reaction of the corresponding thioether precursors. We have observed for the first time that when the oxidation takes place close to the macrocyclic core, the intrinsically chiral subphthalocyanine can induce a high degree of diastereoselectivity in this process. (C) 2008 Elsevier Ltd. All rights reserved.